Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1010, P. 177172 - 177172
Published: Oct. 21, 2024
Language: Английский
Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1010, P. 177172 - 177172
Published: Oct. 21, 2024
Language: Английский
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 22, 2024
Abstract Lithium–sulfur batteries (LSBs), renowned for their superior energy density and the plentiful availability of sulfur resources, are progressively emerging as focal point forthcoming storage technology. Nevertheless, they presently confront fundamental challenges including insulation its discharge product, lithium polysulfides (LiPSs) shuttle phenomenon, growth dendrites. Zeolite imidazole framework materials (ZIFs), particularly ZIF‐8 ZIF‐67, significant members metal–organic frameworks (MOFs) family. Owing to high porosity, exceptional adsorption capacity, structural tunability, straightforward synthesis process, these have demonstrated unique application potential in field LSBs. This review initially provides a comprehensive summary developmental status associated with Subsequently, it delves into an in‐depth analysis distinctive properties strategies ZIFs, particular emphasis on well composites derivatives. The systematically categorizes innovative examples design cathode structures optimization separators It also presents forward‐looking perspective insights future trajectory ZIF‐67 materials, informed by latest research advancements field.
Language: Английский
Citations
11Electrochimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 145831 - 145831
Published: Feb. 1, 2025
Language: Английский
Citations
1Published: Jan. 1, 2025
Li-S batteries are potentially interesting alternatives for green energy applications due to their high density and low cost. Nonetheless, present practical application falls short of theoretical predictions, despite efforts address volumetric expansion enhance electrical conductance through porous sulfur-hosting scaffolds. The performance is mainly restricted by the poor electrochemical reaction kinetics lithium polysulfides (LiPS), which convert into sulfide (Li2S) elemental sulfur (S) during charge-discharge cycles. Single-atom catalysts (SACs) offer novel opportunities addressing complex challenges effective in atomic-resolution characterization intermediates as well precise atomic-level engineering. Inspired single-atom catalysis approach, we designed an innovative electrocatalyst including FeN4 active sites anchored 2D borophene nanosheets. significant electronic coupling between Fe 3d S 2p orbitals promotes charge transfer improves redox dynamics polysulfide intermediates. Moreover, unique properties borophene, its mass density, superior conductivity, rapid Li-ion transport, robust binding with polysulfides, render it a promising choice battery materials. synergistic effect adsorption improved kinetics, enabled configuration three-dimensional architecture FeN4/borophene (Fe@BNS), results outstanding batteries. fabricated cells exhibit exceptional long-term cycle life (1180 mAh g−1 at 1 C 1000 cycles) high-rate (790.3 C) loading 6.5 mg cm−2.
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159406 - 159406
Published: Jan. 1, 2025
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: 1014, P. 178765 - 178765
Published: Jan. 20, 2025
Language: Английский
Citations
0Journal of Power Sources, Journal Year: 2025, Volume and Issue: 644, P. 237097 - 237097
Published: April 23, 2025
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 176639 - 176639
Published: Sept. 1, 2024
Language: Английский
Citations
2Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1010, P. 177511 - 177511
Published: Nov. 12, 2024
Language: Английский
Citations
2Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1010, P. 177172 - 177172
Published: Oct. 21, 2024
Language: Английский
Citations
0