CrystEngComm,
Journal Year:
2024,
Volume and Issue:
26(45), P. 6486 - 6492
Published: Jan. 1, 2024
0D
indium
halide
[1-Me-Pipz]
2
[InCl
6
]Cl·H
O
exhibits
strong
broadband
yellow
emission
with
a
high
PLQY
of
52%.
This
crystal
also
demonstrated
excellent
structural
and
spectral
stability,
allowing
its
use
in
efficient
white
light-emitting
diodes.
Current Organic Chemistry,
Journal Year:
2024,
Volume and Issue:
29(2), P. 144 - 152
Published: Aug. 15, 2024
:
Organo-modified
carbon
nanotubes
have
recently
gained
the
interest
of
many
research
groups.
The
potential
for
applying
a
new
generation
organo-modified
in
technological
fields
reveals
importance
covalent
modifications
on
nanotubes.
In
this
study,
using
microwave
synthesis
method,
multi-walled
nanotube
(MWCNT)
thiophenol
derivatives
were
obtained
with
thioesterification
reaction.
For
purpose,
MWCNT-COOH
was
from
MWCNT
by
oxidation,
and
MWCNT-COCl
synthesized
MWCNT-COOH.
MWCNT-CO-S-
(ortho/meta/para-methyl/methoxy-phenyl)
(MA1-MA6)
compounds
through
both
methods
starting
Steglich
ester
reaction
Products
characterized
Fourier
Transform-
Infrared
Spectroscopy
(FTIR),
Nuclear
Magnetic
Resonance
(NMR),
Thermogravimetric
Analysis
(TGA),
Transmission
Electron
(TEM)
methods.
Furthermore,
step
numbers,
times,
temperatures
molecules,
MA1-MA6,
compared.
esterification
found
to
be
most
effective
technique
creating
these
compounds.
photoluminescent
characteristics
MWCNT,
MWCNT-COOH,
MA1-MA6
examined.
intensity
photoluminescence
(PL)
vary
location
functional
group.
It
detected
that
MA2
compound
had
highest
(6.9x102
a.u.),
while
MA1
secondhighest
a.u.).
radiated
at
low
wavelengths
475-
490
nm
high
PL
values.
Possible
transitions
n→π*
transitions,
values
because
oxygen
atom
methoxy
is
expected
materials
will
find
use
imaging
devices
operating
temperatures,
particularly
structures
containing
groups
exhibit
favourable
properties.
CrystEngComm,
Journal Year:
2024,
Volume and Issue:
26(45), P. 6486 - 6492
Published: Jan. 1, 2024
0D
indium
halide
[1-Me-Pipz]
2
[InCl
6
]Cl·H
O
exhibits
strong
broadband
yellow
emission
with
a
high
PLQY
of
52%.
This
crystal
also
demonstrated
excellent
structural
and
spectral
stability,
allowing
its
use
in
efficient
white
light-emitting
diodes.