Energy Technology,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 17, 2024
Layered
double
hydroxide
(LDH)
has
a
layered
structure,
which
makes
it
strong
candidate
for
supercapacitors
(SC)
due
to
its
high
surface
area.
However,
they
suffer
from
low
conductivity
insufficient
charge
transfer
across
their
layers.
This
research
aims
overcome
this
obstacle
by
introducing
conductive
channels
among
the
layers
addition
of
Ag–citrate
and
polyaniline
(PANI).
Consequently,
five
electrodes
(S
1–5
)
were
made
NiCoMn
LDH
(referred
as
henceforth)
2:1
PANI
composite
(Ag/PANI)
in
different
ratios
into
electrodes.
Electrochemical
analysis
revealed
successful
improvement
performance
fraction
Ag/PANI
increased
until
equaled
where
highest
specific
capacitance
617
F
g
−1
was
obtained,
is
12%
greater
than
value
solely
electrode
(550
).
A
device
fabricated
with
best
3
activated
carbon
electrode,
demonstrated
energy
densities
power
41
WhKg
412.5
W
Kg
14
8250
at
0.5
10
current
densities,
respectively.
It
also
exhibited
capacitive
retention
about
75%
3000
galvanostatic
charge–discharge
cycles.
These
results
encourage
use
LDH,
1:1
ratio
SCs
remarkable
performance.
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 2, 2025
Abstract
Exploring
advanced
high‐performance
electrode
materials
for
aqueous
zinc‐ion
batteries
(AZIBs)
is
of
enormous
significance
the
development
and
commercial
application
AZIBs.
Herein,
nanoparticle
assemble
hollow
structured
Fe
3
O
4
@ZnFe
2
@NC/Mo
TiC
T
x
with
excellent
specific
capacity
cycling
performance
fabricated
via
a
designed
method,
an
strategy
First
proposed
to
modulate
charge
storage
performance.
The
superior
can
be
attributed
enhanced
electrochemical
activity
reversibility,
which
are
mainly
achieved
by
in
situ
Zn
adulteration
trigger
electron
redistribution
between
Fe,
Zn,
atoms.
Additionally,
unique
structure
multiple
components
provide
plentiful
active
sites,
ameliorating
affinity
electrolyte
facilitating
kinetics.
great
ascribed
improved
structural
stability
loading
two
robust
substrates
intimately
coated
carbon
MXene.
renders
distinctly
higher
(364.4
mAh·g
−1
)
than
that
(92.2
),
@NC
(211.2
(276.8
as
well
86.2%
retention
over
1000
cycles.
Moreover,
mechanism
new
effects
composition
regulation
revealed
characterizations
computations.
Applied Organometallic Chemistry,
Journal Year:
2024,
Volume and Issue:
38(8)
Published: May 27, 2024
Transition
metal
sulfides
with
designed
nanostructures
are
expected
to
provide
superior
electrochemical
performance
when
used
as
electrode
materials
for
pseudocapacitors
compared
their
oxide
counterparts.
In
this
paper,
hollow
Co
3
S
4
dodecahedra
were
successfully
prepared
using
cobalt‐based
zeolite
imidazolium
skeleton
(ZIF‐67)
the
precursor
and
thioacetamide
(TAA)
sulfur
source
combined
a
facile
one‐step
vulcanization
process.
The
cavity
structure
not
only
shortens
carrier
transport
distance
but
also
provides
higher
specific
surface
area
abundant
active
sites,
which
promotes
an
efficient
mass
transfer
addition,
synthesis
of
has
greater
advantages
than
in
terms
cost
control
process
simplification.
capacitance
produced
nanopolyhedra
was
668
F/g
at
1
A/g
remained
353
10
pseudocapacitor
electrode,
demonstrating
its
multiplication
capability.
retention
is
86.4%
after
5000
cycles
A/g,
indicating
long
cycle
stability.
Notably,
employing
commercial
activated
carbon
negative
as‐prepared
polyhedrons
positive
assembled
asymmetry
supercapacitor
device
delivers
high
energy
density
20.7
Wh/kg
power
716
kW/kg.
value
remains
up
81.4%
2000
charging/discharging
cycles.
simple
opens
new
opportunities
develop
advanced
exhibiting
potential
various
applications.
Applied Organometallic Chemistry,
Journal Year:
2024,
Volume and Issue:
38(8)
Published: June 18, 2024
Presently,
two‐dimensional
(2D)
metal–organic
framework
(MOF)
are
drawing
increasing
attention
in
energy‐storage
areas.
However,
more
and
complexed
factors
would
affect
the
nucleation
growth
of
2D
MOFs,
subsequently
final
performance.
Particularly,
it
is
important
to
control
coordination
rate
between
ions
ligands.
In
this
paper,
MXene
was
directly
used
as
titanium
source
coordinate
with
an
organic
ligand
form
Ti‐MOF
sheets.
To
further
boost
performance,
mesopores
were
introduced
preparing
Ti‐MOF,
constructing
hierarchical
porous
Ti‐MOF@Ti
3
C
2
T
X
hybrids.
Results
showed
that
diffusion‐controlled
behaviors
play
a
dominant
role
over
surface
capacitive
during
charge
storage
process
A
hybrid
supercapacitor
(HSC)
assembled
obtained
HP‐Ti‐MOF@Ti
activated
carbon
(AC)
exhibited
energy
density
22.9
Wh
kg
−1
at
power
850
W
(1
g
),
4.25
kW
15.3
(5
).
The
present
strategy
expected
provide
design
ideas
for
novel
electrode
materials.