MOF‐Based Electrocatalysts for Water Electrolysis, Energy Storage, and Sensing: Progress and Insights DOI

Tao Pan,

Yingying Wang, Sicong Zhang

et al.

The Chemical Record, Journal Year: 2025, Volume and Issue: unknown

Published: April 24, 2025

Abstract Metal‐organic frameworks (MOFs) and their derivatives have shown broad application prospects in fields such as water electrolysis, electrochemical energy storage, sensing due to high specific surface area, tunable structures, abundant active sites. This article provides a comprehensive overview of our research group′s recent advancements developing MOF‐based electrocatalysts for Oxygen Evolution Reaction (OER) Urea Oxidation (UOR) at anodes, well Hydrogen (HER) cathodes during electrolysis. Furthermore, we integrated these catalysts into practical applications, including metal‐air batteries, lithium‐sulfur non‐enzymatic glucose sensors. To further demonstrate the innovative contributions work, systematically compare it with advanced work by other groups. Based on findings performance benchmarking analyses, identify critical challenges that must be addressed advance MOFs‐based toward next‐generation conversion sensing.

Language: Английский

Surface reconstruction engineering of amorphous Ni-Fe phosphate electrocatalyst for highly stable alkaline water splitting DOI
Wenwu Zhao,

X. J. Yang,

Ying Gu

et al.

Journal of Power Sources, Journal Year: 2025, Volume and Issue: 637, P. 236560 - 236560

Published: Feb. 22, 2025

Language: Английский

Citations

2
Reinforced lattice oxygen mechanism of NiFe-LDH@Fe2O3@NF by optimizing the adsorption of oxygen intermediates for efficient water electrolysis DOI
Yongming Luo,

Yingying He,

Jiarun Li

et al.

Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 115497 - 115497

Published: Jan. 1, 2025

Language: Английский

Citations

0
Cationic defect engineering induces LOM-enhanced electrocatalysts derived from in situ semi-transformed NiFe-LDH/MOF heterostructure for efficient overall water-splitting DOI
Yujun Zhu, Yun Zhao,

Chang Xi

et al.

Composites Part B Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 112356 - 112356

Published: March 1, 2025

Language: Английский

Citations

0
Flexible Electrocatalyst Engineering Based on 2D Ultrathin Nanosheets and Lamellar Fern‐Like Aerogel for Water Electrolysis DOI Open Access
Zhenfeng Zhu,

Jiaxuan Qiu,

Liansong Xie

et al.

Advanced Sustainable Systems, Journal Year: 2025, Volume and Issue: unknown

Published: March 12, 2025

Abstract Water electrolysis represents the primary method to produce green hydrogen. Nevertheless, during water electrolysis, particularly at high current densities, a large number of gas bubbles generated are difficult detach from electrode, triggering series negative effects such as active site covering, ionic conductance block, and catalyst deactivation, which in turn reduces efficiency. In recent years, flexible electrocatalysts have been developed address this issue well, with superior characteristics including mechanical deformability, optimization, mass transfer efficiency, structural stability. The advanced development electrocatalyst engineering for is urgently needed be systematically reviewed. Here, first, summarized deeply understand their impact on performance. Second, strategies design based 2D nanosheets fern‐like structure comprehensively introduced. Last but not least, outlooks research presented, will provide preliminary theoretical basis new ideas low‐cost, high‐performance, long‐life applied electrolysis.

Language: Английский

Citations

0
Interfacial Fe-O-Ni bonding regulates built‐in electric field in Fe3O4@Ni(OH)2 heterogeneous catalysts for full water splitting DOI

Ruanming Liao,

Xiongzhi Yang,

Zhihong Peng

et al.

Journal of Power Sources, Journal Year: 2025, Volume and Issue: 641, P. 236864 - 236864

Published: March 26, 2025

Language: Английский

Citations

0
Bioenzyme Inspired Heterointerface Construction of NiFeSe/Ni3S2 for Improved Overall Water Splitting DOI

Xiuling Xu,

Fumin Wang, Liwen Wang

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 3, 2025

Electrocatalytic water splitting for hydrogen production represents a crucial pathway toward establishing sustainable energy infrastructure and addressing environmental concerns, with the development of high-performance nonprecious metal catalysts being central focus. While Ni3S2 demonstrates potential as an electrocatalyst, its limited functionality suboptimal performance necessitate further enhancement. In this study, drawing inspiration from natural hydrogenases, we engineered novel NiFeSe/Ni3S2 composite electrocatalyst through integration NiFeSe Ni3S2. The synthesized catalyst displayed outstanding overall water-splitting in alkaline media, realizing current densities 100 10 mA cm-2 at remarkably low overpotentials 267.4 mV (vs RHE) oxygen evolution reaction (OER) 105.6 (HER), respectively. Remarkably, two-electrode electrolyzer incorporating achieved density 20 substantially reduced cell voltage 1.586 V. Comprehensive analysis revealed that strategic construction biomimetic active centers heterogeneous interfaces significantly modulates electronic structure, improved charge transfer, redistribution electron catalytic sites. This investigation provides valuable insights promising framework rational design bifunctional electrocatalysts applications.

Language: Английский

Citations

0
Synergistic Ternary Catalysis: NiCo-LDH/Ni₃S₂/Co₉S₈@NiFe-LDH-Ov/NF Composite Catalyst for High-Efficiency HER/OER Bifunctional Water Splitting DOI

Jianhao Du,

Liping Wang,

Aojie Yuan

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 180462 - 180462

Published: April 1, 2025

Language: Английский

Citations

0
MOF‐Based Electrocatalysts for Water Electrolysis, Energy Storage, and Sensing: Progress and Insights DOI

Tao Pan,

Yingying Wang, Sicong Zhang

et al.

The Chemical Record, Journal Year: 2025, Volume and Issue: unknown

Published: April 24, 2025

Abstract Metal‐organic frameworks (MOFs) and their derivatives have shown broad application prospects in fields such as water electrolysis, electrochemical energy storage, sensing due to high specific surface area, tunable structures, abundant active sites. This article provides a comprehensive overview of our research group′s recent advancements developing MOF‐based electrocatalysts for Oxygen Evolution Reaction (OER) Urea Oxidation (UOR) at anodes, well Hydrogen (HER) cathodes during electrolysis. Furthermore, we integrated these catalysts into practical applications, including metal‐air batteries, lithium‐sulfur non‐enzymatic glucose sensors. To further demonstrate the innovative contributions work, systematically compare it with advanced work by other groups. Based on findings performance benchmarking analyses, identify critical challenges that must be addressed advance MOFs‐based toward next‐generation conversion sensing.

Language: Английский

Citations

0