Journal of Materials Chemistry A,
Journal Year:
2023,
Volume and Issue:
11(33), P. 17609 - 17615
Published: Jan. 1, 2023
A
PdRu–RuO
2
heterostructure
with
a
well-defined
PdRu
alloy
and
oxygen-vacancy-enriched
RuO
is
constructed
to
intensify
the
hydrogen
spillover
from
Ru
.
ChemSusChem,
Journal Year:
2024,
Volume and Issue:
unknown
Published: June 4, 2024
Abstract
Electrocatalytic
water
splitting
shows
great
potential
for
producing
clean
and
green
hydrogen,
but
it
is
hindered
by
slow
reaction
kinetics.
Advanced
electrocatalysts
are
needed
to
lower
the
energy
barriers.
The
establishment
of
built‐in
electric
fields
(BIEF)
in
heterointerfaces
has
been
found
be
beneficial
speeding
up
electron
transfer,
increasing
electrical
conductivity,
adjusting
local
environment,
optimizing
chemisorption
with
intermediates.
Engineering
modifying
BIEF
heterojunctions
offer
significant
opportunities
enhance
electronic
properties
catalysts,
thus
improving
This
comprehensive
review
focuses
on
latest
advances
engineering
heterojunction
catalysts
efficient
electrolysis.
It
highlights
fundamentals,
engineering,
modification,
characterization,
application
electrocatalytic
splitting.
also
discusses
challenges
future
prospects
engineering.
Overall,
this
provides
a
thorough
examination
next
generation
electrolysis
devices.
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(34), P. 16037 - 16046
Published: Aug. 9, 2024
The
core
principles
of
multicomponent
interface
and
electronic
structure
engineering
are
essential
in
designing
high-performance
catalysts
for
the
oxygen
evolution
reaction
(OER).
However,
combining
these
aspects
within
a
catalyst
is
significant
challenge.
In
this
investigation,
novel
approach
involving
development
hybrid
Ir-doped
CoMO4–Co(OH)2
(M
=
W
Mo)
hollow
nanoboxes
was
introduced,
enabling
remarkably
efficient
water
oxidation
electrocatalysis.
Constructed
from
ultrathin
nanosheet-assembled
nanoboxes,
structures
boast
wealth
active
centers
intermediate
species,
which
turn
enhance
both
charge
transfer
mass
transport
capabilities.
Moreover,
compelling
synergistic
effects
arising
interaction
between
CoMO4
Co(OH)2
significantly
bolster
OER
electrocatalysis
by
facilitating
electron
transfer.
introduction
Ir
atoms
serves
to
strategically
adjust
structure,
fine-tune
its
state,
operate
as
electrocatalysis,
thus
diminishing
overpotential.
This
configuration
results
Ir-CoWO4–Co(OH)2
Ir-CoMoO4–Co(OH)2
exhibiting
impressively
low
overpotentials
252
261
mV,
respectively,
10
mA
cm–2.
Utilized
conjunction
with
Pt/C
two-electrode
system
overall
splitting,
mere
1.53
V
cell
potential
needed
achieve
desired
cm–2
current
density.