
Scientific African, Journal Year: 2025, Volume and Issue: unknown, P. e02609 - e02609
Published: Feb. 1, 2025
Language: Английский
Scientific African, Journal Year: 2025, Volume and Issue: unknown, P. e02609 - e02609
Published: Feb. 1, 2025
Language: Английский
Fuel, Journal Year: 2025, Volume and Issue: 387, P. 134273 - 134273
Published: Jan. 10, 2025
Language: Английский
Citations
1Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 111, P. 115363 - 115363
Published: Jan. 13, 2025
Language: Английский
Citations
1Journal of Mechanical Science and Technology, Journal Year: 2025, Volume and Issue: unknown
Published: March 3, 2025
Language: Английский
Citations
1Environmental Chemistry Letters, Journal Year: 2024, Volume and Issue: 22(5), P. 2151 - 2158
Published: June 13, 2024
Language: Английский
Citations
7International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 77, P. 1235 - 1244
Published: June 22, 2024
Language: Английский
Citations
6International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 98, P. 1341 - 1355
Published: Dec. 16, 2024
Language: Английский
Citations
6Chemical Engineering Journal Advances, Journal Year: 2024, Volume and Issue: 20, P. 100657 - 100657
Published: Oct. 10, 2024
Language: Английский
Citations
5International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 89, P. 1440 - 1453
Published: Oct. 8, 2024
Language: Английский
Citations
4Fuel, Journal Year: 2025, Volume and Issue: 387, P. 134334 - 134334
Published: Jan. 18, 2025
Language: Английский
Citations
0Chemistry - A European Journal, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 5, 2025
Abstract The use of hybrids, developed by grafting homogeneous catalysts onto supporting materials, has already demonstrated significant potential in various catalytic processes. These systems combine the advantages catalysts, such as high activity and selectivity, with those solid supports, including enhanced recyclability. Catalytic hydrogen (H 2 ) production via dehydrogenation C1 organic molecules targeting its fuel cells is a contemporary scientific issue directly connected climate crisis. Here, Iminophospine hybrid [SiO @benzNP] reduced analogue @benzNHP] were synthesized, covalently grafted on colloidal SiO , fully characterized (FT‐IR, RAMAN, TGA, ssNMR, BET), used for in‐situ synthesis @benzNP‐Fe II ] @benzNHP‐Fe complexes H from formic acid (HCOOH) formaldehyde (HCHO), at 80 °C. In HCOOH, both heterogenized exhibit producing CO 1 : ratio, without contamination, making them ideal cell applications. [SiO₂@benzNHP‐Fe catalyst superior performance substates. HCOOH dehydrogenation, over 82,000 turnover number (TONs) achieved retained efficiency five cycles, any further metal addition. HCHO it showed excellent well, achieving 1.3 L pure TONs exceeding 7,000, 3 consecutive uses. Advanced spectroscopic analysis confirmed stability structural integrity linking Schiff base reduction N−H groups to activity, durability reusability. This study demonstrates materials non‐noble metals cost‐effective sustainable production, paving way scalable renewable energy solutions.
Language: Английский
Citations
0