Modulating the acidity of bimetallic functionalized Zr-based metal–organic frameworks with hierarchical porosity through solvent-free approach to enhance butyl butyrate production DOI
Gan Ye, Xinying Liu, Guangming Shi

et al.

Fuel, Journal Year: 2024, Volume and Issue: 381, P. 133609 - 133609

Published: Nov. 5, 2024

Language: Английский

Synthesis and Characterization of Faujasite/ZIF-8 Composite by One-Pot Method, Used as a Catalyst for Esterification and Aldol Condensation Reaction DOI

Hadis Ghaedrahmat,

Mohammad Yaser Masoomi, Mojgan Zendehdel

et al.

Catalysis Surveys from Asia, Journal Year: 2023, Volume and Issue: 28(1), P. 58 - 73

Published: Dec. 8, 2023

Language: Английский

Citations

6
Metal–organic frameworks-TiO2 as a recyclable photocatalyst for the synthesis of acetals/ketals DOI
Lu Chen,

Zhenyuan Lin,

Zilong Zhang

et al.

Journal of Catalysis, Journal Year: 2023, Volume and Issue: 428, P. 115181 - 115181

Published: Oct. 24, 2023

Language: Английский

Citations

5
DNA-Directed Assembly of Hierarchical MOF-Cellulose Nanofiber Microbioreactors with “Branch-Fruit” Structures DOI
Wanning Gao,

Youcong Li,

Xing Zhang

et al.

Nano Letters, Journal Year: 2024, Volume and Issue: 24(11), P. 3404 - 3412

Published: March 7, 2024

Assembling metal–organic frameworks (MOFs) into ordered multidimensional porous superstructures promises the encapsulation of enzymes for heterogeneous biocatalysts. However, full potential this approach has been limited by poor stability and uncontrolled assembly MOF nanoparticles onto suitable supports. In study, a novel exceptionally robust Ni-imidazole-based was synthesized in water at room temperature, enabling situ enzyme encapsulation. Based on platform, we developed DNA-directed strategy to achieve uniform placement bacterial cellulose nanofibers, resulting distinctive "branch-fruit" structure. The hybrid materials demonstrated remarkable versatility across various catalytic systems, accommodating natural enzymes, nanoenzymes, multienzyme cascades, thus showcasing enormous as universal microbioreactors. Furthermore, hierarchical composites facilitated rapid diffusion bulky substrate while maintaining stability, with ∼3.5-fold higher relative activity compared traditional enzyme@MOF immobilized nanofibers.

Language: Английский

Citations

1
Advances in chemical analysis: Microporous metal–organic frameworks as eco-friendly solutions for selective separations of (bio)molecules DOI
Jemmyson Romário de Jesus, Marcos Vinícius de Sousa Pereira,

Iare Soares Ribeiro

et al.

Microchemical Journal, Journal Year: 2024, Volume and Issue: 203, P. 110951 - 110951

Published: June 9, 2024

Language: Английский

Citations

0
Ti-based MOFs with acetic acid pendings as an efficient catalyst in the preparation of new spiropyrans with biological moieties DOI Creative Commons

Zahra Torkashvand,

Hassan Sepehrmansourie,

Mohammad Ali Zolfigol

et al.

Scientific Reports, Journal Year: 2024, Volume and Issue: 14(1)

Published: June 18, 2024

Abstract The strategy of designing heterogeneous porous catalysts by a post-modification method is smart to increase the catalytic power desired catalysts. Accordingly, in this report, metal-organic frameworks based on titanium with acetic acid pending were designed and synthesized via method. structure target catalyst has been investigated using different techniques such as FT-IR, XRD, SEM, EDX, Mapping, N 2 adsorption/desorption (BET/the BJH) correctness its formation proven. application Ti-based MOFs functionalized was evaluated preparation new spiropyrans, obtained results show that performance improved modification. through methods presents sophisticated approach enhancing efficacy In context, our study focuses synthesis characterization (MOFs) titanium, pendants, Various techniques, including Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive (EDX), mapping, (BET/BJH), employed investigate composition catalyst. These collectively confirmed successful structural integrity products melting point, 1 H-NMR 13 C-NMR FT-IR techniques. Examining general process shows mentioned modification very useful for purposes. presented used wide range biologically active spiropyrans good yields. simultaneous presence several cores will highlight biological properties these compounds. present offers promising insight into rational design, synthesis, task-specific catalysts, particularly context synthesizing candidate molecules.

Language: Английский

Citations

0
Modulating the acidity of bimetallic functionalized Zr-based metal–organic frameworks with hierarchical porosity through solvent-free approach to enhance butyl butyrate production DOI
Gan Ye, Xinying Liu, Guangming Shi

et al.

Fuel, Journal Year: 2024, Volume and Issue: 381, P. 133609 - 133609

Published: Nov. 5, 2024

Language: Английский

Citations

0