Fuel, Journal Year: 2023, Volume and Issue: 357, P. 130024 - 130024
Published: Oct. 9, 2023
Language: Английский
Fuel, Journal Year: 2023, Volume and Issue: 357, P. 130024 - 130024
Published: Oct. 9, 2023
Language: Английский
Applied Catalysis O Open, Journal Year: 2024, Volume and Issue: 190, P. 206930 - 206930
Published: May 1, 2024
This review offers an overview of the pivotal role oxygen vacancies in advanced oxidation technologies used to remove organic pollutants from water, including photocatalytic, electrocatalytic and photoelectrocatalytic processes. The fabrication various catalytic materials as well benefits challenges vacancy engineering are addressed detail. provides collective views published research reports. underlying principles rationale for roles treatment water critically assessed, which is key designing efficient catalysts systems purification.
Language: Английский
Citations
7Nano Materials Science, Journal Year: 2024, Volume and Issue: unknown
Published: July 1, 2024
The electrochemical reduction reaction of carbon dioxide (CO2-ERR) holds tremendous potential as a key approach for achieving neutrality by harnessing renewable resources. However, the current state CO2-ERR encounters challenges in terms efficiency and selectivity. Overcoming these obstacles requires development robust electrocatalyst capable enhancing process improving selectivity towards desired products. In recent years, 2D materials have garnered significant attention efficient catalysts. Among them, MXene stands out high interest due to unique multilayered structure presence surface functional moieties. material offers electrical conductivity, versatile chemistry, tunable interface designs. This comprehensive review explores utilization MXene-based catalysts into valuable It covers fundamental aspects conversion, including CO2 adsorption on Ti3C2Tx, mechanism (Mo2CS2) single-atom catalysts, applications, synthesis methods production, future prospects. Additionally, highlights significance modern artificial intelligence techniques, particularly machine learning, screening activating CO2, making it pioneering scientific endeavor.
Language: Английский
Citations
7Applied Catalysis O Open, Journal Year: 2024, Volume and Issue: 192, P. 206956 - 206956
Published: May 28, 2024
The Ni/CeO2 catalysts are prepared by different methods. Accordingly, the Ni/CeO2-C catalyst synthesized a simple precipitation and impregnation method was developed to obtain an excellent low-temperature activity for CO2 methanation. conversion reached 81.2%, achieved CH4 selectivity as high 100% even at temperature low 250 °C under gas hourly space velocity of 30,000 mL/(g·h) over Ni/CeO2-C. After 50 h stability test, performance still maintained 87.5% 100%. characterization results show that dispersion, particle size, reducibility Ni nanoparticles on Ni/CeO2-P same, which indicates physical structure is similar, difference in mainly caused chemical properties. Compared pure CeO2, exhibits significantly increased amount oxygen vacancies. According basic site there higher density sites than Ni/CeO2-P. Basic can also adsorb activate molecules, conducive further reaction. presence OH groups crucial they influence rate methanation through adsorption, activation, well their effects H*. In situ DRIFTS were conducted elucidate reaction mechanism with be absorbed rapidly surface catalyst, while species detected 200 °C.
Language: Английский
Citations
6Energy & environment materials, Journal Year: 2023, Volume and Issue: 7(2)
Published: Jan. 31, 2023
Dendritic mesoporous silica nanoparticles own three‐dimensional center‐radial channels and hierarchical pores, which endows themselves with super‐high specific surface area, extremely large pore volumes, especially accessible internal spaces, so forth. Dissimilar guest species (such as organic groups or metal nanoparticles) could be readily decorated onto the interfaces of realizing functionalization dendritic for targeted applications. As adsorbents catalysts, nanoparticles‐based materials have experienced nonignorable development in CO 2 capture catalytic conversion. This comprehensive review provides a critical survey on this pregnant subject, summarizing designed construction novel materials, involved chemical reactions methanation, dry reforming CH 4 ), value‐added chemicals from cyclic carbonates, 2‐oxazolidinones, quinazoline‐2,4(1 H ,3 )‐diones), on. The adsorptive performances been compared traditional SBA‐15 MCM‐41), corresponding reaction mechanisms thoroughly revealed. It is sincerely expected that in‐depth discussion give scientists certain inspiration to design brand‐new superior capabilities towards capture, utilization, storage.
Language: Английский
Citations
14Fuel, Journal Year: 2023, Volume and Issue: 357, P. 130024 - 130024
Published: Oct. 9, 2023
Language: Английский
Citations
14