Fundamental Insights into Photoelectrochemical Carbon Dioxide Reduction: Elucidating the Reaction Pathways DOI
Lujie Zuo, Yuchao Deng, Lu Chen

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(22), P. 16795 - 16833

Published: Oct. 31, 2024

The photoelectrochemical (PEC) reduction of carbon dioxide (CO2) to produce solar fuels presents a sustainable strategy mitigate CO2 emissions and alleviate the global energy crisis. While significant research efforts have been dedicated optimizing cell system configurations designing efficient photoelectrocatalysts, there remains lack in-depth understanding pathway. This review provides comprehensive overview fundamental insights PEC with focus on pathways from perspectives final products adsorption modes. First, key challenges are identified analyzed, including initial activation CO2, competitive hydrogen evolution reaction (HER), complex carbon–carbon (C–C) coupling process. then examines aspects process, covering state-of-the-art devices, their operational principles, methodologies for capturing intermediates. through concerted or sequential proton–electron transfer mechanisms is discussed in detail. Furthermore, potential systematically categorized basis distinct modes that drive insertion, carbon-coordinated oxygen-coordinated monodentate adsorption, bidentate oxygen vacancies. Detailed leading formation C1, C2, C3 compounds elucidated, an emphasis strategies enhance selectivity toward C1 C2+ products. In particular, aids catalyst design. For production, design focuses promoting activation, as rate-determining step (RDS) activation. contrast, formation, aim increase intermediate concentration, thereby enhancing lateral interaction intermediates, which crucial C–C coupling. Finally, summarizes future breakthroughs electron, interfacial, ionic pathways, offering into ongoing technologies.

Language: Английский

Recent Advances in Electrochemical, Photochemical, and Photoelectrochemical Reduction of CO2 to C2+ Products DOI

Gyeong Ho Han,

Junbeom Bang,

Gaeun Park

et al.

Small, Journal Year: 2023, Volume and Issue: 19(16)

Published: Jan. 2, 2023

Abstract Environmental problems such as global warming are one of the most prominent challenges. Researchers investigating various methods for decreasing CO 2 emissions. The reduction reaction via electrochemical, photochemical, and photoelectrochemical processes has been a popular research topic because energy it requires can be sourced from renewable sources. converts stable molecules into useful products CO, CH 4 , C H 5 OH. To obtain economic benefits these products, is important to convert them hydrocarbons above . Numerous investigations have demonstrated uniqueness CC coupling Cu‐based catalysts conversion electrocatalysis. Herein, principle semiconductors photocatalysis briefly introduced, followed by description obstacles 2+ production. This review presents an overview mechanism hydrocarbon formation along with advances in improvement, direction, comprehension processes.

Language: Английский

Citations

82
Review on strategies for improving the added value and expanding the scope of CO2 electroreduction products DOI
Minghang Jiang, Huaizhu Wang, Mengfei Zhu

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(10), P. 5149 - 5189

Published: Jan. 1, 2024

This review summarizes promising strategies including the design of catalysts and construction coupled electrocatalytic reaction systems, aimed at achieving selective production various products from CO 2 electroreduction.

Language: Английский

Citations

75
Fabrication and optimization of perovskite-based photoanodes for solar-driven CO2 photoelectroreduction to formate DOI Creative Commons
José Antonio Abarca, Ivan Merino‐Garcia, Guillermo Díaz‐Sainz

et al.

Catalysis Today, Journal Year: 2024, Volume and Issue: 429, P. 114505 - 114505

Published: Jan. 2, 2024

The photoelectrochemical reduction of CO2 to value-added products represents a promising strategy for mitigating emissions. However, further research efforts need be undertaken enable the technology scale-up, including design and fabrication efficient photoelectrodes capable yielding substantial photogenerated current densities. In this work, photoanode combining commercial calcium titanate perovskite (CaTiO3) BiVO4 layers coated onto transparent FTO substrate by automated spray pyrolysis is proposed. Different configurations are tested, with most favourable results achieved when positioned as top layer back illumination. optimization catalytic loading also assessed, finding an optimal at 1 mg cm-2 CaTiO3 3 BiVO4, resulting in impressive density –71 mA –1.8 V vs. Ag/AgCl. This then integrated into electrolyzer continuous visible light-driven gas phase formate, obtaining concentration 63.8 g L-1, Faradaic Efficiency 79.1%, solar-to-fuel conversion efficiency 7.6%. These represent significant advancement development photoanodes, offering promise future scalability processes.

