Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 654, P. 785 - 794
Published: Oct. 19, 2023
Language: Английский
Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 654, P. 785 - 794
Published: Oct. 19, 2023
Language: Английский
Materials Horizons, Journal Year: 2023, Volume and Issue: 10(11), P. 5277 - 5287
Published: Jan. 1, 2023
The hydrazine oxidation reaction (HzOR) is considered as a promising alternative process of the oxygen evolution (OER) to realize more energy-efficient hydrogen generation. However, lack highly active bifunctional catalysts poses huge challenge this strategy. In work, we report novel and universal electrodeposition strategy rationally synthesize self-supporting electrode. utilization ammonium fluoride helps modulate not only morphology CoP, but also synchronous formation an anion-modified structure, leading excellent performance. optimal F-CoP/CF exhibits small potentials -90 mV 41 at 1 A cm-2, high stability low Tafel slopes 28 dec-1 3.26 for HER HzOR, respectively. efficient stable activity can be further confirmed in anion-exchange membrane hydrazine-assisted water electrolyzer (0.49 V cm-2). Utilizing density functional theory calculations, optimized adsorption energy molecules intermediates well rate-determining step HzOR are demonstrated F-CoP.
Language: Английский
Citations
61Chemical Communications, Journal Year: 2024, Volume and Issue: 60(39), P. 5104 - 5135
Published: Jan. 1, 2024
This review has examined the advancements and challenges in development of transition metal-based electrocatalysts for alkaline water splitting reaction last decade.
Language: Английский
Citations
53Journal of Energy Chemistry, Journal Year: 2023, Volume and Issue: 89, P. 646 - 669
Published: Nov. 8, 2023
Language: Английский
Citations
49Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 655, P. 296 - 306
Published: Nov. 3, 2023
Language: Английский
Citations
45International Journal of Hydrogen Energy, Journal Year: 2023, Volume and Issue: 48(87), P. 34009 - 34017
Published: June 4, 2023
Language: Английский
Citations
43Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 80, P. 110293 - 110293
Published: Jan. 5, 2024
Language: Английский
Citations
32Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(15)
Published: March 10, 2024
Abstract Electrochemical water splitting plays a vital role in facilitating the transition towards sustainable energy future by enabling renewable hydrogen (H 2 ) production, storage, and emission‐free transportation. Developing earth‐abundant electrocatalysts with outstanding overall water‐splitting performance, excellent catalytic activity, robust long‐term stability is highly important practical application of electrolysis. Self‐supported have emerged as most appealing candidate for H production due to their increased active site loading, rapid mass charge transfer, strong interaction underneath conducting support. Additionally, these also provide enhanced reaction kinetics stability. Here, comprehensive review recent progress developing self‐supported Fe‐based selective oxidation reactions presented examples oxyhydroxides, layered double hydroxides, oxides, chalcogenides, phosphides, nitrides, other Fe‐containing electrocatalysts. A historical development synthesis provided, an emphasis on various deposition methods choice substrates considering large‐scale commercial applications. An overview mechanistic understanding approaches are presented. Finally, challenges opportunities associated applications alternative discussed.
Language: Английский
Citations
29Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 664, P. 349 - 359
Published: March 11, 2024
Language: Английский
Citations
19Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 355, P. 124197 - 124197
Published: May 12, 2024
Language: Английский
Citations
18Journal of Alloys and Compounds, Journal Year: 2023, Volume and Issue: 946, P. 169451 - 169451
Published: March 1, 2023
Language: Английский
Citations
42