RSC Advances,
Journal Year:
2025,
Volume and Issue:
15(9), P. 7050 - 7068
Published: Jan. 1, 2025
This
study
investigates
the
use
of
bean
husks
as
a
precursor
for
synthesis
an
efficient
and
regenerable
catalyst,
with
aim
offering
economical
sustainable
alternative
biodiesel
production.
Residual
shell
biomass
(RBBH)
was
calcined
at
different
temperatures
(350-500
°C)
times
(1-4
h)
to
determine
optimum
conditions.
The
catalyst
obtained
characterized
by
various
methods,
such
X-ray
Diffraction
(XRD),
Fourier
Transform
Infrared
Spectroscopy
(FT-IR),
Scanning
Electron
Microscopy
(SEM),
Energy
Dispersive
(EDS)
Thermogravimetric
Analysis
(TG/DTG).
results
showed
that
contains
metal
oxides
carbonates
active
sites.
In
addition,
influence
reaction
conditions
evaluated
in
ranges
temperature
(60-120
°C),
time
(0.5-2.5
h),
MeOH
:
oil
molar
ratio
(12
1-28
1)
concentration
(2-10%
weight).
maximum
ester
content
(97.6%)
achieved
120
°C,
2
h,
20
1
8%
catalyst.
After
partial
deactivation
solid
it
regenerated
KOH,
yielding
biodiesels
over
75%
three
consecutive
cycles,
demonstrating
its
efficiency
potential
continuous
use.
RSC Advances,
Journal Year:
2025,
Volume and Issue:
15(9), P. 7050 - 7068
Published: Jan. 1, 2025
This
study
investigates
the
use
of
bean
husks
as
a
precursor
for
synthesis
an
efficient
and
regenerable
catalyst,
with
aim
offering
economical
sustainable
alternative
biodiesel
production.
Residual
shell
biomass
(RBBH)
was
calcined
at
different
temperatures
(350-500
°C)
times
(1-4
h)
to
determine
optimum
conditions.
The
catalyst
obtained
characterized
by
various
methods,
such
X-ray
Diffraction
(XRD),
Fourier
Transform
Infrared
Spectroscopy
(FT-IR),
Scanning
Electron
Microscopy
(SEM),
Energy
Dispersive
(EDS)
Thermogravimetric
Analysis
(TG/DTG).
results
showed
that
contains
metal
oxides
carbonates
active
sites.
In
addition,
influence
reaction
conditions
evaluated
in
ranges
temperature
(60-120
°C),
time
(0.5-2.5
h),
MeOH
:
oil
molar
ratio
(12
1-28
1)
concentration
(2-10%
weight).
maximum
ester
content
(97.6%)
achieved
120
°C,
2
h,
20
1
8%
catalyst.
After
partial
deactivation
solid
it
regenerated
KOH,
yielding
biodiesels
over
75%
three
consecutive
cycles,
demonstrating
its
efficiency
potential
continuous
use.