Electrochimica Acta, Journal Year: 2024, Volume and Issue: 507, P. 145138 - 145138
Published: Sept. 26, 2024
Language: Английский
Electrochimica Acta, Journal Year: 2024, Volume and Issue: 507, P. 145138 - 145138
Published: Sept. 26, 2024
Language: Английский
Renewable Energy, Journal Year: 2024, Volume and Issue: 228, P. 120613 - 120613
Published: May 5, 2024
Language: Английский
Citations
10Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161560 - 161560
Published: March 1, 2025
Language: Английский
Citations
1International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 73, P. 305 - 315
Published: June 11, 2024
Language: Английский
Citations
4International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 91, P. 1343 - 1354
Published: Oct. 22, 2024
Language: Английский
Citations
4Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 178815 - 178815
Published: Jan. 1, 2025
Language: Английский
Citations
0Electrochimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 146226 - 146226
Published: April 1, 2025
Language: Английский
Citations
0Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 163332 - 163332
Published: April 1, 2025
Language: Английский
Citations
0ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(17)
Published: April 30, 2025
Abstract A novel alkaline anion exchange membrane was designed using poly(styrene‐b‐ethylene‐co‐butylene‐b‐styrene) (SEBS) as the backbone. Long side chains were grafted onto SEBS via a Friedel‐Crafts reaction, and cross‐linked (SEBS‐C6‐DiPRD) prepared an N‐heterocyclic crosslinker, 1,3‐N‐4‐piperidinyl propane, which features ring strain steric hindrance. The SEBS‐C6‐DiPRD exhibited ion capacity of approximately 1.8 mmol·g −1 , water uptake 85.4%, swelling ratio 24.1% at 80 °C. Thermal degradation began 370 °C, broke 310.6% stress 31.1 MPa. At operating temperature °C (typical for AEMFCs), conductivity reached 75.95 mS·cm . Notably, after 1000 hours testing under simulated AEMFC conditions, membrane's only decreased by 27.6%, demonstrating excellent long‐term stability. Under H 2 air peak power density 18.89 mW·cm −2
Language: Английский
Citations
0Journal of Electroanalytical Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 118991 - 118991
Published: Feb. 1, 2025
Language: Английский
Citations
0Journal of the American Ceramic Society, Journal Year: 2025, Volume and Issue: unknown
Published: April 6, 2025
Abstract Anion exchange membrane fuel cells (AEMFCs), which operate in alkaline environments, offer advantages such as compatibility with non‐precious metal catalysts Fe‒N‒C, making them an alternative to Pt‐based systems. This study explores development of iron phthalocyanine (FePc)‐derived Fe‒N‒C for AEMFCs, focusing on optimizing oxygen reduction reaction (ORR) activity and durability. The Fe‒N‒C/C were synthesized by pyrolyzing FePc supported carbon (FePc/C) precursors at varying temperatures (500°C–900°C), followed acid washing. High‐angle angular dark field scanning electron microscopy confirmed the atomic dispersion Fe species, while X‐ray photoelectron spectroscopy analysis revealed impact pyrolysis temperature active site configuration. catalyst heat treated 600°C exhibited optimal balance content pyrrolic‐N, resulting superior ORR performance a half‐wave potential ( E 1/2 ) 0.882 V, surpassing commercial Pt/C. Durability tests demonstrated minimal losses (3 mV after 20 000 cycles, emphasizing strong coordination Fe‒N x sites matrix. In single‐cell tests, promising comparable that Pt/C high‐operating voltage region. These findings highlight cost‐effective, durable AEMFCs.
Language: Английский
Citations
0