Progress in Preparation and Application of Titanium Sub-Oxides Electrode in Electrocatalytic Degradation for Wastewater Treatment DOI Open Access
Siyuan Guo, Zhicheng Xu,

Wenyu Hu

et al.

Catalysts, Journal Year: 2022, Volume and Issue: 12(6), P. 618 - 618

Published: June 6, 2022

To achieve low-carbon and sustainable development it is imperative to explore water treatment technologies in a carbon-neutral model. Because of its advantages high efficiency, low consumption, no secondary pollution, electrocatalytic oxidation technology has attracted increasing attention tackling the challenges organic wastewater treatment. The performance an system depends mainly on properties electrodes materials. Compared with instability graphite electrodes, expenditure noble metal boron-doped diamond hidden dangers titanium-based oxide titanium sub-oxide material been characterized as ideal choice anode due unique crystal electronic structure, including conductivity, decent catalytic activity, intense physical chemical stability, corrosion resistance, cost, long service life, etc. This paper systematically reviews electrode preparation Magnéli phase research progress electrochemical advanced recent years, technical difficulties highlighted. Future directions are further proposed process optimization, modification, application expansion. It worth noting that sub-oxides have played very important roles degradation. There doubt will become indispensable materials future.

Language: Английский

Anodic oxidation of ciprofloxacin antibiotic and real pharmaceutical wastewater with Ti/PbO2 electrocatalyst: Influencing factors and degradation pathways DOI
Mohammad Mahdi Emamjomeh,

Amir Shabanloo,

Amin Ansari

et al.

Journal of Water Process Engineering, Journal Year: 2023, Volume and Issue: 57, P. 104662 - 104662

Published: Dec. 12, 2023

Language: Английский

Citations

33

Synergistic activation of persulfate by ultrasound/PbO2 anodic oxidation system for effective degradation of naproxen, a toxic and bio-recalcitrant pollutant: Process optimization and application for pharmaceutical wastewater DOI

Amir Shabanloo,

Hamed Akbari, Amir Adibzadeh

et al.

Journal of Water Process Engineering, Journal Year: 2023, Volume and Issue: 54, P. 103915 - 103915

Published: June 21, 2023

Language: Английский

Citations

28

Loading of zinc oxide nanoparticles from green synthesis on the low cost and eco-friendly activated carbon and its application for diazinon removal: isotherm, kinetics and retrieval study DOI Creative Commons

Peyman Pourali,

Yousef Rashtbari,

Aylar Behzad

et al.

Applied Water Science, Journal Year: 2023, Volume and Issue: 13(4)

Published: March 19, 2023

Abstract Diazinon (DZN) has been reported as an important pesticide with wide application in agriculture. The entry of these compounds into water resources brought serious environmental problems due to their resistance biodegradation; thus, this study was considered be done explore the process DZN uptake and influence effective parameters. performed experimentally on a laboratory scale. Investigating structure morphology nanocomposite based different analyses, i.e., FE-SEM, FTIR, XRD. experiments Box–Behnken scheme were by surveying four operating parameters (pH, contact time, dose, concentration). Optimization experiment design software using response surface method analysis proposed model. removal efficiency obtained 100% under optimal conditions including pH = 5, dose 0.83 g/L, reaction time 55 min, concentration 5 mg/L. Considering high correlation coefficient R 2 (0.9873) $$R_{{{\text{Adj}}}}^{{2}}$$ R Adj 2 (0.9725), model (quadratic) approved. results indicative conforming kinetic pseudo-second-order correspondence isotherm Freundlich ( 0.997). Based results, adsorption AC–ZnO could introduced efficient eco-friendly technique remove DZN.

Language: Английский

Citations

27

Improved electrocatalytic degradation of toxic and resistant picric acid with PbO2-ZrO2 anode; New insight into degradation mechanism by a DFT approach DOI

Mitra Zargarian,

Amin Ansari, Hossein Masoumi

et al.

Journal of environmental chemical engineering, Journal Year: 2023, Volume and Issue: 11(3), P. 110280 - 110280

Published: June 1, 2023

Language: Английский

Citations

26

Enhanced favipiravir drug degradation using the synergy of PbO2-based anodic oxidation and Fe-MOF-based cathodic electro-Fenton DOI

Parva Ashrafi,

Davood Nematollahi,

Amir Shabanloo

et al.

Environmental Research, Journal Year: 2024, Volume and Issue: 262, P. 119883 - 119883

Published: Aug. 29, 2024

Language: Английский

Citations

10

Degradation and mineralization of diazinon pesticide by G/PbO2 anodic oxidation process DOI Creative Commons
Mohammad Reza Samarghandi, Alireza Rahmani, Mohammad Rasool Khazaei

et al.

