Hybrid layer-by-layer assembly of AuNPs/NSF composite for electrochemical detection of miRNA-196a DOI Creative Commons
Junhua Ji,

Gongjie Shi,

Jiayi Jiang

et al.

Discover Nano, Journal Year: 2024, Volume and Issue: 19(1)

Published: Nov. 26, 2024

Detection of microRNA-196a (miRNA-196a) is crucial in cancer research, enabling early diagnosis and providing guidance for individualized treatment. In this work, we employed a naturally occurring negatively charged nano silk fibroin (NSF) with high mechanical properties, biocompatibility, conductivity to be encapsulated positively gold nanoparticles (AuNPs) were used as film-forming materials electrostatic layer-by-layer self-assembly modify the working electrode screen-printed carbon (SPCE). Under optimized experimental conditions, uniformly distributed AuNPs on surface multilayer film modified SPCE (AuNPs/NSF)5.5/SPCE combined sulfhydryl-modified capture probe cp-DNA through gold-sulfur bonds. Furthermore, miRNA-196a specifically captured complementary base pairing achieve highly sensitive specific detection. can detect concentration range 1.0 × 10−13 10−6 M, calculated detection limit 4.63 10−14 M when signal-to-noise ratio 3. The obtained results showed that has excellent selectivity good stability over time.

Language: Английский

Unveiling the Electrocatalytic Performances of the Pd-MoS2 Catalyst for Methanol-Mediated Overall Water Splitting DOI Creative Commons
Aviraj M. Teli, Sagar M. Mane, Rajneesh Kumar Mishra

et al.

Inorganics, Journal Year: 2025, Volume and Issue: 13(1), P. 21 - 21

Published: Jan. 15, 2025

Herein, this work elucidates the synthesis of Pd-MoS2 catalyst for application in methanol-mediated overall water splitting. The scanning electron microscope (SEM) and transmission (TEM) pictures offer an exciting nanostructured shape Pd-MoS2, depicting a high surface area. Further, high-resolution TEM (HRTEM) confirm lattice plane (100), spacing (0.26 nm), hexagonal crystal structure Pd-MoS2. Moreover, high-angle annular dark-field (HAADF) images related color maps disclose Mo, S, Pd elements exhibits lower overpotentials 224.6 mV [methanol-mediated hydrogen evolution reaction (MM-HER)] at −10 mA cm−2 133 oxygen (MM-OER)] 10 cm−2. illustrates noteworthy stability 15.5 h MM-HER 18 MM-OER by chronopotentiometry test. Excitingly, Pd-MoS2∥Pd-MoS2 cell reveals small potential 1.581 V compared to MoS2∥MoS2 (1.648 V) In addition, combination brilliant durability over

Language: Английский

Citations

1

ZIF-67 derived superhydrophilic Fe-CoP/Ni2P@NC to construct self-supported electrode for boosting electrochemical water splitting DOI
Huihua Wang, Jinhong Wu,

Siwei Guo

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 179796 - 179796

Published: March 1, 2025

Language: Английский

Citations

1

Bimetallic Selenide NiCo‐Se/CFP as Effective Oxygen Evolution Reaction Electrocatalyst for Electrocatalytic Water Splitting DOI Open Access
Yajie Guo, Mengwei Wang, Cong Zhang

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(2)

Published: Jan. 1, 2025

Abstract The industrial application of green hydrogen production from water electrolysis strongly depends on the invention low‐cost, highly‐active, and stable nonprecious electrocatalysts for an oxygen evolution reaction (OER). In this work, a two‐step process is developed to prepare NiCo‐Se/CFP bimetallic electrocatalyst by low‐temperature selenization NiCo‐PBA precursors electro‐deposited carbon fibre paper. exhibits good catalytic activity OER, with overpotential 307 mV at 10 mA cm −2 , Tafel slope only 39.94 dec −1 in 1 M KOH. steady current density well‐preserved microscopic morphology during 20 h proves its outstanding stability. high inherent attributed 3D porous structure, synergistic effects Ni, Co active components doping, selenization. results provide insightful reference further improving composition structure design while investigating metal electrocatalysts.

