Combined Catalytic Conversion of NOx and VOCs: Present Status and Prospects DOI Open Access
Mengzhao Li, Rui Wang

Materials, Journal Year: 2024, Volume and Issue: 18(1), P. 39 - 39

Published: Dec. 25, 2024

This article presents a comprehensive examination of the combined catalytic conversion technology for nitrogen oxides (NOx) and volatile organic compounds (VOCs), which are primary factors contributing to formation photochemical smog, ozone, PM2.5. These pollutants present significant threat air quality human health. The examines reaction mechanism interaction between photocatalytic NH3-SCR oxidation technology, highlighting limitations existing techniques, including catalyst deactivation, selectivity issues, regeneration methods, environmental impacts catalysts. Furthermore, anticipates prospective avenues research, underscoring necessity development bifunctional catalysts capable concurrently transforming NOx VOCs across broad temperature spectrum. review encompasses multitude integrated selective reduction (SCR), oxidation, low-temperature plasma biological purification technology. highlights further research into design principles, structure–activity relationships, performance evaluations in real industrial environments. is required develop more efficient, economical, environmentally friendly waste gas treatment technologies. concludes by outlining importance collaborative management strategies VOC emissions potential achieving these goals.

Language: Английский

Mechanisms of Individual and Simultaneous Adsorption of Antibiotics and Dyes onto Halloysite Nanoclay and Regeneration of Saturated Adsorbent via Cold Plasma Bubbling DOI Creative Commons

Stefania Giannoulia,

Irene‐Eva Triantaphyllidou,

Athanasia G. Tekerlekopoulou

et al.

Nanomaterials, Journal Year: 2023, Volume and Issue: 13(2), P. 341 - 341

Published: Jan. 13, 2023

Halloysite nanoclay (HNC) was examined as an adsorbent for the individual and simultaneous removal of antibiotic enrofloxacin (ENRO) methylene blue (MB) from aqueous solutions, alongside its regeneration via cold atmospheric plasma (CAP) bubbling. Initially, batch kinetics isotherm studies were carried out, while effect several parameters evaluated. Both ENRO MB adsorption onto HNC better described by Langmuir model, with maximum capacity being 34.80 27.66 mg/g, respectively. A Pseudo-second order model fitted experimental data satisfactorily, suggesting chemisorption (through electrostatic interactions) prevailing mechanism, whereas also controlled film diffusion. In binary system, presence seemed to act antagonistically ENRO. The saturated regenerated inside a CAP microbubble reactor re-tested applying new cycles. bubbling able efficiently regenerate low energy requirements (16.67 Wh/g-adsorbent) in contrast Fenton oxidation. Most importantly, enhanced CAP-regenerated (compared raw HNC), when applied cycles, indicated activation during process. present study provides green, sustainable highly effective alternative water remediation where pharmaceutical dyes co-exist.

Language: Английский

Citations

16

Understanding of the synergy effect of DBD plasma discharge combined to photocatalysis in the case of Ethylbenzene removal: Interaction between plasma reactive species and catalyst DOI
Nacer Belkessa,

Abdelkrim Bouzaza,

Aymen Amine Assadi

et al.

Journal of environmental chemical engineering, Journal Year: 2023, Volume and Issue: 11(5), P. 110640 - 110640

Published: Aug. 2, 2023

Language: Английский

Citations

12

Plasma catalytic degradation of naphthalene using activated alumina in cycled storage-discharge mode: A study of mass transfer-reaction process in pores DOI
Xiao Cui, Yifan Li, Chuanguo Yang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159345 - 159345

Published: Jan. 1, 2025

Language: Английский

Citations

0

Layered Double Oxides for VOC Degradation in Nonthermal Plasma: Composition and Structural Effect DOI
Xiang Li, Min Xu, Xiaoqiang Zhang

et al.

