A tutorial on solid-phase analytical derivatization in sample preparation applications
Journal of Chromatography Open,
Journal Year:
2024,
Volume and Issue:
6, P. 100157 - 100157
Published: July 14, 2024
Solid-phase
analytical
derivatization
is
a
versatile
sample
preparation
technique
that
enhances
analysis
accuracy,
efficiency,
reproducibility,
and
sensitivity.
The
combines
the
advantages
of
solid-phase
extraction,
providing
approach
for
analysing
analytes
with
various
functional
groups
in
complex
matrices.
Analytical
used
group
involves
modifying
structure
an
analyte
to
enhance
sensitivity
specificity.
one-pot
procedure
extraction.
In
presence
acids,
it
can
derivatize
phenols,
carboxylic
other
analytes.
Furthermore,
increases
reaction
rate
carbonyl
compounds,
making
easier
extract
aldehydes
ketones
rapidly.
This
utilises
electrophoresis,
chromophores,
fluorophores,
detection
It
initially
began
as
batch
but
has
now
developed
into
automated,
microextraction,
method.
highly
efficient
due
significant
excess
derivatizing
reagent
relative
analyte,
along
pre-impregnation
reagents,
which
speed
up
process
compared
traditional
solution-based
derivatization.
tutorial
aims
provide
detailed
insights
practical
aspects
implementing
method
development
discuss
prospects
future
trends.
Language: Английский
Emerging deep eutectic solvents for food waste valorization to achieve sustainable development goals: Bioactive extractions and food applications
Sayani Mavai,
No information about this author
Aarti Bains,
No information about this author
Kandi Sridhar
No information about this author
et al.
Food Chemistry,
Journal Year:
2024,
Volume and Issue:
462, P. 141000 - 141000
Published: Aug. 26, 2024
Language: Английский
Comprehensive Review on Chromatographic Analysis of Flavonoids in Fruits
Journal of Chromatography Open,
Journal Year:
2025,
Volume and Issue:
unknown, P. 100209 - 100209
Published: Feb. 1, 2025
Language: Английский
Quality Control Strategies for Differentiation of Kalanchoe Species
Phytochemical Analysis,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 11, 2025
ABSTRACT
Kalanchoe
species
products
are
commercially
available
in
local
markets
and
by
internationally
accessible
online
retailers
may
exhibit
quality
issues
because
of
misidentification
from
similar
common
names
anatomical
similarities
among
related
used
as
feedstock.
This
study
proposes
an
approach
using
UPLC‐MS/MS
E
HPTLC,
coupled
with
morphoanatomical
analysis
to
establish
chemical
composition
pattern
data
for
five
species.
Subsequently,
the
methods
were
validated
analyzing
commercial
purported
contain
100%
extract.
HPTLC
profiles
demonstrated
that
quercetin
kaempferol
derivatives
identified
primary
flavonoids
genuine
plant
extracts.
Chemometric
showed
clear
differences
no
between
extracts
products.
Different
patterns
anticlinal
epidermal
cell
walls
midrib
leaves
shape
arrangement
vascular
bundles
petiole
micro‐morphological
observed.
Evaluation
samples
revealed
labeled
containing
did
not
match
pharmacobotanical
nor
These
can
be
considered
important
tools
control
derived
Language: Английский
Quantitative Assessment and Chemical Characterization of Secondary Metabolites from Ethnomedicinal Plant Bergenia ciliata using ATR-FTIR and NMR Techniques
Asian Journal of Chemistry,
Journal Year:
2025,
Volume and Issue:
37(5), P. 1159 - 1168
Published: April 30, 2025
Bergenia
ciliata,
an
ethnomedicinal
plant,
is
widely
recognized
for
its
therapeutic
potential.
This
study
aimed
to
conduct
a
comprehensive
phytochemical
screening
and
chemical
characterization
of
root
rhizome
extracts
using
ATR-FTIR
NMR
techniques.
Preliminary
qualitative
analysis
was
performed
on
prepared
in
aqueous,
ethyl
acetate
methanol
solvents
identify
bioactive
compounds.
The
presence
tannins,
flavonoids,
saponins,
alkaloids,
glycosides,
steroids,
terpenoids
other
secondary
metabolites
confirmed.
Fourier
transform
infrared
spectroscopy
(ATR-FTIR)
employed
determine
the
functional
groups
present
extracts.
spectral
revealed
key
including
hydroxyl
(-OH),
carbonyl
(C=O),
aliphatic
nitriles
(C≡N)
amides,
which
contribute
medicinal
properties
plant.
Peaks
corresponding
stretching
bending
vibrations
were
identified,
highlighting
various
constituents.
Furthermore,
metabolite
profiling
proton
nuclear
magnetic
resonance
(1H
NMR)
provided
insights
into
structure
Bergenin,
compound
known
pharmacological
activities,
detected
along
with
metabolites.
results
this
confirm
diverse
composition
supporting
traditional
applications.
integration
provides
reliable
approach
characterizing
plant-based
compounds,
facilitating
further
their
Language: Английский
Phytochemicals from Eucalyptus camaldulensis and Coleus barbatus Control Eragrostis plana in Horticulture
Horticulturae,
Journal Year:
2025,
Volume and Issue:
11(3), P. 291 - 291
Published: March 7, 2025
Eragrostis
plana
is
an
invasive
plant
in
horticulture
that
extremely
difficult
to
control.
The
use
of
chemical
herbicides
causes
weed
resistance
and
contamination
crops.
Therefore,
leaf
extracts
obtained
from
E.
camaldulensis,
C.
barbatus,
L.
leucocephala
were
evaluated
the
control
this
weed.
leaves
by
infusion,
pressurized
liquid
extraction,
ultrasound-assisted
extraction
using
water
or
ethanol
as
solvents,
which
are
green
methods.
phytochemicals
camaldulensis
barbatus
reduced
germination
growth
weed,
reaching
up
97%
inhibition
germination,
52%
reduction
shoot
length,
46%
root
length
for
germinated
seeds.
Language: Английский
Molecularly imprinted polymers-based sensors in phytochemical analysis: a comprehensive review of recent advances and applications
Essential Chem,
Journal Year:
2025,
Volume and Issue:
2(1), P. 1 - 23
Published: April 1, 2025
Language: Английский
A novel Co/Zn-ferrite molecularly imprinted polymer-based electrochemical assay for sensing of gallic acid in plant extracts, wine, and herbal supplement
Analytical and Bioanalytical Chemistry,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 5, 2024
Language: Английский
Flavonoids analysis in citrus peels by UPLC-Q-TOF-MS/MS and its antioxidant and anti-inflammation activity
Yulin Zheng,
No information about this author
Yingxian WU,
No information about this author
Biying Wang
No information about this author
et al.
Food Chemistry Advances,
Journal Year:
2024,
Volume and Issue:
5, P. 100853 - 100853
Published: Dec. 1, 2024
Language: Английский
Horticultural Plants and By-Products as Sources of Biological Active Compounds
Horticulturae,
Journal Year:
2024,
Volume and Issue:
10(11), P. 1133 - 1133
Published: Oct. 24, 2024
Horticultural
plants
and
their
by-products
from
vegetable,
herb
fruit
cultivation,
as
well
food
industry
operations,
warehouses,
retail
trade,
are
abundant
in
biologically
active
compounds
such
polyphenols,
flavonoids,
carotenoids,
vitamins
minerals
[...]
Language: Английский