Language: Английский

Citations

0

Catalyst‐Anchored 3D Framework Electrodes: A Breakthrough in Large‐Scale Hydrogen Production DOI Creative Commons

Samruddhi V. Chauhan,

Kinjal K. Joshi,

Pratik M. Pataniya

et al.

Particle & Particle Systems Characterization, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 20, 2025

Abstract The idea of grid‐scale hydrogen production by water electrolysis has been made possible developing catalyst‐anchored three‐dimensional (3D) foam‐based electrodes. Catalytic performance in and oxygen evolution reactions is improved incorporating catalyst 3D interlinked porous architecture, which enhances electrical conductivity speeds up the discharge gas bubbles. detailed study on role‐play frameworks energy generation explained this article. review also focuses recent development utilizing these substrates field electrochemistry. Furthermore, it imperative to enhance their compatibility with renewable systems high‐temperature for sustainable hydrogen. Therefore, briefly explores innovative design self‐supported framework electrodes using heterostructures doping techniques develop stable, durable, efficient electrocatalysts. These catalysts aim provide near‐zero overpotential, high selectivity, long‐term stability through electrolysis, paving way commercial‐scale green production. can emerge as a key technology

Language: Английский

Citations

0

Metal nitrides vs. metal carbides: a comparative analysis of catalysts for the hydrogen evolution reaction DOI
Yuping Yang, Abdulrahman T. Ahmed,

Pinank Patel

et al.

Brazilian Journal of Chemical Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: March 25, 2025

Language: Английский

Citations

0

Advancements in non-renewable and hybrid hydrogen production: Technological innovations for efficiency and carbon reduction DOI Creative Commons
Vahid Madadi Avargani, Sohrab Zendehboudi, Xili Duan

et al.

Fuel, Journal Year: 2025, Volume and Issue: 395, P. 135065 - 135065

Published: March 30, 2025

Language: Английский

Citations

0

Covalent organic framework-derived C@COF core-shell microspheres for electrocatalytic hydrogen evolution DOI

Zhanpeng Xu,

Xiang Li,

Linlin Zang

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 89, P. 443 - 452

Published: Sept. 29, 2024

Language: Английский

Citations

2

Bioinspired octanuclear copper cubane complex as an efficient molecular electrocatalyst for water oxidation DOI

Xiangming Liang,

Ni Zhao,

Pei Wang

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 83, P. 1385 - 1391

Published: Aug. 18, 2024

Language: Английский

Citations

1

Nickel–Molybdenum-Based Three-Dimensional Nanoarrays for Oxygen Evolution Reaction in Water Splitting DOI Creative Commons

Zhi Lu,

Shilin Li,

Yuxin Wang

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(16), P. 3966 - 3966

Published: Aug. 22, 2024

Water splitting is an important approach to hydrogen production. But the efficiency of process always controlled by oxygen evolution reaction process. In this study, a three-dimensional nickel–molybdenum binary nanoarray microstructure electrocatalyst successfully synthesized. It grown uniformly on Ni foam using hydrothermal method. Attributed their unique nanostructure and controllable nature, Ni-Mo-based samples show superior reactivity durability in reactions. The series electrocatalysts presents competitive overpotential 296 mV at 10 mA·cm−2 for OER 1.0 M KOH, corresponding with low Tafel slope 121 dec−1. has large double-layer capacitance plenty channels ion transfer, which demonstrates more active sites improved charge transmission. This study provides valuable reference development non-precious catalysts water splitting.

Language: Английский

Citations

1

NiP/Fe3P/MoP@NF nanoblocks as a bifunctional electrocatalyst for water splitting in alkaline seawater and urea solution DOI
Xiang Zhao, Xiaoqiang Du, Xiaoshuang Zhang

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 176794 - 176794

Published: Sept. 1, 2024

Language: Английский

Citations

1