Langmuir, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 25, 2025

The ever-increasing emissions of volatile organic compounds (VOCs) from industrial activities pose significant environmental and health risks. Nonthermal plasma (NTP) degradation technology has emerged as a prominent method for VOC due to the mild reaction conditions but demands an efficient catalyst high product conversion. This study presents mesoporous layered NiFe double silicate fabricated by between 13X zeolite hydroxides (LDHs). Under NTP conditions, catalysts achieved 90% ethyl acetate conversion with CO2 selectivity 45%, maintaining stability over 400 min. performance demonstrates synergy in adsorption offers more active catalytic sites on situ-generated catalyst. Simulation results also suggested that two-dimensional sheet structure effectively localizes electric field surface therefore may facilitate generation species adsorption. work provides pathway design highly stable applications.

Language: Английский

Citations

0

Transition metal doped zeolite as acid/base catalyst for efficient ozone decomposition DOI
Jialin Li, Jing Wang, Tonghui Cai

et al.

Surfaces and Interfaces, Journal Year: 2025, Volume and Issue: unknown, P. 106173 - 106173

Published: March 1, 2025

Language: Английский

Citations

0

Non-thermal plasma assisted catalytic water splitting for clean hydrogen production at near ambient conditions DOI

Wenping Li,

Mingyuan Cao, Shijun Meng

et al.

Journal of Cleaner Production, Journal Year: 2023, Volume and Issue: 387, P. 135913 - 135913

Published: Jan. 5, 2023

Language: Английский

Citations

9

Impact of Residual Surface Charges on Energy Coupling of Packed-Bed Dielectric Barrier Discharge: A Simulation Investigation DOI
Chenhua Ren, Bangdou Huang,

Yi Luo

et al.

Plasma Chemistry and Plasma Processing, Journal Year: 2023, Volume and Issue: 43(6), P. 1613 - 1632

Published: Aug. 22, 2023

Language: Английский

Citations

9

Unveiling the positive effect of mineral induced natural organic matter (NOM) on catalyst properties and catalytic dechlorination performance: An experiment and DFT study DOI

Police Anil Kumar Reddy,

Thillai Govindaraja Senthamaraikannan, Dong–Hee Lim

et al.

Water Research, Journal Year: 2022, Volume and Issue: 222, P. 118871 - 118871

Published: July 15, 2022

Language: Английский

Citations

11

Fabrication of core–shell Fe3O4@SiO2/graphite catalyst to improve the charge separation for enhanced photocatalytic toluene oxidation DOI

Le Xu,

Tianlong Yu,

Shuang Li

et al.

Applied Surface Science, Journal Year: 2024, Volume and Issue: unknown, P. 161294 - 161294

Published: Sept. 1, 2024

Language: Английский

Citations

2

Application of Unconventional External-Field Treatments in Air Pollutants Removal over Zeolite-Based Adsorbents/Catalysts DOI Open Access

Haodan Cheng,

Xiaoning Ren,

Yuan Yao

et al.

Catalysts, Journal Year: 2023, Volume and Issue: 13(12), P. 1461 - 1461

Published: Nov. 23, 2023

Zeolite-based materials are widely used as adsorbents and catalysts for purifying air pollutants like NOx VOCs due to abundant pore structure, regular distribution, numerous ion exchange sites. Thermal treatment is a necessary procedure both removing impurities in pores promoting the metal active dispersed evenly before zeolite-based adsorbents/catalysts were applied NOx/VOCs. Nevertheless, conventional thermal field (i.e., high-temperature calcination, purging, etc.) takes large energy consumption. In contrast, unconventional external-field treatments such non-thermal plasma microwave show significant advantages of high efficiency, low consumption well pollution, which substitute traditional many fields. this paper, roles or adsorption/catalysis NOx/VOCs reviewed from three aspects assisting activation materials, cooperative catalysis process, zeolites synthesis. The reasons improving textural properties, sites, performance, etc. illuminated detail. Moreover, influences various parameters power, time, temperature, on above elaborated. It hoped that review could provide some advanced guidance researchers develop highly efficient materials.

Language: Английский

Citations

5