Chimica Techno Acta,
Journal Year:
2024,
Volume and Issue:
11(4)
Published: Nov. 22, 2024
Low
biodegradability
of
several
dyes
leads
to
their
accumulation
in
water,
causing
ecological
and
health
damage.
The
adsorption
and,
particular,
biosorption
processes
are
widely
applied
for
the
wastewater
treatment.
This
article
presents
first
comparative
study
Allura
red
dye
removal
under
neutral
pH
at
25
oC
applying
novel
biosorbents:
carboxyethyl
chitosan
hydrogel
(CEC)
cryogel
cross-linked
with
butanediol-1,4
diglycidyl
ether
(DEB-CEC).
gels
were
synthesized
“green”
manner,
characterization
revealed
porous
structure
high
swelling
both
biopolymer
compositions,
which
properties
important
adsorption.
kinetic
studies
demonstrated
that
rate
DEB-CEC
is
better
represented
by
pseudo-second-order,
while
CEC
followed
pseudo-first-order
kinetics.
isotherm
Red
suited
Temkin
model
samples,
maximum
capacity
22.523
mg/g
(45.4
μmol/g)
10.482
(21.1
DEB-CEC,
respectively.
results
polymers
can
be
used
as
biodegradable
eco-friendly
biosorbents
from
aqueous
solutions,
making
these
promising
treatment
prevention
azo-dye
environmental
pollution.
International Journal of Scientific Research in Chemistry,
Journal Year:
2024,
Volume and Issue:
9(4), P. 11 - 18
Published: Aug. 18, 2024
Nigella
sativa
is
a
herb
that
has
been
used
for
centuries
to
treat
various
ailments,
including
infectious
diseases.
The
aim
of
this
work
was
show
in
laboratory
conditions
the
influence
different
temperature
regimes
and
methods
storage
Sativa
oils
on
their
physicochemical
properties
microbiological
stability.
Analyzes
have
established
method
significant
change
quality
oil,
especially
when
it
comes
total
acidity
oil
peroxide
value,
where
values
increased
with
time
storage.
lowest
obtained
value
number
at
first
measurement,
Pb
=
9.99,
which
meets
prescribed
standards
safe
use,
then
highest
34.47
sample
constantly
exposed
sun
bright
bottle.
Also,
iodine
time,
14.56,
102.48.
Therefore,
extremely
important
stored
suitable
packaging
dark
glass
bottles,
protected
from
direct
sunlight
high
temperatures.
Journal of Composites Science,
Journal Year:
2024,
Volume and Issue:
8(10), P. 402 - 402
Published: Oct. 3, 2024
Purifying
polluted
water
is
becoming
a
crucial
concern
to
meet
quantity
and
quality
demands
as
well
ensure
the
resource’s
sustainability.
In
this
study,
new
material
was
prepared
from
cherry
stone
powder
sodium
alginate,
its
capacity
remove
methylene
blue
(MB)
determined.
The
characterization
of
resulting
product,
performed
via
scanning
electron
microscopy
(SEM)
Fourier-transform
infrared
spectroscopy
(FTIR),
revealed
that
raw
considered
for
synthesis
successfully
embedded
in
polymeric
matrix.
impact
three
main
working
parameters
(pH
3–9,
adsorbent
dose
50–150
g/L,
contact
time
60–180
min)
on
retention
MB
evaluated
through
response
surface
methodology
with
Box–Behnken
design.
optimal
settings,
removal
efficiency
80.46%
maximum
sorption
0.3552
mg/g
were
recorded.
followed
pseudo-second-order
kinetic
suitably
described
by
Freundlich,
Khan,
Redlich–Peterson,
Sips
isotherm
models.
experimental
results
show
synthesized
composite
can
be
used
at
least
successive
cycles
adsorption.
From
these
findings,
it
concluded
use
cherry-stone-based
environmentally
friendly,
efficacious
contaminants
environment.
Chimica Techno Acta,
Journal Year:
2024,
Volume and Issue:
11(4)
Published: Nov. 22, 2024
Low
biodegradability
of
several
dyes
leads
to
their
accumulation
in
water,
causing
ecological
and
health
damage.
The
adsorption
and,
particular,
biosorption
processes
are
widely
applied
for
the
wastewater
treatment.
This
article
presents
first
comparative
study
Allura
red
dye
removal
under
neutral
pH
at
25
oC
applying
novel
biosorbents:
carboxyethyl
chitosan
hydrogel
(CEC)
cryogel
cross-linked
with
butanediol-1,4
diglycidyl
ether
(DEB-CEC).
gels
were
synthesized
“green”
manner,
characterization
revealed
porous
structure
high
swelling
both
biopolymer
compositions,
which
properties
important
adsorption.
kinetic
studies
demonstrated
that
rate
DEB-CEC
is
better
represented
by
pseudo-second-order,
while
CEC
followed
pseudo-first-order
kinetics.
isotherm
Red
suited
Temkin
model
samples,
maximum
capacity
22.523
mg/g
(45.4
μmol/g)
10.482
(21.1
DEB-CEC,
respectively.
results
polymers
can
be
used
as
biodegradable
eco-friendly
biosorbents
from
aqueous
solutions,
making
these
promising
treatment
prevention
azo-dye
environmental
pollution.