Case Studies in Chemical and Environmental Engineering, Journal Year: 2024, Volume and Issue: 9, P. 100685 - 100685

Published: March 12, 2024

The high toxicity and environmental stability of organochlorine pesticides have made organophosphorus (OPPs) more preferred today. Diazinon is one the most widely used insecticides in group OPPs, which has environment causes neurobehavioral side effects case long-term exposure to humans. present study aims fabricate PbO2 electrocatalyst on a graphite sheet (G/PbO2) use it as non-active anode for diazinon degradation. effect independent variables such solution pH, current applied electrodes, initial concentration reaction time removal efficiency pesticide was studied. SEM XRD results showed that lead dioxide crystals β-PbO2 phase were formed compact pyramidal clusters surface anode. At pH 8, significantly improved. However, mild operating conditions (solution = 5 0.4 A), with concentrations 20 100 mg/L after 90 min 100% 70%, respectively. After optimizing intermediates LC-MS analysis, proposed degradation pathway mineralization presented. confirm anodic oxidation can be an effective method pesticide.

Language: Английский

Citations

9

Mechanism of enhanced degradation of antibiotic wastewater by three-dimensional electrocatalytic oxidation system: Coconut shell biochar as particle electrode DOI

Qiaona Xie,

Siyi Li,

Yiting Lian

et al.

Journal of Water Process Engineering, Journal Year: 2024, Volume and Issue: 64, P. 105749 - 105749

Published: July 1, 2024

Language: Английский

Citations

9

Degradation of Antiviral Drug Favipiravir Using UV, UV/H2O2, and Photocatalysis with Co-Doped ZnS Quantum Dots: Operational Parameters, Kinetic Studies, and Toxicity Assessment DOI Creative Commons
Bahriye Eryıldız Yesir, Hale Özgün, Mustafa Evren Erşahin

et al.

Langmuir, Journal Year: 2025, Volume and Issue: unknown

Published: March 5, 2025

Antiviral drugs, in particular those used to treat COVID-19, have been categorized as emerging pollutants recent years due their persistent presence water/wastewater. They identified environmental matrices all over the world, proving that current treatment methods cannot eliminate them from In this study, degradation of favipiravir (FAV) and ecotoxicity changes different water were investigated using UV, UV/H2O2, UV/Co-doped ZnS quantum dots (QDs) photocatalytic processes. The effects initial FAV concentration, matrices, pH, H2O2 catalyst amount on rate evaluated. Initial concentrations (50, 100, 150 μg/L) a slight effect rate. matrix composition significantly reduced rates efficiencies for QDs processes following order: wastewater plant (WWTP) effluent > tap (TW) distilled (DW). pH (4.0, 5.0, 7.0, 9.0) had remarkable enhanced 86.3 98.1% with increasing 4.0 9.0 ionization degree UV process. maximum was obtained at 7.0 removal 93.9 100% UV/H2O2 processes, respectively. Transformation products determined toxicity algae increased 50 μg/L water. Growth inhibition 50, 15.1, 33.3, 36.3% 96 h, respectively, without any treatment. After 60 min process, growth decreased below 0.5% regardless concentration. Overall, process is effective degrading aqueous matrices; however, an step required remove natural organic matter actual matrices.

Language: Английский

Citations

1

Bisphenol A adsorption using modified aloe vera leaf-wastes derived bio-sorbents from aqueous solution: kinetic, isotherm, and thermodynamic studies DOI
Farzad Hashemzadeh,

Seyed Hamed Derakhshandeh,

Mohammad Mahdi Soori

et al.

International Journal of Environmental Health Research, Journal Year: 2023, Volume and Issue: 34(4), P. 2031 - 2051

Published: May 9, 2023

Reactive-oxygen-species are produced more often in the body when bisphenol A (BPA), an endocrine-disrupting-substance, is present. In this investigation, bio-sorbents from aqueous solution adapted Aloe-vera were used to survey BPA removal. leaf wastes create activated carbon, which was then analyzed using Fourier transform infrared (FTIR), Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Thermogravimetric analysis (TGA), Zeta potential, and Brunauer-Emmett-Teller (BET) techniques. It revealed that adsorption process adheres Freundlich isotherm model with R2>0.96 pseudo-second-order kinetic R2>0.99 under ideal conditions (pH = 3, contact time 45 min, concentration of 20 mg.L−1, adsorbent 2 g.L−1). After five-cycle, efficacy removal greater than 70%. The phenolic-chemicals industrial-effluent can be accomplished assistance a cost-effective effective-approach.

Language: Английский

Citations

20

Construction of the multi-layer TiO2-NTs/Sb-SnO2/PbO2 electrode for the highly efficient and selective oxidation of ammonia in aqueous solution: Characterization, performance and mechanism DOI
Zhiyong Zhang, Jianqiao Liu, Huiying Ai

et al.

Journal of environmental chemical engineering, Journal Year: 2023, Volume and Issue: 11(3), P. 109834 - 109834

Published: March 30, 2023

Language: Английский

Citations

19