Influence of Piperazine on CO2 Hydrate Dissociation Equilibrium Conditions DOI

Jing Xia,

Zhigao Sun

Journal of Chemical & Engineering Data, Journal Year: 2024, Volume and Issue: 69(11), P. 4098 - 4103

Published: Oct. 22, 2024

Carbon dioxide hydrate has a broad application such as the separation and capture of carbon cold storage in hydrates. However, its industrial is limited by problems formation conditions lower temperature or higher pressure, long induction time, slow growth rate. Thermodynamic promoters can effectively improve conditions. Piperazine selected new promoter to investigate influence on dissociation equilibrium this paper. Compared with pure forming structure I hydrate, addition piperazine forms II significantly move pressures temperatures. The concentration piperazine, better promoting effect.

Language: Английский

Robust and comprehensive predictive models for methane hydrate formation condition in the presence of brines using black-box and white-box intelligent techniques DOI

Marzieh Rashnavadi Nezhad,

M.A. Moradkhani, Behrouz Bayati

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 77, P. 612 - 624

Published: June 19, 2024

Language: Английский

Citations

4

Probing the pathway of H2-THF and H2-DIOX sII hydrates formation: Implication on hydrate-based H2 storage DOI
Jibao Zhang, Yan Li,

Yizhi Rao

et al.

Applied Energy, Journal Year: 2024, Volume and Issue: 376, P. 124289 - 124289

Published: Aug. 29, 2024

Language: Английский

Citations

4

Structure-H Type Hydrates Containing Cyclooctane-Based Epoxy (Oxirane) Compounds DOI Creative Commons
Jiwoong Seol

Korean Journal of Chemical Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 13, 2025

Abstract Recently, various epoxy (oxirane) compounds have been identified as novel methane hydrate formers, and their hydrates’ structural thermodynamic properties studied. However, most reported, thus far, are relatively small molecules that form structure-II (sII) hydrates. This study demonstrates two compounds, 1,2-epoxycyclooctane 1,2,5,6-diepoxycyclooctane, which cyclooctane backbones with one groups, respectively, can structure-H (sH) hydrates CH 4 help gas serve promoters of Crystallographic, spectroscopic, phase equilibrium analyses indicate the group LGM has minimal effect on composition (i.e., storage) but significantly influences conditions. The moderate hydrophilicity induced by enhances stability These findings suggest potential in hydrate-based technologies.

Language: Английский

Citations

0

A Comprehensive Review on the Rapid Hydrate Formation for CO2 Capture: Characteristics, Mechanism, and Applications DOI Open Access
Xuemin Zhang,

Wenqiang Cui,

Jiale Chen

et al.

Greenhouse Gases Science and Technology, Journal Year: 2025, Volume and Issue: unknown

Published: March 21, 2025

ABSTRACT CO 2 , being a major greenhouse gas, is regarded as an important contributor to global warming and environmental problems. capture separation are efficient approach for reducing emissions in the atmosphere. A hydrate method of provides feasible solution emission reduction However, rapid formation crucial using technique. As consequence, this paper comprehensively reviewed characteristics kinetic law hydrate, well deeply analyzed influences temperature pressure conditions, gas–liquid ratios, additives, hydration reaction system, process, other factors on its process. On basis, quantitative impact regulatory mechanisms different nucleation growth process were analyzed. The influence laws temperature, pressure, ratio selection, additive concentration, type system detailed. enhancement under multiple elucidated. application by challenges summarized. In end, key problems future directions pointed out. synergistic mechanism through still need be further investigated. Developing new reactor structures optimizing promoting hydrate.

Language: Английский

Citations

0

Molecular insight into hydrogen storage in clathrate hydrates: The effect of different promoters on the spontaneous nucleation of hydrogen hydrates studied via microsecond-scale molecular dynamics simulations DOI Creative Commons
Fengyi Mi, Fulong Ning, Thijs J. H. Vlugt

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162253 - 162253

Published: April 1, 2025

Language: Английский

Citations

0

Phase equilibria and guest gas occupancy characteristics of H2-DIOX sII hydrates based on calorimetric and Raman analysis DOI
Jibao Zhang, Yan Li, Yang Li

et al.

Fluid Phase Equilibria, Journal Year: 2024, Volume and Issue: unknown, P. 114262 - 114262

Published: Oct. 1, 2024

Language: Английский

Citations

2

Evaluation of the perturbed hard-sphere-chain equation of state for calculations of methane hydrate formation condition in the presence of ionic liquids DOI

Yaling Jiang,

Wenyuan Li, Yajun Mao

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 68, P. 1331 - 1343

Published: May 1, 2024

Language: Английский

Citations

1

Effect of cement slurry filtrate on methane hydrate stability during deepwater cementing operations DOI

Yuwei Zhang,

Huajie Liu, Dong Sheng Li

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 91, P. 822 - 833

Published: Oct. 18, 2024

Language: Английский

Citations

1

The Role of Gas Hydrates in Storing Natural Gas-Hydrogen Blends for Coupling Power-to-X and Decarbonization DOI
Shanker Krishna, Bhavikkumar Mahant, María Dolores Robustillo

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 6, 2024

Language: Английский

Citations

0

Influence of Piperazine on CO2 Hydrate Dissociation Equilibrium Conditions DOI

Jing Xia,

Zhigao Sun

Journal of Chemical & Engineering Data, Journal Year: 2024, Volume and Issue: 69(11), P. 4098 - 4103

Published: Oct. 22, 2024

Carbon dioxide hydrate has a broad application such as the separation and capture of carbon cold storage in hydrates. However, its industrial is limited by problems formation conditions lower temperature or higher pressure, long induction time, slow growth rate. Thermodynamic promoters can effectively improve conditions. Piperazine selected new promoter to investigate influence on dissociation equilibrium this paper. Compared with pure forming structure I hydrate, addition piperazine forms II significantly move pressures temperatures. The concentration piperazine, better promoting effect.

Language: Английский

Citations

0