The role of ionomers in the electrolyte management of zero-gap MEA-based CO2 electrolysers: A Fumion vs. Nafion comparison DOI Creative Commons
Menglong Liu, Huifang Hu, Ying Kong

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 335, P. 122885 - 122885

Published: May 16, 2023

We study the role of binders (ionomers) in determining life-span gas diffusion electrodes (GDEs) used for high throughput CO2-to-CO electrolysis. compare two typical ionomer materials (Nafion and Fumion, both are widely preparation Ag nanoparticles-based catalyst inks) to show that when zero-gap membrane/electrode assemblies, Fumion-containing inks superior Nafion-based ones can uphold a very CO-selectivity electrochemical CO2 reduction reaction longer time. This is due ability Fumion containing suppress precipitation inside GDE structure. As Fumion-fixed GDEs significantly less hydrophobic than Nafion-fixed ones, our results contradict accepted opinion it their non-wettability what mostly protects CO2-reducing from flooding. In turn, we argue more important maintain efficient electrolyte drainage pathways structure, explain superiority on this basis.

Language: Английский

Applications of Metal–Organic Frameworks and Their Derivatives in Electrochemical CO2 Reduction DOI Creative Commons
Chengbo Li,

Yuan Ji,

Youpeng Wang

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 15(1)

Published: April 30, 2023

Abstract Electrochemically reducing CO 2 to more reduced chemical species is a promising way that not only enables the conversion of intermittent energy resources stable fuels, but also helps build closed-loop anthropogenic carbon cycle. Among various electrocatalysts for electrochemical reduction, multifunctional metal–organic frameworks (MOFs) have been employed as highly efficient and selective heterogeneous due their ultrahigh porosity topologically diverse structures. Up now, great progress has achieved in design synthesis active MOF-related catalysts reduction reaction (CO RR), corresponding mechanisms thoroughly studied. In this review, we summarize recent applying MOFs derivatives RR, with focus on strategies electrolyzers. We first discussed different RR products introduced commonly applied electrolyzer configurations current system. Then, an overview several categories (CO, HCOOH, CH 4 , 3 OH, multi-carbon chemicals) generated from or via was discussed. Finally, offer some insights perspectives future development reduction. aim provide new into field further guide research large-scale applications.

Language: Английский

Citations

78
Electrochemical CO2 reduction coupled with alternative oxidation reactions: Electrocatalysts, electrolytes, and electrolyzers DOI

Wanlong Xi,

Yang Peng,

Mingkun Jiang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 341, P. 123291 - 123291

Published: Sept. 16, 2023

Language: Английский

Citations

48
Materials challenges on the path to gigatonne CO2 electrolysis DOI
Blanca Belsa, Lu Xia, Viktoria Golovanova

et al.

Nature Reviews Materials, Journal Year: 2024, Volume and Issue: 9(8), P. 535 - 549

Published: June 24, 2024

Language: Английский

Citations

23
Integrated carbon capture and CO production from bicarbonates through bipolar membrane electrolysis DOI Creative Commons
Hakhyeon Song, Carlos A. Fernández, Hyeonuk Choi

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(10), P. 3570 - 3579

Published: Jan. 1, 2024

Bicarbonate electrolysis with integrated carbon capture (BE-ICC) enables direct conversion of a solution.

Language: Английский

Citations

18
Developing electrochemical hydrogenation towards industrial application DOI
Julian T. Kleinhaus, Jonas Wolf, Kevinjeorjios Pellumbi

et al.

Chemical Society Reviews, Journal Year: 2023, Volume and Issue: 52(21), P. 7305 - 7332

Published: Jan. 1, 2023

Electrochemical hydrogenation reactions hold the promise of more sustainable production routes for towards bulk and fine chemicals. Their broad applicability, reactor concepts, achieved milestones future perspectives are described herein.

Language: Английский

Citations

41
Electrode and cell design for CO2 reduction: A viewpoint DOI Creative Commons
Claudio Ampelli,

Francesco Tavella,

Daniele Giusi

et al.

