Better Together: Photoredox/Copper Dual Catalysis in Atom Transfer Radical Polymerization DOI Creative Commons
Julian Sobieski, Adam Gorczyński, Arman Moini Jazani

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 29, 2024

Abstract Photomediated Atom Transfer Radical Polymerization (photoATRP) is an activator regeneration method, which allows for the controlled synthesis of well‐defined polymers via light irradiation. Traditional photoATRP often limited by need high‐energy ultraviolet or violet light. These could negatively affect control and selectivity polymerization, promote side reactions, may not be applicable to biologically relevant systems. This drawback can circumvented introduction catalytic amount photocatalysts, absorb visible and/or NIR and, therefore, controlled, regenerative ATRP performed with dual‐catalytic cycle. Herein, a critical summary recent developments in field dual‐catalysis concerning Cu‐catalyzed provided. Contributions involved species are examined mechanistically, followed challenges future directions towards next generation advanced functional macromolecular materials.

Language: Английский

Chloridion induced acid sites in covalent organic frameworks for 5‑hydroxymethylfurfural synthesis from fructose DOI

Biao Meng,

Xiaoling Liu, Fengming Chen

et al.

Journal of Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 115985 - 115985

Published: Jan. 1, 2025

Language: Английский

Citations

0
Better Together: Photoredox/Copper Dual Catalysis in Atom Transfer Radical Polymerization DOI Creative Commons
Julian Sobieski, Adam Gorczyński, Arman Moini Jazani

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 29, 2024

Abstract Photomediated Atom Transfer Radical Polymerization (photoATRP) is an activator regeneration method, which allows for the controlled synthesis of well‐defined polymers via light irradiation. Traditional photoATRP often limited by need high‐energy ultraviolet or violet light. These could negatively affect control and selectivity polymerization, promote side reactions, may not be applicable to biologically relevant systems. This drawback can circumvented introduction catalytic amount photocatalysts, absorb visible and/or NIR and, therefore, controlled, regenerative ATRP performed with dual‐catalytic cycle. Herein, a critical summary recent developments in field dual‐catalysis concerning Cu‐catalyzed provided. Contributions involved species are examined mechanistically, followed challenges future directions towards next generation advanced functional macromolecular materials.

Language: Английский

Citations

1
Better Together: Photoredox/Copper Dual Catalysis in Atom Transfer Radical Polymerization DOI Creative Commons
Julian Sobieski, Adam Gorczyński, Arman Moini Jazani

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 29, 2024

Abstract Photomediated Atom Transfer Radical Polymerization (photoATRP) is an activator regeneration method, which allows for the controlled synthesis of well‐defined polymers via light irradiation. Traditional photoATRP often limited by need high‐energy ultraviolet or violet light. These could negatively affect control and selectivity polymerization, promote side reactions, may not be applicable to biologically relevant systems. This drawback can circumvented introduction catalytic amount photocatalysts, absorb visible and/or NIR and, therefore, controlled, regenerative ATRP performed with dual‐catalytic cycle. Herein, a critical summary recent developments in field dual‐catalysis concerning Cu‐catalyzed provided. Contributions involved species are examined mechanistically, followed challenges future directions towards next generation advanced functional macromolecular materials.

Language: Английский

Citations

0