CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2024, Volume and Issue: 66, P. 152 - 167
Published: Nov. 1, 2024
Language: Английский
CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2024, Volume and Issue: 66, P. 152 - 167
Published: Nov. 1, 2024
Language: Английский
Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 100, P. 234 - 244
Published: Aug. 30, 2024
Language: Английский
Citations
9Molecular Catalysis, Journal Year: 2025, Volume and Issue: 575, P. 114912 - 114912
Published: Feb. 12, 2025
Language: Английский
Citations
0Small, Journal Year: 2025, Volume and Issue: unknown
Published: March 21, 2025
Achieving a precise understanding and accurate design of heterogeneous catalysts based on bioinspired principles is challenging yet crucial to digging out optimal materials for artificial catalysis. Here, an ADH-mimicking dual-site photocatalyst (YCuCdS) developed, demonstrates the powerful effects atomic site configuration proton transfer environments alcohol-amine coupling. Mechanism studies reveal that alcohol substrate effectively dehydrogenated at Y sites, forming carbonyl intermediates rapidly experience condensation with amine. Meanwhile, released hydrogen species (Hads) migrate from adjacent Cu sites active S atoms, promoting H2 production hindering over-hydrogenation imine. As result, high imine yield 92% achieved, along rate 7400 µmol g-1 h-1. This work showcases effective strategy bioinspiration.
Language: Английский
Citations
0Catalysis Today, Journal Year: 2024, Volume and Issue: 443, P. 114990 - 114990
Published: Aug. 12, 2024
Language: Английский
Citations
0CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2024, Volume and Issue: 66, P. 152 - 167
Published: Nov. 1, 2024
Language: Английский
Citations
0