Catalysis Today, Journal Year: 2023, Volume and Issue: 421, P. 114217 - 114217

Published: May 18, 2023

The electrocatalytic reduction of carbon dioxide (CO2RR) is a crucial technology to develop the decarbonisation strategy for circularity and producing solar fuels substituting fossil fuels. This viewpoint discusses role electrode reactor design as main factor in determining performance CO2RR, at least under reaction conditions relevant industrial scalability, evidencing need overturn current strategic vision focused more on improving characteristics materials. Many parameters characterising performances (such Faradaic efficiency, selectivity potential onset, besides density) are strongly influenced typically dominated (under conditions) by effective population adspecies surface, which is, turn, related mass control transport resistances, local pH changes, multiphase boundaries, wettability other aspects. Even preliminary screening catalysts could be incorrect, not operating representative conditions, thus without properly choosing reactor. Advanced electrode/reactor designs, e.g., based gas-diffusion electrodes (GDEs) that avoid having liquid electrolyte (zero-gap design), necessary improve CO2RR scalability applications. situ catalyst nanoparticle reconstruction may depend these Electrochemical characterization methods like electrochemical impedance spectroscopy (EIS) right approach study reactions, providing indications controlling elements determine electrocatalyst/electrode performances.

Language: Английский

Citations

32
Electrochemical CO2reduction with ionic liquids: review and evaluation DOI Creative Commons
Yangshuo Li, Fangfang Li, Aatto Laaksonen

et al.

Industrial Chemistry and Materials, Journal Year: 2023, Volume and Issue: 1(3), P. 410 - 430

Published: Jan. 1, 2023

Evaluation for electrochemical CO 2 reduction to C1 with Ionic liquids.

Language: Английский

Citations

31
Recent Progress in Surface-Defect Engineering Strategies for Electrocatalysts toward Electrochemical CO2 Reduction: A Review DOI Open Access
Sridharan Balu, Abdul Hanan, Harikrishnan Venkatesvaran

et al.

Catalysts, Journal Year: 2023, Volume and Issue: 13(2), P. 393 - 393

Published: Feb. 11, 2023

Climate change, caused by greenhouse gas emissions, is one of the biggest threats to world. As per IEA report 2021, global CO2 emissions amounted around 31.5 Gt, which increased atmospheric concentration up 412.5 ppm. Thus, there an imperative demand for development new technologies convert into value-added feedstock products such as alcohols, hydrocarbons, carbon monoxide, chemicals, and clean fuels. The intrinsic properties catalytic materials are main factors influencing efficiency electrochemical reduction (CO2-RR) reactions. Additionally, electroreduction mainly affected poor selectivity large overpotential requirements. However, these issues can be overcome modifying heterogeneous electrocatalysts control their morphology, size, crystal facets, grain boundaries, surface defects/vacancies. This article reviews recent progress in reactions accomplished surface-defective identifies significant research gaps designing highly efficient electrocatalytic materials.

Language: Английский

Citations

31
Recent Advances in Electrochemical CO2‐to‐Multicarbon Conversion: From Fundamentals to Industrialization DOI
Changli Wang,

Zunhang Lv,

Xiao Feng

et al.

Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 13(47)

Published: Nov. 2, 2023

Abstract The electrochemical CO 2 (eCO )‐to‐multicarbon conversion with higher value is regarded as a potential way to promote the transformation of industrial production and green balance carbon cycle. Recently, series advances have been achieved in progress eCO ‐to‐multicarbon conversion, including in‐depth exploration coupling mechanisms, up‐to‐date development characterization techniques, novel interdisciplinary design strategies catalysts electrolytic systems. Therefore, it essential systematically overview from fundamentals industrialization, compensating for limited insufficient reviews that reported. To fill aforementioned research gap, this focused on industrialization. First, possible catalytic mechanisms are accordingly summarized order reduction, small molecule‐coupled tandem conversion. Second, situ technologies assisting rationalization presented. Third, optimizing systems briefly classified advance industrialization process. Finally, challenges perspectives further reasonably proposed, aiming offer insights following work field.

Language: Английский

Citations

31
Advances and challenges in membrane electrode assembly electrolyzers for CO2 reduction DOI
Qingqing Ye,

Xueyang Zhao,

Ruiben Jin

et al.

Journal of Materials Chemistry A, Journal Year: 2023, Volume and Issue: 11(40), P. 21498 - 21515

Published: Jan. 1, 2023

This review emphasizes the fundamentals of MEA construction, different technical routes, and remaining challenges opportunities for large-scale electrochemical CO 2 reduction applications.

Language: Английский

Citations

25