Developments in the Construction of Benzo[b]thiophenes from 2‐Alkynylthioanisoles by Electrophilic and Radical Cyclization Reactions DOI

Tianbo Shang,

Chao Ma, Mengyu Xie

et al.

European Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 1, 2024

Abstract Benzo[ b ]thiophene moieties are important skeletons which have been widely found in many natural products, pharmaceuticals, as well functionalized materials. 2‐Alkynylthioanisoles, a class of bifunctional compounds bearing methylthio and alkynyl groups, easily accessible from Pd‐catalyzed Sonogashira coupling between 2‐halothioanisoles terminal alkynes, employed synthons the construction benzo[b]thiophenes through an electrophilic or radical pathway. This review summarizes related developments with particular focus on reaction mechanism. We hope it will help future research this area believe that discovery new catalytic systems, industrial synthesis benzo[ ]thiophenes 2‐alkynylthioanisoles be achieved soon.

Language: Английский

Enhanced Hydrazine Electrooxidation Activities on Novel Benzofused Tricyclic Heterocyclic Derivatives DOI Creative Commons

Omrüye Ozok Arıcı,

Raffaella Mancuso, Bartolo Gabriele

et al.

ACS Omega, Journal Year: 2024, Volume and Issue: 9(39), P. 40644 - 40649

Published: Sept. 17, 2024

In this study, some benzofused tricyclic heterocyclic derivatives have been tested as possible new catalysts for anode hydrazine electrooxidation in a direct fuel cell (DHFC). Electrochemical studies were carried out solution media containing 1 M KOH and + 0.5 N

Language: Английский

Citations

0
Palladium Iodide Catalyzed Oxidative Carbonylations DOI Creative Commons
Bartolo Gabriele

Tetrahedron Chem, Journal Year: 2024, Volume and Issue: 12, P. 100107 - 100107

Published: Nov. 1, 2024

Language: Английский

Citations

0
Developments in the Construction of Benzo[b]thiophenes from 2‐Alkynylthioanisoles by Electrophilic and Radical Cyclization Reactions DOI

Tianbo Shang,

Chao Ma, Mengyu Xie

et al.

European Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 1, 2024

Abstract Benzo[ b ]thiophene moieties are important skeletons which have been widely found in many natural products, pharmaceuticals, as well functionalized materials. 2‐Alkynylthioanisoles, a class of bifunctional compounds bearing methylthio and alkynyl groups, easily accessible from Pd‐catalyzed Sonogashira coupling between 2‐halothioanisoles terminal alkynes, employed synthons the construction benzo[b]thiophenes through an electrophilic or radical pathway. This review summarizes related developments with particular focus on reaction mechanism. We hope it will help future research this area believe that discovery new catalytic systems, industrial synthesis benzo[ ]thiophenes 2‐alkynylthioanisoles be achieved soon.

Language: Английский

Citations

0