Photocatalytic degradation of antibiotics in municipal wastewater over ZnIn2S4 DOI
Bao Zhang, Rong Xu,

Yun Feng

et al.

Ionics, Journal Year: 2024, Volume and Issue: 30(3), P. 1291 - 1306

Published: Jan. 5, 2024

Language: Английский

Magnetic NH2-MIL-101(Al)/Chitosan nanocomposite as a novel adsorbent for the removal of azithromycin: modeling and process optimization DOI Creative Commons
Ali Azari,

Malakoutian Mohammad,

Kamyar Yaghmaeain

et al.

Scientific Reports, Journal Year: 2022, Volume and Issue: 12(1)

Published: Nov. 8, 2022

In the present study, magnetic NH2-MIL-101(Al)/chitosan nanocomposite (MIL/Cs@Fe3O4 NCs) was synthesized and used in removal of azithromycin (AZT) from an aqueous solution for first time. The as-synthesized MIL/Cs@Fe3O4 NCs characterized by SEM, TEM, XRD, FTIR, BET, VSM techniques. effect various key factors AZT adsorption process modeled optimized using response surface methodology based on central composite design (RSM-CCD). low value p-value (1.3101e-06) RSD (1.873) parameters, along with coefficient determination > 0.997 implied that developed model well fitted experimental data. Under conditions, including pH: 7.992, adsorbent dose: 0.279 g/L, time: 64.256 min concentration: 10.107 mg/L, efficiency capacity were obtained as 98.362 ± 3.24% 238.553 mg/g, respectively. fitting data Langmuir isotherm (R2: 0.998, X2: 0.011) Pseudo-second-order kinetics 0.999, 0.013) showed is monolayer chemical nature. ΔH° 0, ΔS° ∆G° < 0 indicated spontaneous endothermic Magnesium more complicated than other background ions. Reuse 10 consecutive experiments reduced about 30.24%. performance under real conditions also tested promising results achieved, except treatment raw wastewater.

Language: Английский

Citations

94
Pharmaceuticals wastewater treatment via different advanced oxidation processes: Reaction mechanism, operational factors, toxicities, and cost evaluation – A review DOI
Jibran Iqbal, Noor S. Shah, Javed Ali Khan

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 347, P. 127458 - 127458

Published: April 11, 2024

Language: Английский

Citations

51
An in silico study of sustainable drug pollutants removal using carboxylic acid functionalized-MOF nanostructures (MIL-53 (Al)-(COOH)2): Towards a greener future DOI

Iman Salahshoori,

Majid Namayandeh Jorabchi,

Somayeh Ghasemi

et al.

Desalination, Journal Year: 2023, Volume and Issue: 559, P. 116654 - 116654

Published: May 1, 2023

Language: Английский

Citations

49
Metal oxide functionalized ceramic membranes for the removal of pharmaceuticals in wastewater DOI
Lawrence Sawunyama, Opeyemi A. Oyewo,

Naledi Seheri

et al.

Surfaces and Interfaces, Journal Year: 2023, Volume and Issue: 38, P. 102787 - 102787

Published: March 5, 2023

Language: Английский

Citations

47
Recent advances in photocatalytic removal of sulfonamide pollutants from waste water by semiconductor heterojunctions: a review DOI

Sahil Rana,

Amit Kumar,

Pooja Dhiman

et al.

Materials Today Chemistry, Journal Year: 2023, Volume and Issue: 30, P. 101603 - 101603

Published: June 1, 2023

Language: Английский

Citations

46
The recent advances in adsorption and membrane separation and their hybrid technologies for micropollutants removal from wastewater DOI Open Access

Jemal Fito Nure,

Thabo T.I. Nkambule

Journal of Industrial and Engineering Chemistry, Journal Year: 2023, Volume and Issue: 126, P. 92 - 114

Published: June 22, 2023

Language: Английский

Citations

46
Efficient removal of tetracycline, ciprofloxacin, and amoxicillin by novel magnetic chitosan/microalgae biocomposites DOI Creative Commons
Shabnam Mirizadeh,

Carlo Solisio,

Attílio Converti

et al.

Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 329, P. 125115 - 125115

Published: Sept. 18, 2023

Two new highly-efficient and eco-friendly biosorbents comprised of magnetite, chitosan Chlorella vulgaris (MCC) or Arthrospira platensis (MCA) were prepared in such a way to be easily separated reused for removing different classes antibiotics as tetracycline (TC), ciprofloxacin (CIP) amoxicillin (AMX) from wastewater. They characterized using SEM, FTIR TGA. Biosorption experiments performed investigate the impact pH, biosorbent dosage, initial antibiotic concentration, contact time, concentration background electrolytes (NaCl, KCl CaCl2) on adsorption. Both biocomposites showed outstanding performance removal. Equilibrium data modelled Langmuir, Freundlich, Temkin, Dubinin-Radushkevich adsorption isotherms, among which first one gave best fit, with maximum TC, CIP AMX capacities 834.0, 394.9, 150.8 mg/g MCA 831.1, 374.2, 140.2 MCC, respectively. To follow time-evolution, pseudo-first-order, pseudo-second-order intraparticle diffusion kinetic models tested, second proved best-fitting one. Thermodynamic parameters revealed that was spontaneous endothermic. regenerated through microwave-assisted treatment repeatedly up four cycles, losing at equilibrium by no >7, 4 9 %, This study suggests both may effective sustainable alternatives commercial adsorbents

Language: Английский

Citations

45
Adsorptive removal of paracetamol from aqueous media: A review of adsorbent materials, adsorption mechanisms, advancements, and future perspectives DOI
Md. Aminul Islam, Mazen K. Nazal, Muhammad Sajid

et al.

Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: 396, P. 123976 - 123976

Published: Jan. 10, 2024

Language: Английский

Citations

31
Photocatalytic Degradation of Antibiotics via Exploitation of a Magnetic Nanocomposite: A Green Nanotechnology Approach toward Drug-Contaminated Wastewater Reclamation DOI Creative Commons
Noor Zulfiqar, Raziya Nadeem, Othman Al Musaimi

et al.

ACS Omega, Journal Year: 2024, Volume and Issue: unknown

Published: Feb. 6, 2024

In the quest for eco-conscious innovations, this research was designed sustainable synthesis of magnetite (Fe3O4) nanoparticles, using ferric chloride hexahydrate salt as a precursor and extract Eucalyptus globulus leaves both reducing capping agent, which are innovatively applied photocatalyst photocatalytic degradation antibiotics "ciprofloxacin amoxicillin". Sugar cane bagasse biomass, sugar pyrolyzed biochar, magnetite/sugar biochar nanocomposite were also synthesized via environmentally friendly organized approaches. The optimum conditions ciprofloxacin amoxicillin found to be pH 6 5 amoxicillin, dosage (0.12 g), concentration (100 mg/L), irradiation time (240 min). maximum efficiencies percentage (73.51%) > (63.73%) (54.57%) (74.07%) (61.55%) (50.66%) magnetic nanocomposites, respectively. All catalysts demonstrated favorable performance; however, "magnetite/SCB biochar" exhibited most promising results among various employed in antibiotics. Kinetic studies performed, notably, pseudo-first-order chemical reaction showed best Through comprehensive comparative analysis three unique photocatalysts, identified optimal efficient treatment drug-contaminated wastewater, thus amplifying practical significance findings. recycling nanoparticles through separation, coupled with their functional modification integration into composite materials, holds significant application potential

Language: Английский

Citations

31
Advancing pharmaceutical wastewater treatment: A comprehensive review on application of catalytic membrane reactor-based hybrid approaches DOI
Ramesh Kumar,

Elinah Awino,

Dorcas Wanja Njeri

et al.

Journal of Water Process Engineering, Journal Year: 2024, Volume and Issue: 58, P. 104838 - 104838

Published: Feb. 1, 2024

Language: Английский

Citations

30