Transition metal nanomaterial-based electrocatalysts for water and CO2 electrolysis: preparation, catalytic activity, and prospects DOI Creative Commons
Govindhan Maduraiveeran

Frontiers in Energy Research, Journal Year: 2024, Volume and Issue: 12

Published: Oct. 24, 2024

The production of hydrogen (H 2 ) and multi-carbon fuels through water electrolysis (oxygen evolution reaction (OER)/hydrogen (HER)) water–CO co-electrolysis (OER/CO reduction (CO RR)), respectively, is supposed to be the emergent energy carrier. These electrochemical processes are essential chemical conversion pathways that initiate changes toward renewable energy. This review summarizes systematic design earth-abundant transition metal-based nanomaterials their electrocatalytic activities reactions such as OER, HER, CO RR. primary focus on fabricating highly effective, low-cost, advanced nanostructures for both OER/HER OER/CO RR systems. Developing synthetic strategies surface morphology-controlled nanostructured electrocatalysts, engineering electrode surface, enhancing activity, understanding relationship between intrinsic catalytic activity preparation approaches or precursor choices, exploring mechanism focused on. Furthermore, current challenges, figure-of-merit, prospects described. study may open new opportunities develop shape-controlled high-performance electrocatalysts storage reactions.

Language: Английский

Hydrogen production, storage, transportation and utilization for energy sector: A current status review DOI
Shahbaz Ahmad, Abid Ullah, Ayesha Samreen

et al.

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 101, P. 113733 - 113733

Published: Sept. 16, 2024

Language: Английский

Citations

37
Silver Decorated Copper Coordination Polymer for the Electroreduction of CO2 to Hydrocarbon Liquid Fuels DOI

Ann Mariella Babu,

Sobin Mathew, Anitha Varghese

et al.

Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 116675 - 116675

Published: April 1, 2025

Language: Английский

Citations

0
Unraveling the Role of Pressure, Oxidation State, and Morphology in CO2 Electroreduction to C2+ Products over Copper Oxides DOI Creative Commons
Asghar Ali, Ali S. Alnaser

Nanoscale Advances, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

This study provides compelling experimental evidence of the synergistic effects reaction pressure, oxidation state, and catalyst morphology on C2+ selectivity copper (Cu) oxide catalysts in electrochemical CO2 reduction (ECR). We employed femtosecond laser structuring thermal treatments to synthesize Cu(0), Cu(i), Cu(ii), a mixed state Cu(x) with characteristic micro- nano-morphologies. The optimal pressure for maximizing productivity aqueous bicarbonate media was established by assessing products at different imposed pressures custom-designed, pressurizable two-compartment cell. Among thermally produced Cu(i) only unstructured exhibiting ethylene gas-phase selectivity. Nanostructuring enhanced such that all three states could produce ethylene. More importantly, nanostructured comprising well-dispersed exhibited as well ethane production - associated undercoordinated Cu stabilizing intermediates facilitating charge transfer yield longer products. work important insights into key factors influencing Cu-based catalysts, establishing basis an informed design high-energy density

Language: Английский

Citations

0
Review on Principal and Applications of Temporal and Spatial Beam Shaping for Ultrafast Pulsed Laser DOI Creative Commons
Jong-Hyun Kim, Hae-Woon Choi

Photonics, Journal Year: 2024, Volume and Issue: 11(12), P. 1140 - 1140

Published: Dec. 4, 2024

Ultrafast or ultrashort pulsed lasers have become integral in numerous industrial applications due to their high precision, non-thermal interaction with materials, and ability induce nonlinear absorption. These characteristics expanded use microfabrication, semiconductor processing, automotive engineering, biomedical fields. Temporal pulse shaping reduces laser durations, often shorter timescales than many physical chemical processes, enabling greater control. Meanwhile, spatial improves efficiency precision micro- nanofabrication applications. Advances optical parametric amplifiers (OPAs) chirped-pulse (CPAs) allowed for more refined temporal shaping, ensuring the preservation of peak power while achieving durations. Additionally, light modulators (SLMs) facilitated sophisticated beam which, when combined ultrafast lasers, supports like computer-generated holography nanoscale fabrication. developments underscore growing utility versatility both research contexts.

Language: Английский

Citations

1
Transition metal nanomaterial-based electrocatalysts for water and CO2 electrolysis: preparation, catalytic activity, and prospects DOI Creative Commons
Govindhan Maduraiveeran

Frontiers in Energy Research, Journal Year: 2024, Volume and Issue: 12

Published: Oct. 24, 2024

The production of hydrogen (H 2 ) and multi-carbon fuels through water electrolysis (oxygen evolution reaction (OER)/hydrogen (HER)) water–CO co-electrolysis (OER/CO reduction (CO RR)), respectively, is supposed to be the emergent energy carrier. These electrochemical processes are essential chemical conversion pathways that initiate changes toward renewable energy. This review summarizes systematic design earth-abundant transition metal-based nanomaterials their electrocatalytic activities reactions such as OER, HER, CO RR. primary focus on fabricating highly effective, low-cost, advanced nanostructures for both OER/HER OER/CO RR systems. Developing synthetic strategies surface morphology-controlled nanostructured electrocatalysts, engineering electrode surface, enhancing activity, understanding relationship between intrinsic catalytic activity preparation approaches or precursor choices, exploring mechanism focused on. Furthermore, current challenges, figure-of-merit, prospects described. study may open new opportunities develop shape-controlled high-performance electrocatalysts storage reactions.

Language: Английский

Citations

0