NiII, PdII and PtII pincer complexes of 2-(diphenylphosphaneyl)-N-(2-(diphenyl-phosphaneyl)benzyl)benzamide: synthesis, reactivity and catalytic studies DOI

K. Dwivedi,

Gazal Sabharwal,

Basvaraj S. Kote

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

This paper describes the synthesis of bis(phosphine), o -Ph 2 PC 6 H 4 C(O)N(H)CH C PPh - and its group 10 metal chemistry catalytic studies.

Language: Английский

Solvent-Free terminal alkyne hydrosilylation to β-(E)-vinylsilanes mediated by platinum(II) aminophosphine complexes DOI
Hanna Stachowiak, Marcin Gruszczyński, Grzegorz Hreczycho

et al.

Journal of Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 116027 - 116027

Published: Feb. 1, 2025

Language: Английский

Citations

0
Copper-driven formation of siloxanes via dehydrocoupling between hydrosilanes and silanols DOI Creative Commons
Martyna Markwitz, Kacper Łyczek, Qingqing Bu

et al.

Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(15), P. 4855 - 4866

Published: Jan. 1, 2024

Sustainable dehydrogenative coupling: silanols and hydrosilanes unite under Earth abundant copper catalysis with exceptional efficiency selectivity at room temperature.

Language: Английский

Citations

1
Streamlining Si-O Bond Formation Through Cobalt-Catalyzed Dehydrocoupling DOI
Ewelina Szafoni, Dariusz Lewandowski, Marcin Gruszczyński

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(78), P. 10886 - 10889

Published: Jan. 1, 2024

Herein we report a strategy for the synthesis of organosilicons, including siloxanes, silyl ethers, and aminosilanes,

Language: Английский

Citations

1
Catalytic Construction of C(sp3)‐Ge Bonds: Recent Advances and Future Perspectives DOI
Jia‐Lin Tu, Binbin Huang

Advanced Synthesis & Catalysis, Journal Year: 2024, Volume and Issue: 366(22), P. 4618 - 4633

Published: Oct. 16, 2024

Abstract Germanium (Ge), a congener of carbon, possesses unique properties that hold extensive potential for applications across multiple domains. Recent years have seen significant progress in the development carbon‐germanium bond formation strategies, particularly those more challenging C( sp 3 )−Ge bonds. This review systematically summarizes recent advances forming methodologies, with particular emphasis on (1) versatility transition‐metals, including iron, nickel, copper, rhodium and palladium, as catalysts broadening reaction scope controlling selectivity; (2) powerfulness organic photocatalysis achieving mild selective formation, (3) sustainability catalytic electrosynthesis facilitating chemical oxidant‐/reductant‐ free conversions. Additionally, examples (4) non‐catalytic strategies are also discussed. The representative scopes, well mechanistic proposals, these protocols highlighted. Through an overview current state research, this aims to offer insights into construction bonds, provide perspectives future research directions address challenges.

Language: Английский

Citations

1
NiII, PdII and PtII pincer complexes of 2-(diphenylphosphaneyl)-N-(2-(diphenyl-phosphaneyl)benzyl)benzamide: synthesis, reactivity and catalytic studies DOI

K. Dwivedi,

Gazal Sabharwal,

Basvaraj S. Kote

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

This paper describes the synthesis of bis(phosphine), o -Ph 2 PC 6 H 4 C(O)N(H)CH C PPh - and its group 10 metal chemistry catalytic studies.

Language: Английский

Citations

0