Hydrogen storage state in clay mineral nanopores: A molecular dynamics simulation study
International Journal of Hydrogen Energy,
Journal Year:
2025,
Volume and Issue:
105, P. 1491 - 1502
Published: Feb. 5, 2025
Language: Английский
Adsorption-Induced Deformation in Microporous Kerogen by Hydrogen and Methane: Implications for Underground Hydrogen Storage
Langmuir,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 2, 2025
Accurately
assessing
the
adsorption
and
diffusion
behaviors
of
H2,
CH4,
their
mixtures
are
essential
for
estimating
underground
hydrogen
storage
(UHS).
This
understanding
is
critical
safe
efficient
H2
in
depleted
shale
gas
reservoirs.
Although
kerogen
has
been
extensively
studied,
adsorption-induced
swelling
remains
unexplored
UHS.
In
this
study,
we
investigate
mechanisms
using
Lagrangian
Eulerian
approaches
analyze
through
molecular
simulations.
Our
results
reveal
that
presence
cushion
gases
like
which
exhibit
stronger
than
neglecting
deformation
can
lead
to
an
underestimation
capacity
by
approximately
40%.
Furthermore,
increasing
pressure
makes
behavior
deviate
from
consistent
trend
observed
with
either
or
contracting
depending
on
pore
size.
Simulations
also
predict
self-diffusion
coefficient
porous
1
order
magnitude
higher
CH4.
These
findings
highlight
importance
incorporating
flexibility
into
modeling
UHS
involving
multiple
species
improve
accuracy
safety
operations
Language: Английский
Hydrogen storage potential of coal: influence of coal on pore structure and adsorption mechanisms
Liru Tao,
No information about this author
Yiwen Ju
No information about this author
Frontiers in Earth Science,
Journal Year:
2025,
Volume and Issue:
13
Published: April 15, 2025
The
development
of
clean
energy
is
crucial
for
the
transition
to
a
low-carbon
economy,
and
hydrogen,
with
its
high
density
environmental
friendliness,
has
become
increasingly
important.
Coal,
as
porous
medium,
provides
possible
site
underground
storage
hydrogen.
structural
evolution
coal
during
coalification
significantly
influences
hydrogen
adsorption
capabilities
within
nanopores,
yet
comprehensive
studies
evaluating
potential
in
coals
different
ranks
(low,
high)
remain
limited.
Our
study
innovatively
addresses
this
research
gap
by
investigating
low-,
medium-,
high-rank
seams,
focusing
particularly
on
how
molecular
structure
affects
pore
mechanisms.
Coal
samples
representing
various
were
collected
from
basins
China.
Multiple
experimental
techniques,
including
CO
2
low-temperature
N
adsorption,
isotherms,
XRD,
HRTEM
analyses,
employed
characterize
structures
properties
comprehensively.
Results
indicate
that
rich
nanopores.
correlation
microporous
characteristics,
which
determines
capacity.
With
increase
rank,
capacity
showed
an
obvious
four-stage
pattern.
High-rank
strong
capacity,
faster
rate
lower
retention
after
desorption,
more
suitable
storage.
These
findings
enhance
fundamental
understanding
coal-hydrogen
interactions
provide
guidelines
selecting
optimal
geological
reservoirs
Language: Английский
Experimental study on isothermal adsorption and desorption characteristics and influencing factors of transitional facies shale gas
Scientific Reports,
Journal Year:
2025,
Volume and Issue:
15(1)
Published: April 24, 2025
Methane
adsorption
and
desorption
are
important
for
shale
gas
storage
production,
but
the
effects
of
shale,
temperature,
pressure,
water
content
not
fully
understood.
This
study
looks
at
methane
in
reservoirs
under
different
conditions.
It
highlights
how
molecules
compete
sites,
reducing
capacity.
A
new
ternary
Langmuir
model
is
introduced,
which
better
describes
behavior
than
traditional
model.
The
results
show
that
increases
with
pressure
decreases
reduces
further.
There
also
a
linear
relationship
between
volume
(VL)
(PL)
temperature
changes.
shows
usefulness
predicting
provides
useful
insights
resource
development.
Language: Английский