Advanced Methods for Hydroxylation of Vegetable Oils, Unsaturated Fatty Acids and Their Alkyl Esters DOI Open Access
Marlena Musik, Marcin Bartkowiak,

Eugeniusz Milchert

et al.

Coatings, Journal Year: 2021, Volume and Issue: 12(1), P. 13 - 13

Published: Dec. 23, 2021

Vegetable oils and their derivatives have great potential as renewable sustainable raw materials for the production of polyurethanes bio-based polyols. For industry an important process is modification. Chemical reactions that are carried out on vegetable are: transesterification, auto-oxidation, hydrogenation, epoxidation, hydroxylation, acrylation, isocyanation others. One modifications performed double bonds and/or carbonyl moieties plants derivatives. These result in products actively used binders coating due to unique structural properties. In this manuscript, we describe technological methods introduction hydroxyl groups: opening oxirane rings by nucleophilic reagents such as: water, alcohols, glycols, amino carboxylic acids; direct hydroxylation unsaturated with peracids combination hydrolysis carboxyl groups hydration; hydroformylation subsequent hydrogenation alkoxylation; ozonolysis alkoxylation.

Language: Английский

Production of polyols and polyurethane from biomass: a review DOI

My Ha Tran,

Eun Yeol Lee

Environmental Chemistry Letters, Journal Year: 2023, Volume and Issue: 21(4), P. 2199 - 2223

Published: March 22, 2023

Language: Английский

Citations

55

Recent Advances in Development of Waste-Based Polymer Materials: A Review DOI Open Access
Krzysztof Formela, Maria Kurańska, Mateusz Barczewski

et al.

Polymers, Journal Year: 2022, Volume and Issue: 14(5), P. 1050 - 1050

Published: March 6, 2022

Limited petroleum sources, suitable law regulations, and higher awareness within society has caused sustainable development of manufacturing recycling polymer blends composites to be gaining increasing attention. This work aims report recent advances in the environmentally friendly low-cost materials based on post-production post-consumer wastes. Sustainable three groups materials: wood composites, polyurethane foams, rubber products were comprehensively described. Special attention was focused examples industrially applicable technologies developed Poland over last five years. Moreover, current trends limitations future “green” waste-based also discussed.

Language: Английский

Citations

52

Biobased Ultralow-Density Polyurethane Foams with Enhanced Recyclability DOI Creative Commons
Olga Gotkiewicz, Miķelis Kirpļuks,

Zuzana Walterová

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(4), P. 1605 - 1615

Published: Jan. 16, 2024

Polyurethane (PUR) foams are widely used in many engineering applications, but their efficient recycling has remained a major challenge for years. This study presents novel strategy of incorporating hydrolyzable ester units into the PUR structure to enhance foam recyclability. The present eco-design concept materials enables fully replacement petrochemical polyols with biobased alternatives and production ultralow-density (16 kg·m–3) foams. To reach this target, series low-function based on succinic acid (SA) were first synthesized. Their subsequent use combination high-functional tall oil-derived polyol led highly homogenous semirigid, partly open-cell outstanding structural, thermal, mechanical properties. Additionally, shows that incorporation SA-polyols linkages significantly enhances recyclability via glycolysis, proving potential contributing circular economy addressing plastic waste concerns.

Language: Английский

Citations

13

New perspectives on biomass conversion and circular economy based on Integrated Algal-Oil Palm Biorefinery framework for sustainable energy and bioproducts co-generation DOI
Mohd Azmuddin Abdullah,

Muhammad Shahid Nazir,

Hanaa Ali Hussein

et al.

Industrial Crops and Products, Journal Year: 2024, Volume and Issue: 213, P. 118452 - 118452

Published: April 4, 2024

Language: Английский

Citations

11

Sound absorption and thermal insulation materials from waste palm oil for housing application: Green polyurethane/water hyacinth fiber sheet composite DOI
Ekkachaï Martwong, Thanathach Yingshataporn-a-nan,

Tanapat Minanandana

et al.

Construction and Building Materials, Journal Year: 2024, Volume and Issue: 438, P. 137007 - 137007

Published: June 15, 2024

Language: Английский

Citations

10

Strategies for the Transformation of Waste Cooking Oils into High-Value Products: A Critical Review DOI Open Access
Valentina Beghetto

Polymers, Journal Year: 2025, Volume and Issue: 17(3), P. 368 - 368

Published: Jan. 29, 2025

Waste cooking oils (WCOs) are generated globally from households, the hospitality industry, and other sectors. Presently, WCOs mainly employed as feedstock for biodiesel energy production, strongly depending on availability of WCOs, which often imported countries. The objective this review is to give an overall comprehensive panorama impacts, regulations, restrictions affecting their possible uses producing high-value products, such bio lubricants, surfactants, polymer additives, road construction solvents. Interestingly, many reviews reported in literature that address use but a topic missing. Published studies, industry reports, regulatory documents were examined identify trends, challenges, production statistics, environmental current production. data collected show hold immense potential renewable resources sustainable industrial applications line with global carbon neutrality goals circular economy principles. However, achieving shift requires addressing gaps, enhancing collection systems, optimizing conversion technologies. This underlines need collaborative efforts among policymakers, stakeholders, researchers maximize contribute development.

Language: Английский

Citations

1

Open-cell bio-polyurethane foams based on bio-polyols from used cooking oil DOI
Krzysztof Polaczek, Maria Kurańska, Aleksander Prociak

et al.

Journal of Cleaner Production, Journal Year: 2022, Volume and Issue: 359, P. 132107 - 132107

Published: May 5, 2022

Language: Английский

Citations

34

Recent Advances in the Preparation and Application of Bio-Based Polyurethanes DOI Open Access

Ya Mo,

Xiaoyue Huang,

Chuanqun Hu

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(15), P. 2155 - 2155

Published: July 29, 2024

Amid environmental pollution and resource depletion, developing utilizing biomass resources as alternatives to petroleum is a prominent research focus. Driven by protection sustainable development, the shift from petroleum-based bio-based polyurethane prevailing trend in material development. Biomass sources such vegetable oil, polysaccharides, lignin offer extensive application prospects production. Functional modifications of these polyurethanes can further expand their range. This article explores preparation various polyurethanes, applications across different fields, anticipated future development uses.

Language: Английский

Citations

6

Green polyurethanes from bio-based building blocks: recent advances and applications DOI Creative Commons

Filippo Campana,

Giulia Brufani,

Francesco Mauriello

et al.

Green Synthesis and Catalysis, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 1, 2024

Language: Английский

Citations

6

Sustainable Rigid Polyurethane Foam from Wasted Palm Oil and Water Hyacinth Fiber Composite—A Green Sound-Absorbing Material DOI Open Access
Nathapong Sukhawipat, Laksana Saengdee, Pamela Pasetto

et al.

Polymers, Journal Year: 2022, Volume and Issue: 14(1), P. 201 - 201

Published: Jan. 4, 2022

A novel rigid sound-absorbing material made from used palm oil-based polyurethane foam (PUF) and water hyacinth fiber (WHF) composite was developed in this research. The NCO index set at 100, while the WHF content 1%wt with mesh sizes ranging 80 to 20. mechanical properties, morphology, flammability, sound absorption coefficient (SAC) of PUF were all investigated. When size reduced 20, compression strength increased 0.33 0.47 N/mm2. Furthermore, use small resulted a smaller pore improved flammability. feasible an SAC value 0.92. As result, derived both oil could be promising green alternative for applications.

Language: Английский

Citations

28