ACS Agricultural Science & Technology,
Journal Year:
2023,
Volume and Issue:
3(11), P. 1103 - 1112
Published: Nov. 7, 2023
The
traditional
use
of
soluble
phosphate
fertilizers
in
agriculture
depletes
finite
global
supplies
and
accounts
for
a
major
nonpoint
source
phosphorus
pollution.
In
potting
experiments,
we
tested
whether
two
modified
softwood
biochars
that
strongly
bind
could
fertilize
romaine
"Dragoon"
lettuce
while
retarding
P
leaching.
Modifications
included
doping
with
MgO
(MgO-BC),
or
binding,
postpyrolysis,
cationic
polymer,
poly(diallyldimethylammonium)
chloride
(pDADMAC-BC).
former
sorbs
via
coordination
nanoparticles
coatings
the
latter
through
enhanced
anion
exchange.
presterilized
soil
(SS)
was
mixture
fine
sand
peat
moss.
test
sets
contained
(3
2%
g-C/g-SS)
either
preadsorbed
added
along
same
amount
phosphate,
all
at
rate
180
120
mg-P/pot.
We
also
containing
P-rich
mineral
dolomite.
Control
SS
amended
unmodified
biochar,
without
MgO-BC
but
phosphate.
All
pots
were
fertilized
weekly
phosphate-free
Hoagland
nutrient
solution.
Sets
biochars,
gave
dramatically
higher
plant
yields
than
control
dolomite
sets.
leached
small
fraction
(0.1–23%)
relative
to
controls
Plant
uptake
Mg
high
MgO-doped
induced
toxic
response
when
those
incorporated
uniformly
powdered
form.
Arbuscular
mycorrhizal
fungi
some
decreased
root:shoot
ratio
otherwise
had
little
impact.
results
indicate
can
appreciably
reduce
leaching
providing
bioavailable
crop
growth.
Langmuir,
Journal Year:
2024,
Volume and Issue:
40(8), P. 4255 - 4266
Published: Feb. 19, 2024
Phosphate
pollution
is
a
very
challenging
problem
for
the
water
environment.
mixed
with
in
various
ways
causes
eutrophication.
To
sustain
life
aquatic
systems,
phosphate
ions
must
be
cleaned.
Therefore,
it
important
to
remove
wastewater.
Here,
an
adsorption
method
has
been
tried
removal
of
phosphate.
MOF-76
(Ce),
cerium-based
metal–organic
framework,
was
synthesized
by
hydrothermal
method.
Since
metal
oxides
are
known
successful
adsorption,
CeO2
nanoparticles
were
also
obtained
pyrolysis
this
MOF
structure.
The
efficiencies
both
adsorbents
compared.
characterization
methods
(SEM,
FTIR,
XRD,
and
TGA)
applied
adsorbents.
kinetic,
isotherm,
thermodynamics
studies
experimental
results.
At
298
K,
capacity
(Ce)
higher
than
that
CeO2,
according
Langmuir
isotherm
qm
values.
values
72.97
55.71
mg/g,
respectively.
Both
follow
pseudo
second-order
kinetic
model.
It
found
pH-selective
property
adsorption.
No
change
observed
pH.
In
terms
thermodynamics,
endothermic
reaction
valid