Published: Jan. 1, 2024
Language: Английский
Published: Jan. 1, 2024
Language: Английский
Applied Organometallic Chemistry, Journal Year: 2025, Volume and Issue: 39(3)
Published: Feb. 5, 2025
ABSTRACT Two novel multifunctional complexes [M(CCAM) 2 (NO 3 )](NO ) ·C H 5 OH (M = Dy (III)/Er (III); CCAM 2‐cyano‐ N ′‐((4‐oxo‐4H‐chromen‐3‐yl)methylene)acetohydrazide) were synthesized and characterized via elemental thermal analyses, molar conductivity, UV–vis., FT‐IR spectroscopy, revealing a 1:2 metal‐to‐ligand stoichiometry. The ligand coordinated with Dy(III) or Er(III) ions through nitrogen of azomethine oxygen the carbonyl γ‐pyran groups. Corrosion inhibition studies for Dy(CCAM), Er(CCAM), on carbon steel (C‐steel) in 1‐M HCl showed Dy(CCAM) Er(CCAM) as highly efficient, offering best protection. In solution, Fe 2+ at C‐steel surface interacts CCAM, compounds, demonstrated by UV–vis spectroscopy. At concentration 10 −3 M, compounds greater performance efficiency weight loss test reaching 93.34% 95.67%, respectively. Langmuir adsorption isotherm pronounced mixed mechanisms. characteristics SEM, EDX, AFM, contact angle measurements confirmed shielding. vitro antibacterial antifungal activity prepared against organisms, including Escherichia coli , Pseudomonas aeruginosa Staphylococcus aureus Bacillus subtilis bacteria, C andida albicans A spergillus fumigatus fungi is carried out. inhibitor exhibits greatest action different tested antimicrobials. Additionally, cytotoxicity produced growth inhibitory effects Erlish Acities Carcinoma was ascertained. found to have cytotoxic levels (IC 50 64 65 μM), As result, more effective therapeutic approach creation antimicrobial antitumor agents. For superior corrosion protection, theoretical molecular docking DFT MD simulations validated experimental results.
Language: Английский
Citations
1Technologies, Journal Year: 2025, Volume and Issue: 13(3), P. 103 - 103
Published: March 5, 2025
This review examines recent advances in corrosion inhibitor technologies, with a focus on sustainable and environmentally friendly solutions that address both industrial efficiency environmental safety. Corrosion is ubiquitous problem, contributing to massive economic losses globally, costs estimated between 1 5% of GDP different countries. Traditional inorganic inhibitors, while effective, are often based toxic compounds, necessitating the development more non-toxic alternatives. The present work highlights innovative eco-friendly inhibitors derived from natural sources, including plant extracts oils, biopolymers, etc., being biodegradable substances provide effective resistance minimal impact. In addition, this explores organic–inorganic hybrid nanotechnology-enhanced coatings demonstrate improved efficiency, durability, adaptability across industries. Key considerations, such as application techniques, mechanisms action, impact factors performance, discussed. comprehensive presentation aims contribute updating data advanced capable meeting requirements modern industries promoting safe practices management.
Language: Английский
Citations
1Results in Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 104504 - 104504
Published: Feb. 1, 2025
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: 1026, P. 180393 - 180393
Published: April 22, 2025
Language: Английский
Citations
0Industrial Crops and Products, Journal Year: 2024, Volume and Issue: 223, P. 120306 - 120306
Published: Dec. 18, 2024
Language: Английский
Citations
1Published: Jan. 1, 2024
Language: Английский
Citations
0