Co-ZIF-derived dual Co and Co3S4 nanoparticles encapsulated in N-doped carbon matrix for efficient photocatalytic CO2 reduction DOI

Lili Huang,

Shengpeng Mo, Xin Zhao

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(3), P. 112566 - 112566

Published: March 20, 2024

Language: Английский

Recent Advances in Electrocatalysts for Efficient Nitrate Reduction to Ammonia DOI
Di Liu, Lulu Qiao,

Shuyang Peng

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(43)

Published: June 25, 2023

Abstract Ammonia as an irreplaceable chemical has been widely demanded to keep the sustainable development of modern society. However, its industrial production consumes huge energy and releases extraordinary green‐house gases, leading various environmental issues. To achieve green ammonia is a great challenge that extensively pursued recently. In review, most promising strategy, electrochemical nitrate reduction reaction (e‐NO 3 RR) for purpose comprehensively investigated give full understanding mechanism provide guidance future directions. Particularly, electrocatalysts focused realize high yield rate Faraday efficiency applications. The recent‐developed catalysts, including noble metallic materials, alloys, metal compounds, single‐metal‐atom metal‐free are systematically discussed review effects factors on catalytic performance in e‐NO RR. Accordingly, strategies, defects engineering, coordination environment modulating, surface controlling, hybridization, carefully improve performance, such intrinsic activity selectivity. Finally, perspectives challenges given out. This shall insightful advanced systems efficiently industry.

Language: Английский

Citations

144
Recent Progress and Perspectives on Transition Metal-Based Electrocatalysts for Efficient Nitrate Reduction DOI
Jun Zhou,

Sanshuang Gao,

Guangzhi Hu

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: 38(8), P. 6701 - 6722

Published: April 8, 2024

Electrochemical nitrate reduction is the process of converting into ammonia or nitrogen using electric energy. This saves energy, protects environment, and an important technology for resource recovery water purification. paper examines recent advances in electrochemical research analyzes reaction mechanism path as well influence various factors on through thermodynamic kinetic principles. Second, catalytic performances transition metal electrocatalysts form single metals, alloys, oxides, composites are analyzed detail, which lays foundation rational development new, efficient, stable electrocatalysts. Finally, future directions prospects envisioned.

Language: Английский

Citations

20
Three-dimensional porous Co foam with nanosheets subunits for high-performance electrocatalytic nitrate-to-ammonia conversion DOI
Jie Chen, Xun He, Jun Li

et al.

Inorganic Chemistry Frontiers, Journal Year: 2023, Volume and Issue: 10(15), P. 4450 - 4455

Published: Jan. 1, 2023

Three-dimensional porous Co foam/TP is a high-performance catalyst for electrochemical NO 3 − -to-NH conversion, delivering large NH yield of 600.6 μmol h −1 cm −2 and high faradaic efficiency 96.5%.

Language: Английский

Citations

24
Ni-CoS2@MoS2 hollow nanorod array in-situ synthesized on Ti foil as Pt-free self-supporting electrode for efficient wide-pH hydrogen evolution DOI
Xing Qian, Jiashuo Wu,

Yajie Yang

et al.

Applied Surface Science, Journal Year: 2024, Volume and Issue: 655, P. 159629 - 159629

Published: Feb. 8, 2024

Language: Английский

Citations

11
Metal/covalent-organic framework-based electrocatalysts for electrochemical reduction of nitrate to ammonia DOI Creative Commons
Tarekegn Heliso Dolla, Boying Zhang, Thabo Matthews

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 518, P. 216061 - 216061

Published: July 8, 2024

The pervasive contamination of industrial, domestic, and agricultural wastewater with nitrate poses profound ecological public health risks. Traditional methods for remediating nitrate-laden water face formidable challenges due to its high solubility stability. However, a promising solution emerges in the form electrochemical reduction (eNO3RR), offering both efficient removal valuable ammonia generation sustainable manner. This review explores burgeoning field eNO3RR, focusing on recent advancements utilizing porous crystalline framework materials − metal–organic frameworks (MOFs) covalent-organic (COFs) as novel class electrocatalysts. These innovative exhibit unique properties such adjustable porosity, diverse structures, tunable pore sizes, well-defined active sites, making them ideal candidates enhancing efficiency selectivity under ambient conditions. By dissecting structure–activity relationship inherent MOF/COF-based electrocatalysts, this aims provide comprehensive understanding their role driving conversion NO3− NH3. Moreover, it identifies current proposes future prospects leveraging these advanced pollutants, glimpse into greener more effective approach remediation resource recovery.

Language: Английский

Citations

9
ZIF-67 derivatives in electrocatalysis DOI

Guoliang Gao,

Chengzhi Xiao,

Rongrong Zhang

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 523, P. 216296 - 216296

Published: Nov. 2, 2024

Language: Английский

Citations

8
Mechanism of Key Intermediates Regulation in Electrocatalytic Nitrate-to-Ammonia Conversion Driven by Polarized Electric Field DOI

Xiaochuan Tang,

Wei Liu,

Chenjun Lei

et al.

Nano Energy, Journal Year: 2025, Volume and Issue: unknown, P. 110708 - 110708

Published: Jan. 1, 2025

Language: Английский

Citations

1
In Situ Generation of Co-Decorated Carbon Nanotubes by Zeolitic Imidazolate Frameworks to Facilitate High-Performance Lithium–Sulfur Batteries DOI
Hang Zhao, Xinzhi Ma, Zhixuan Xu

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 19, 2024

Lithium–sulfur (Li–S) batteries are perceived as a promising energy storage system for the next generation because of advantages high theoretical specific capacity and environmental friendliness. Whereas, challenges such poor conductivity sulfur, "shuttle effect" polysulfides, sluggish redox kinetics polysulfides in conversion reactions remain. Herein, cubic shape ZIF–67 was prepared, Co-decorated carbon nanotubes covered on nitrogen–carbon matrix (CoNC–CNT) CoNC–CNT coated with reduced graphene oxide (CoNC–CNT/rGO) hybrids obtained by using raw material. The compounds proposed sulfur carrier Li–S to promote electrochemical performance. porous three-dimensional (3D) conductive network provides physical confinement, Co nanoparticles provide chemical adsorption catalysis polysulfides. CoNC–CNT/S hybrid delivers reversible high-capacity 1267.2 mAh g–1 at 0.05C 509.4 even under 4C. CoNC–CNT/rGO/S electrode exhibits an outstanding long-term cycle stability decay rate 0.0516% per cycle. This study combines adsorption, strategies obtain high-performance batteries.

Language: Английский

Citations

7
Transition metal single-atom electrocatalytic reduction catalyst for nitrate to ammonia DOI

Zhenlin Mo,

Jincheng Mu,

Baojun Liu

et al.

Journal of Electroanalytical Chemistry, Journal Year: 2024, Volume and Issue: 969, P. 118533 - 118533

Published: July 27, 2024

Language: Английский

Citations

6
High Faraday efficiency of Cu1Co1–BCN based on a dodecahydro-closo-dodecaborate hybrid for electrocatalytic reduction of nitrate to ammonia DOI
Jia-Jia Wang, Zhengyu Fan,

Haixu Zhao

et al.

Journal of Materials Chemistry A, Journal Year: 2023, Volume and Issue: 11(37), P. 20234 - 20241

Published: Jan. 1, 2023

The process of electrocatalytic nitrate reduction reaction (NIRR) to produce ammonia (NH 3 ) presents a promising solution the challenges contamination and high value synthesis.

Language: Английский

Citations

15