Fabricating Effective and Recyclable Cadmium‐based Coordination Polymer for Selective Synthesis of 1,5‐Benzodiazepines DOI
Li Chen, Jiahao Li, Likui Wang

et al.

Asian Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 12(12)

Published: Oct. 9, 2023

Abstract Metal coordination polymers are widely applied in the synthesis of heterocyclic compounds due to advantages highly dispersed metal active sites, low cost and strong designability. Herein, employing 9‐benzyl‐3,6‐di( 1H ‐pyrazol‐1‐yl)‐ 9H ‐carbazole (BPC) as a ligand, cadmium‐coordinated polymer compound (Cd‐BPC) was facilely prepared by solvothermal method characterized energy dispersive spectrometer (EDS), flourier‐transform infrared spectroscopy (FT‐IR), scanning electron microscope (SEM), transmission microscopy (TEM) X‐ray photoelectron spectrometry (XPS). Employing Cd‐BPC catalyst, 1,5‐benzodiazepine derivatives were produced with relatively high yields through reaction o ‐phenylenediamine ketones, alcohols. Additionally, could be reused for at least 5 times without significant decrease.

Language: Английский

Photo-induced oxidative esterification via aldehyde and alkyl halides using dimethyl carbonate as green solvent DOI

Huahui Wang,

Xiaotong Long,

Jiabin Chen

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: 1317, P. 139180 - 139180

Published: June 30, 2024

Language: Английский

Citations

2
Metal–organic frameworks-TiO2 as a recyclable photocatalyst for the synthesis of acetals/ketals DOI
Lu Chen,

Zhenyuan Lin,

Zilong Zhang

et al.

Journal of Catalysis, Journal Year: 2023, Volume and Issue: 428, P. 115181 - 115181

Published: Oct. 24, 2023

Language: Английский

Citations

5
Catalytic Aldehyde–Alkyne Couplings Triggered by Ketyl Radicals DOI Creative Commons

Zhi-Xi Xing,

Shu-sheng Chen, Huan‐Ming Huang

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(46), P. 9949 - 9954

Published: Nov. 8, 2024

A general and flexible platform for catalytic aldehyde-alkyne couplings triggered by ketyl radicals is described. This open-shell strategy necessitates only a quantity of photoredox catalyst, along with Hünig's base (DIPEA) as halogen atom transfer reagent. The reaction proceeds through sequential steps involving activation, transfer, radical addition. carbonyl-alkyne coupling exhibits wide substrate scope functional group compatibility has been successfully applied to the late-stage modification complex architectures.

Language: Английский

Citations

1
Highly Efficient Photocatalytic Divergent Decarbonylative Silylation with Cinnamaldehyde via a [Ru(dcbpy)(bpy)2]2+-Incorporated UiO-67 Framework DOI

Huahui Wang,

Bing-Bing Qin,

Jiali Cai

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 18542 - 18549

Published: Dec. 5, 2024

We herein develop an innovative approach for the decarbonylative silylation using a molecular [Ru(dcbpy)(bpy)2]2+ (dcbpy = 2,2′-bipyridyl-5,5′-dicarboxylic acid; bpy 2,2′-bipyridine) incorporated UiO-67 metal–organic framework (MOFs) (denoted as UiO-67-Ru) powerful heterogeneous catalyst, which is then applied in reaction of abundantly available cinnamaldehydes with silanes under photothermal condition. Mechanistic studies reveal that silane can be absorbed and activated within cavities framework, leading to generation silyl radical. The radical plays key role process further goes through oxidative generate corresponding alkenyl silanes. This work not only develops strategy preparation from highly abundant cinnamaldehyde but also affords useful inspiration on rational design MOFs materials silylation.

Language: Английский

Citations

1
Potassium xanthate-promoted reductive sulfuration reaction: from aldehydes to thiol, disulfide, and thioester derivatives DOI

Yingqi Feng,

Jinli Nie,

Sijie Xie

et al.

Chemical Communications, Journal Year: 2023, Volume and Issue: 60(9), P. 1140 - 1143

Published: Dec. 26, 2023

Herein, we developed a synthetic strategy for the direct construction of C-S bonds to obtain biologically active sulfur-containing compounds and methodology involving reductive sulfuration aldehydes or ketones diverse substituted thiol, disulfide, thioester derivatives. EtOCS

Language: Английский

Citations

3
Fabricating Effective and Recyclable Cadmium‐based Coordination Polymer for Selective Synthesis of 1,5‐Benzodiazepines DOI
Li Chen, Jiahao Li, Likui Wang

et al.

Asian Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 12(12)

Published: Oct. 9, 2023

Abstract Metal coordination polymers are widely applied in the synthesis of heterocyclic compounds due to advantages highly dispersed metal active sites, low cost and strong designability. Herein, employing 9‐benzyl‐3,6‐di( 1H ‐pyrazol‐1‐yl)‐ 9H ‐carbazole (BPC) as a ligand, cadmium‐coordinated polymer compound (Cd‐BPC) was facilely prepared by solvothermal method characterized energy dispersive spectrometer (EDS), flourier‐transform infrared spectroscopy (FT‐IR), scanning electron microscope (SEM), transmission microscopy (TEM) X‐ray photoelectron spectrometry (XPS). Employing Cd‐BPC catalyst, 1,5‐benzodiazepine derivatives were produced with relatively high yields through reaction o ‐phenylenediamine ketones, alcohols. Additionally, could be reused for at least 5 times without significant decrease.

Language: Английский

Citations

2