Journal of Analytical and Applied Pyrolysis, Journal Year: 2024, Volume and Issue: unknown, P. 106934 - 106934
Published: Dec. 1, 2024
Language: Английский
Journal of Analytical and Applied Pyrolysis, Journal Year: 2024, Volume and Issue: unknown, P. 106934 - 106934
Published: Dec. 1, 2024
Language: Английский
ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 8, 2024
N-doped porous carbon materials possess abundant pores and nitrogen functionalities, holding significant potential for supercapacitors. However, achieving precise control of the pore structure to enhance electrochemical performance remains challenging in large-scale production commercial electrode materials. Herein, Chinese yam, a rhizome plant rich dopamine, is selected as precursor prepare N,O-codoped hierarchical (N/O-PC-3) via one-step carbonization activation process. The precisely controlled by adjusting degree aggregation zinc-containing hydrolysates biomass through synergistic action ZnCl2 (activating agent) NH4Cl (nitrogen source). Due its micropore-dominant structure, high (10.5 at. %) oxygen (13.1 content, along with good electronic conductivity excellent wettability, N/O-PC-3 exhibits remarkable frequency response, an ultrahigh rate up 5 V s–1 gravimetric, volumetric, areal capacitances 414 F g–1, 311 cm–3, 23.8 μF cm–2 at 1 A respectively. It also demonstrates capability (326 g–1 100 79% capacitance retention). Even mass loading 15 mg cm–2, achieves gravimetric 223 g–1. assembled symmetric supercapacitor delivers energy density 22.9 W h kg–1 power 102.9 kg–1, making it highly desirable practical application storage. Additionally, this work offers straightforward approach controlling
Language: Английский
Citations
46Fuel, Journal Year: 2025, Volume and Issue: 388, P. 134464 - 134464
Published: Jan. 22, 2025
Language: Английский
Citations
1Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162487 - 162487
Published: April 1, 2025
Language: Английский
Citations
1Biomass and Bioenergy, Journal Year: 2025, Volume and Issue: 198, P. 107883 - 107883
Published: April 9, 2025
Language: Английский
Citations
0ACS Applied Energy Materials, Journal Year: 2024, Volume and Issue: 7(17), P. 7185 - 7204
Published: Aug. 20, 2024
The rational molecular engineering of a heteroatom-enriched polymer precursor to achieve inherently doped carbon material is crucial importance for advanced applications. In the present work, molecular-design flexibility polybenzoxazine utilized fabricate N, O-codoped framework using facile template-free extended sol–gel method phloroglucinol, polyethylenimine, and formaldehyde as multifunctional precursors. uniform spherical morphology polymeric particles was attained by careful tuning reactant stoichiometric ratio, concentration, solvent ratio in reaction medium control kinetics particle formation. corresponding heteroatom-doped spheres with 28% nitrogen 20.5% oxygen determined CHNS analysis were subjecting moderate carbonization conditions, resulting formation partial graphitic structure. structure BET surface area 221 m2 g–1 high heteroatom content makes it potential candidate electrochemical energy storage. performance supercapacitor evaluated three-electrode system where displayed an excellent specific capacitance 728 F at 10 A current density 0.1 M H2SO4 electrolyte, 56 W h kg–1 power 14246 kg–1. further flexible all-solid-state symmetric two-electrode simulate real-time analysis. active appreciable 50.3 0.2 g–1. addition, retention ∼86% after 2500 cycles asymmetric configuration also confirmed reversible nature device, negligible changes resistance values obtained before cyclic tests. as-synthesized precursor-based fabrication presents itself promising electrodes.
Language: Английский
Citations
2Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 107, P. 114887 - 114887
Published: Dec. 8, 2024
Language: Английский
Citations
2Advanced Sustainable Systems, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 23, 2024
Abstract Hierarchical porous carbon exhibits great potential as the cathode materials for zinc ion hybrid capacitor. Herein, a convenient and novel strategy is reported to prepare oxygen rich hierarchical derived from alginate by dual molten salt using KHCO 3 NaHCO activators. The obtained (OPC‐700) possesses well‐developed interconnected skeleton, large specific surface area (1193.6 m 2 g −1 ), abundant functional groups. Owing co‐effect, prepared electrode shows capacity of 410.7 F superior electrochemical stabilization. More importantly, Zn// ZnSO 4 //OPC‐700 capacitor assembled with OPC‐700 cathode, foil anode delivers an energy density 124.5 Wh kg stabilization in .
Language: Английский
Citations
2Journal of Materials Science, Journal Year: 2024, Volume and Issue: 59(37), P. 17545 - 17557
Published: Sept. 26, 2024
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 177228 - 177228
Published: Oct. 1, 2024
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 177472 - 177472
Published: Nov. 1, 2024
Language: Английский
Citations
0