Semi-liquid-stated flux assisted synthesis of CdS for boosting photocatalytic hydrogen evolution DOI
Xiaoyan Xiang, Huanmin Liu, Kangle Lv

et al.

New Journal of Chemistry, Journal Year: 2024, Volume and Issue: 48(35), P. 15633 - 15644

Published: Jan. 1, 2024

Highly crystalline CdS with an S defect and a Cl dopant was synthesized through low-temperature calcination within semi-liquid-state complex chloride molten salts.

Language: Английский

Sustainable H2 Production from Lignocellulosic Biomass over MoS2 Modified Sulfur Vacancy Enriched ZnIn2S4 Photocatalyst DOI

Jiping Tang,

Yan Chen, Ziyi Wang

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 15(1), P. 265 - 274

Published: Dec. 17, 2024

Exploring visible-light-responsive photocatalysts for photocatalytic lignocellulosic biomass-to-H2 conversion remains a glamorous but challenging goal because the photogenerated holes cannot directly transfer to biomass owing absence of charge channel. Herein, we design ZnIn2S4 nanosheets with abundant sulfur vacancy (VS-ZnIn2S4) as visible light responsive H2 production from in presence MoS2 cocatalyst. In this smartly designed photocatalysts, reduces energy barrier •OH generation reaction and results fast dynamics •OH, which acts crucial species oxygenolysis biomass. As expected, rate optimized MoS2/VS-ZnIn2S4 photocatalyst α-cellulose bamboo powder aqueous solution achieves 1572 133 μmol·g–1·h–1, respectively. This study validates feasibility boost into fuel.

Language: Английский

Citations

4
Production of biomaterials and biochemicals from lignocellulosic biomass through sustainable approaches: current scenario and future perspectives DOI Creative Commons
Avinash P. Ingle, Shreshtha Saxena, M. P. Moharil

et al.

Deleted Journal, Journal Year: 2025, Volume and Issue: 2(1)

Published: March 9, 2025

Language: Английский

Citations

0
Co0.5CuP loaded Cd0.9Co0.1S hollow nanospheres with p-n heterojunction for photocatalytic hydrogen production DOI
Qian Liu,

Changdi Wang,

Jianxiang Wang

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137491 - 137491

Published: March 1, 2025

Language: Английский

Citations

0
Research Progress of Bifunctional Photocatalysts for Biomass Conversion and Fuel Production DOI Creative Commons

Tianyu Hang,

Linlin Wu,

Wenxin Liu

et al.

Advanced Energy and Sustainability Research, Journal Year: 2024, Volume and Issue: unknown

Published: June 27, 2024

Bifunctional photocatalysis for biomass conversion and fuel production not only utilizes abundant renewable resources, but also obtains high‐energy fuels while obtaining fine chemicals. It is a green, clean, efficient, low‐cost, high‐value strategy, which conducive to achieving carbon neutralization, cycle, solving energy environmental problems. However, very few literatures have classified analyzed the bifunctional of biomass. On basis latest research progress, photocatalysts based on classification transformation coupled with (hydrogen or CO 2 reduction) by mainly using rate, value‐added product yield, (H , CO) so as evaluation indicators are reviewed. The reaction mechanisms, development status, prospects analyzed, summarized prospected. This review helps better understand in route.

Language: Английский

Citations

2
Solar‐driven reforming of lignocellulosic biomass to renewable biohydrogen: A review DOI Open Access

Xuan Cuong Luu,

Lan‐Anh Phan Thi, Pankaj Raizada

et al.

ChemCatChem, Journal Year: 2024, Volume and Issue: 16(22)

Published: Aug. 12, 2024

Abstract To date, humans are looking for suitable energy sources to meet the global demand fuels. Among many candidates, biohydrogen (bio‐H 2 ), a future fuel perspective, is expected grow critically and receive considerable attention replace fossil This review focuses on production via post‐method photocatalytic reforming of ideal feedstock abundant lignocellulosic biomass. Renewable biomass precursors used without net greenhouse gas emissions. idea holds great promise as sustainable environmentally friendly solution. In particular, saccharide substrates, including monosaccharides, disaccharides, polysaccharides, etc., have been sacrificial reagents in over past few decades. various cellulose has attracted worldwide since it most polymeric resource that can be obtained from sources. Following, photo‐reforming renewable biomass, which aligns with requirements development, successfully proposed. The overall catalytic efficiency will discussed regarding evolution rate (mmol g cat −1 h ). Finally, concluded challenges potential opportunities enhance also given.

Language: Английский

Citations

2
Selective photocatalytic glucaric acid production from TEMPO-mediated glucose oxidation on alkalized carbon nitride DOI Creative Commons
Jiu Wang, Qi Zhao, Zheng Li

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 360, P. 124526 - 124526

Published: Aug. 23, 2024

Biomass photorefining is a promising approach for sustainable clean energy and high-value chemical production. However, selectively converting glucose into glucaric acid, the most valuable derivative, still poses significant challenge due to difficulty in transforming terminal hydroxyl group carboxy group. Here, we demonstrate that highly selective acid can be achieved by synergistically coupling alkalizing modification of polymeric carbon nitride (CN) with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) mediation, which promotes oxidation primary alcohol attached C6 site gluconic acid. Density functional theory (DFT) calculations affirm enhanced performance modified CN When medicated TEMPO, optimized photocatalysis achieves ∼ 100 % conversion > 30 yield, setting record photocatalytic This work showcases significance combining photocatalyst redox mediation inspiring high-efficiency systems biomass photorefining.

Language: Английский

Citations

2
Roles of Cocatalysts in Biomass Photo(electro)refining DOI Creative Commons
Zheng Li, Wenping Li, Jiu Wang

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(42)

Published: Sept. 2, 2024

Abstract Photosynthesis converts solar energy, carbon dioxide, and water into biomass, offering a renewable energy chemical source. Biomass photo(electro)refining (BPeR) emerges as sustainable alternative to petrochemicals for fuel production. However, BPeR faces challenges due photocatalyst limitations, necessitating the integration of cocatalysts. Cocatalysts significantly impact efficiency, selectivity, durability reactions, yet their roles require systematic elucidation understanding. This review explores how cocatalysts bond functionalization, cleavage, formation in biomass its derivatives. It discusses crucial charge carrier generation, separation, transportation, particularly catalyzing surface reactions such hydrogen‐involved manipulation oxygen or radicals, C─C/O/H transformations. Additionally, it outlines prospects developing enhance efficiency durability, boosting viability source materials.

Language: Английский

Citations

2
Molybdate modified ZnCdS to construct fast carrier transfer channels for efficient hydrogen evolution DOI
Zhiliang Jin, Lihong Zhang,

Entian Cui

et al.

Journal of Photochemistry and Photobiology A Chemistry, Journal Year: 2024, Volume and Issue: 454, P. 115693 - 115693

Published: April 21, 2024

Language: Английский

Citations

1
Boosting solar-light photocatalytic activity of Ni2P-decorated ZnCr2O4 nanofibers for H2 evolution and tetracycline elimination DOI
Hao Peng,

Meiying Luo,

Xiaogang Zheng

et al.

Ceramics International, Journal Year: 2024, Volume and Issue: 50(15), P. 26474 - 26481

Published: April 27, 2024

Language: Английский

Citations

1
Strong electron coupling between amorphous WP and MoSe2/ZnCdS S-scheme heterojunction for enhanced wide spectrum photocatalytic hydrogen production DOI
Jiaqi Yang, Xuqiang Hao,

Jia Liu

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 354, P. 129348 - 129348

Published: Aug. 24, 2024

Language: Английский

Citations

1