Impact of Supercritical Carbon Dioxide on Pore Structure and Gas Transport in Bituminous Coal: An Integrated Experiment and Simulation
Kui Dong,
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Zhiyu Niu,
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Shaoqi Kong
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et al.
Molecules,
Journal Year:
2025,
Volume and Issue:
30(6), P. 1200 - 1200
Published: March 7, 2025
The
injection
of
CO2
into
coal
reservoirs
occurs
in
its
supercritical
state
(ScCO2),
which
significantly
alters
the
pore
structure
and
chemical
composition
coal,
thereby
influencing
adsorption
diffusion
behavior
methane
(CH4).
Understanding
these
changes
is
crucial
for
optimizing
CH4
extraction
improving
sequestration
efficiency.
This
study
aims
to
investigate
effects
ScCO2
on
structure,
bonds,
mechanisms
bituminous
provide
insights
reservoir
stimulation
storage.
By
utilizing
high-pressure
adsorption,
low-pressure
gas
(LP-CO2-GA),
Fourier-transform
infrared
spectroscopy
(FTIR),
reactive
force
field
molecular
dynamics
(ReaxFF-MD)
simulations,
this
examines
multi-scale
at
nano-
levels.
following
results
were
found:
Pore
Structure
Evolution:
After
treatment,
micropore
volume
increased
by
19.1%,
specific
surface
area
11.2%,
while
mesopore
14.4%
5.7%,
respectively.
Chemical
Composition
Changes:
content
aromatic
structures,
oxygen-containing
functional
groups,
hydroxyl
groups
decreased,
aliphatic
structures
increased.
Specific
included
an
increase
(CH2)n,
2H,
1H,
secondary
alcohol
(-C-OH)
phenol
(-C-O)
Car-Car
Car-H
bonds
decreased.
Mechanisms
Volume
evolves
through
three
distinct
phases:
Swelling
Phase:
Breakage
low-energy
generates
new
micropores.
Aromatic
expansion
reduces
intramolecular
spacing
but
increases
intermolecular
spacing,
causing
a
decrease
volume.
Early
Dissolution
Continued
bond
breakage
volume,
released
partially
occupy
pores,
converting
some
mesopores
Later
Minimal
alterations
occur,
weakened
π-π
interactions
van
der
Waals
forces
between
layers
result
further
expansion.
Impact
Diffusion:
Changes
directly
affect
migration.
In
early
stages
interaction,
shrinkage
mean
square
displacement
(MSD)
self-diffusion
coefficient
CH4.
However,
as
reaction
progresses,
enhances
diffusion,
ultimately
provides
fundamental
understanding
how
modifies
transport
properties,
offering
theoretical
guidance
enhanced
recovery
strategies.
Language: Английский
Carbon Dioxide (CO<sub>2</sub>) Mineralization in Solid Waste-Based Grouting Slurry: A Review
Safiwu Alhaji,
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Bei Gao,
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Wenjie Zhu
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et al.
Journal of Geoscience and Environment Protection,
Journal Year:
2025,
Volume and Issue:
13(01), P. 121 - 155
Published: Jan. 1, 2025
Language: Английский
Research on innovative PVC-steel wire mesh composite confined spontaneous combustion coal gangue concrete: Experiment and finite element analysis
Hongbo Guan,
No information about this author
Keling Wang,
No information about this author
Benxin Hao
No information about this author
et al.
Structures,
Journal Year:
2025,
Volume and Issue:
74, P. 108603 - 108603
Published: March 8, 2025
Language: Английский
Investigation of Coal-Based Solid Waste Grouting Materials for Environmental Repair
Yiqian Jin,
No information about this author
S. H. Zhang,
No information about this author
Suping Peng
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et al.
Journal of Building Engineering,
Journal Year:
2025,
Volume and Issue:
unknown, P. 112334 - 112334
Published: March 1, 2025
Language: Английский
Influence of carbonized fly ash on the early-age shrinkage of blended cement paste with different water-to-binder ratios
Faliang Gao,
No information about this author
Zhi Ge,
No information about this author
Shiyang Zhang
No information about this author
et al.
Case Studies in Construction Materials,
Journal Year:
2025,
Volume and Issue:
unknown, P. e04607 - e04607
Published: April 1, 2025
Language: Английский
Towards carbon neutrality: A comprehensive study on the utilization and resource recovery of coal-based solid wastes
International Journal of Coal Science & Technology,
Journal Year:
2025,
Volume and Issue:
12(1)
Published: April 19, 2025
Abstract
Coal-based
soild
wastes
(CBSWs)
are
industrial
byproducts
that
can
be
harmful
to
the
environment.
The
exploitation
and
utilization
of
CBSWs
offer
societal
advantages
such
as
resource
conservation,
pollution
reduction,
cost-effective
production.
However,
environmentally
sustainable
management
remains
a
worldwide
challenge
due
substantial
production
volume
limited
disposal
capacity
CBSWs.
physicochemical
properties
summarized,
including
fly
ash,
coal
gangue
gasification
slag.
It
also
presents
current
global
applications
status
resources
examines
market
supply
demand.
Subsequently,
paper
provides
an
overview
studies
on
ways
utilise
CBSWs,
highlighting
primary
avenues
which
mainly
from
fields
chemical
materials,
metallurgy
agriculture.
Furthermore,
comparative
evaluation
various
methods
for
recovery
is
conducted,
outlining
their
respective
disadvantages.
future
development
recycling
processes
discussed.
review
concludes
while
there
growing
need
attention
in
recycling,
its
will
involve
combination
both
large-scale
treatment
refinement
processes.
aims
references
insights
effective
environmental
protection
Future
direction
focus
collaborative
emphasizing
high-value
utilization.
In
addition,
establish
comprehensive
database
based
on-site
practices,
explore
solutions
reduce
transportation
costs,
improve
during
process.
Language: Английский