Industrial Crops and Products, Journal Year: 2024, Volume and Issue: 212, P. 118316 - 118316
Published: March 2, 2024
Language: Английский
Industrial Crops and Products, Journal Year: 2024, Volume and Issue: 212, P. 118316 - 118316
Published: March 2, 2024
Language: Английский
Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: unknown, P. 109557 - 109557
Published: Jan. 1, 2024
Language: Английский
Citations
23Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 687, P. 24 - 35
Published: Feb. 8, 2025
Language: Английский
Citations
16Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159303 - 159303
Published: Jan. 1, 2025
Language: Английский
Citations
4Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 663, P. 345 - 357
Published: Feb. 21, 2024
Language: Английский
Citations
13Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 492, P. 152353 - 152353
Published: May 17, 2024
Language: Английский
Citations
13Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 337, P. 126265 - 126265
Published: Jan. 2, 2024
Language: Английский
Citations
11Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 358, P. 124388 - 124388
Published: July 9, 2024
Language: Английский
Citations
11ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 1206 - 1216
Published: Jan. 6, 2025
Aqueous-phase tandem reactions, as a fundamental aspect of green chemistry, hold crucial position in the contemporary synthesis fine chemicals, wherein advancement high-performance heterogeneous catalysts remains formidable challenge. Herein, we report Pt1Con single-atom alloy (SAA) catalyst which Pt single atoms are immobilized onto surface Co nanoparticles through Pt–Co coordination. The SAA exhibits high chemoselectivity for aqueous-phase hydrogenation–rearrangement reaction furfural (FAL) to cyclopentanol (CPL) (yield: >93%, considering carbon loss), with TOF value 2257 h–1 (based on Pt). A joint investigation based dynamics, isotope-label tracing experiments, EPR, and situ FT-IR verifies five-step consecutive pathway formation CPL. Notably, during reaction, rapid exchange hydrogen would occur between activated species water solvent. Furthermore, molecule does not serve H-donor but is involved rearrangement side chain furan ring. Kinetic studies combined DFT calculations substantiate that interface sites effectively lower energy barrier cyclopentanone (CPO) hydrogenation step via facilitating activation adsorption carbonyl group, accounting largely enhanced catalytic behavior. This study sheds light highly efficient stable biomass upgrading aqueous phase.
Language: Английский
Citations
1ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 12, 2025
Language: Английский
Citations
1International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: 270, P. 132465 - 132465
Published: May 18, 2024
Language: Английский
Citations
8