Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Language: Английский
Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Language: Английский
Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 358, P. 130350 - 130350
Published: Nov. 1, 2024
Language: Английский
Citations
5Journal of Alloys and Compounds, Journal Year: 2023, Volume and Issue: 976, P. 173235 - 173235
Published: Dec. 20, 2023
Language: Английский
Citations
11Environmental Nanotechnology Monitoring & Management, Journal Year: 2024, Volume and Issue: 22, P. 100966 - 100966
Published: May 18, 2024
Language: Английский
Citations
4Published: Jan. 1, 2025
Covalent organic frameworks (COFs) equipped with controllable porosity and excellent structural stability are regarded as promising candidates for photocatalytic CO2 reduction, yet some inherent drawbacks including low activation sluggish charge carriers' transfer properties urgently need to be addressed. Herein, we developed an imine-bridged strategy construct ZnO/COF heterostructure by integrating donor-acceptor COF (TAPT-DMTP COF) on the surface of amino-modified ZnO reduction. The optimal photocatalyst, N-ZnO/TAPT-DMTP COF-3, exhibited superior activity reducing CO CH4, which was significantly higher than pristine non-covalently bridged ZnO/TAPT-DMTP COF. Experimental photo-electrochemical results reveal that microstructure TAPT-DMTP COF, interfacial imine-bridging S-scheme heterojunction play a crucial role in promoting photoinduced separation, thus improving efficiency. Moreover, in-situ characterization theoretical calculations indicate electrons from N-ZnO upon hybridization this dramatically lower energy barrier rate-determining step *COOH *CO. This work provides insight into covalent-linked COF-based photocatalyst highlights vital roles enhancing
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Language: Английский
Citations
0