C – Journal of Carbon Research,
Journal Year:
2023,
Volume and Issue:
9(4), P. 107 - 107
Published: Nov. 13, 2023
As
heterogeneous
catalysis
is
a
practical
method
for
activating
Oxone,
the
immobilization
of
transition
metals
(e.g.,
Co,
Fe)
on
carbonaceous
supports
promising
platform.
Thus,
this
study
attempts
to
develop
carbon-supported
metallic
catalyst
by
growing
Co/Fe
carbon
foam
(CF)
via
adopting
melamine
as
readily
available
template
which
could
be
transferred
nitrogen-doped
CF
with
marcoporous
structures.
Specifically,
unique
adornment
species
facilely
fabricated
through
complexation
plant
extract,
tannic
acid,
foam,
followed
carbonization
produce
nano-needle-like
N-doped
CF,
forming
magnetic
(MCF).
This
resultant
MCF
exhibits
much
higher
surface
area
54.6
m2/g
than
(9.5
m2/g),
and
possesses
larger
specific
capacitance
9.7
F/g,
that
4.0
F/g.
These
superior
features
enable
it
accelerate
Oxone
activation
in
order
degrade
an
emerging
contaminant,
bis(4-hydroxyphenyl)methanone
(BHPM).
Furthermore,
+
lower
energy
18.6
kJ/mol
BHPM
elimination
retains
its
effectiveness
eliminating
over
multiple
rounds.
More
importantly,
also
prepared
directly
compared
composition-structure-property
relationship
provide
valuable
insights
further
understanding
catalytic
behaviors,
surficial
characteristics,
application
such
functional
material.
Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
12(30), P. 19532 - 19550
Published: Jan. 1, 2024
Herein,
an
innovative
assembly
of
multi-metal
ferrite
nanoparticles,
MgCuFe
2
O
4
,
was
anchored
on
a
g-C
3
N
surface
to
improve
the
degradation
efficiency
2,4-D
over
visible-light-assisted
peroxymonosulfate
activation
system.
The
rationale
for
stable
bifunctional
acidic
sites
on
the
surface
of
carbon
materials
remains
a
challenge.
In
this
study,
phosphorus-doped
activated
was
synthesized
through
pyrolysis
phosphoric
acid
and
used
in
acetylene
dimerization
reaction.
bonding
phosphorus
to
atoms
creates
Lewis
as
result
difference
electronegativity.
Meanwhile,
generates
more
oxygen-containing
groups,
enhancing
Brönsted
surfaces
materials.
resulting
material
exhibits
significant
number
oxygen
functional
sites,
defects,
ensuring
ample
exposure
availability
catalytic
facilitate
notable
activity
dimerization.
Theoretical
calculations
an
empirical
dynamics
model
were
developed
investigate
reaction
mechanism
This
study
has
potential
provide
insights
into
optimizing
chemical
structure
promoting
them
or
other
reactions.