Construction of Donor–Acceptor-Type Conjugated Microporous Polymers by Oxidative Coupling of Boranil-Carbazole Mixed Monomers for Enhanced Photocatalytic Oxidation DOI
Zehao Zhao, Wenshuo Xu,

Dongxin Yang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(42), P. 57200 - 57208

Published: Oct. 11, 2024

Conjugated microporous polymers (CMPs), featuring photoactive structures, a high surface area, robust thermal stability, and facile modulation, provide versatile platform for fabricating diverse heterogeneous photocatalysts. The incorporation of donor–acceptor (D–A) structures into CMPs to increase their charge separation potential enhance the photocatalytic efficacy is viable strategy. In this work, we designed synthesized unique set D–A monomers, incorporating boranil dyes as electron-deficient moieties carbazoles electron-rich subunits. Subsequently, were prepared via an economical environmentally friendly oxidation coupling reaction, in reactions was investigated. Modulation polymer's photoelectronic properties performance can be achieved by adjusting content monomer. polymer pCZFB-3, with highest units, exhibited optimal activity. This finding confirms that strengthening effect significantly catalyst's catalytic efficacy. study presents insights designing innovative photocatalysts based on boron-containing dyes.

Language: Английский

Thiophene-functionalized triazolate metal-organic frameworks for enhanced oxygen evolution reaction: Insights from electrochemical studies and DFT calculations DOI
Limin Ma, Muhammad Imran Anwar, Faheem Abbas

et al.

International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 127, P. 447 - 461

Published: April 15, 2025

Language: Английский

Citations

0
Synthesis, structure and luminescent sensing behaviour of a thieno[3,4-b]thiophene-based coordination polymer DOI

Ye-Feng Wu,

Yu-Chen Ma,

Quan Yuan

et al.

Inorganica Chimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 122733 - 122733

Published: April 1, 2025

Language: Английский

Citations

0
Hyaluronic acid mediated ZnO-NPs: In relation to electrical and photocatalytic activity for dye degradation DOI
Abdullah Akkaya, Ebru Karakaş Sarıkaya, Osman Kahveci

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1005, P. 175861 - 175861

Published: Aug. 5, 2024

Language: Английский

Citations

1
Oxygen vacancies and heterojunction synergistically enhancing degradation of rhodamine B by UiO-66-NH2 derived photocatalyst DOI
J. Y. T. Wei,

Zhanming Liang,

Lingyun Hao

et al.

Journal of Water Process Engineering, Journal Year: 2024, Volume and Issue: 69, P. 106830 - 106830

Published: Dec. 21, 2024

Language: Английский

Citations

1
Construction of Donor–Acceptor-Type Conjugated Microporous Polymers by Oxidative Coupling of Boranil-Carbazole Mixed Monomers for Enhanced Photocatalytic Oxidation DOI
Zehao Zhao, Wenshuo Xu,

Dongxin Yang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(42), P. 57200 - 57208

Published: Oct. 11, 2024

Conjugated microporous polymers (CMPs), featuring photoactive structures, a high surface area, robust thermal stability, and facile modulation, provide versatile platform for fabricating diverse heterogeneous photocatalysts. The incorporation of donor–acceptor (D–A) structures into CMPs to increase their charge separation potential enhance the photocatalytic efficacy is viable strategy. In this work, we designed synthesized unique set D–A monomers, incorporating boranil dyes as electron-deficient moieties carbazoles electron-rich subunits. Subsequently, were prepared via an economical environmentally friendly oxidation coupling reaction, in reactions was investigated. Modulation polymer's photoelectronic properties performance can be achieved by adjusting content monomer. polymer pCZFB-3, with highest units, exhibited optimal activity. This finding confirms that strengthening effect significantly catalyst's catalytic efficacy. study presents insights designing innovative photocatalysts based on boron-containing dyes.

Language: Английский

Citations

0