Language: Английский

Citations

10
Emerging Single-Atom Catalysts and Nanomaterials for Photoelectrochemical Reduction of Carbon Dioxide to Value-Added Products: A Review of the Current State-of-the-Art and Future Perspectives DOI
Shaurya Verma, Ashish Yadav

Energy & Fuels, Journal Year: 2023, Volume and Issue: 37(8), P. 5712 - 5742

Published: April 4, 2023

Rapid industrialization has resulted in a drastic increase the consumption of natural resources, particularly fossil fuels. Fossil fuels form coal, gas, oils, etc. have been extensively used to meet ever-increasing energy demands, resulting adverse environmental effects. Massive fuel led enormous carbon dioxide (CO2) emissions, adversely impacting environment through global warming. Photoelectrochemical (PEC) reduction CO2 into valuable fuels, for instance, formic acid (HCOOH), methanol (CH3OH), ethanol (C2H5OH), etc., which combines merits both photochemical and electrochemical techniques, considered as potential approach address issue mitigation. Single-atom catalysts (SACs) along with emerging nanomaterials (NMTs) photoelectrode composite materials present an effective avenue augment PEC owing their well-defined structures almost complete atom utilization. The review focuses on application various SACs NMTs that are advantageous efficient such HCOOH, CH3OH, C2H5OH, monoxide. mechanism pertaining utilization incident light overcome band gap produce photogenerated charge carriers contribute also elucidated. At outset, some challenges opportunities lie ahead boosting SAC's performance discussed.

Language: Английский

Citations

22
Paired electrosynthesis design strategy for sustainable CO2 conversion and product upgrading DOI

Mengyao Gong,

Changsheng Cao, Qi‐Long Zhu

et al.

EnergyChem, Journal Year: 2023, Volume and Issue: 5(6), P. 100111 - 100111

Published: Nov. 1, 2023

Language: Английский

Citations

18
Electron-rich Cu0-Cu2O heterogeneous interface constructed via controllable electrochemical reconstruction for a single CO2 deep-reduction product ethylene DOI
Weiqi Liu,

Peiyao Bai,

Shilin Wei

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 348, P. 123831 - 123831

Published: April 24, 2024

Language: Английский

Citations

8
Efficient CO2 reduction to formate using a Cu-doped BiVO4 electrocathode in a WO3 photoanode-assisted photoelectrocatalytic system DOI

Fanfan Gao,

Huimin Yang, Nan Cheng

et al.

Journal of Electroanalytical Chemistry, Journal Year: 2023, Volume and Issue: 930, P. 117146 - 117146

Published: Jan. 6, 2023

Language: Английский

Citations

13
Supercritical carbon dioxide technology in synthesis, modification, and recycling of battery materials DOI Creative Commons

Yiyao Han,

Xiaozheng Zhou,

Ruyi Fang

et al.

Carbon Neutralization, Journal Year: 2023, Volume and Issue: 2(2), P. 169 - 185

Published: March 1, 2023

Abstract For pursuing the ambitious goals in burgeoning electric vehicles, portable electronic devices, and energy storage sectors, Li‐ion batteries (LIBs) are considered as one of most promising electrochemical power sources because their high density moderate cost. Particularly, improvement battery materials recycling spent LIBs receiving great attention since sustainable approaches for synthesis, modification, crucial factors to successful large‐scale implementation LIBs. In this regard, supercritical carbon dioxide (SC‐CO 2 ), which possesses many merits, such environmentally friendly, low‐cost, individual chemical environment, especially its unique physical properties, has been employed solvent reaction medium synthesis modification diverse functional materials. review, we mainly aim at compiling applications SC‐CO technology electrode well First, properties principles highlighted. Second, latest progresses design with assistance technique summarized. Finally, challenges, future directions, perspectives on development by proposed.

Language: Английский

Citations

13
Recent Progress and Perspective of the Electrochemical Conversion of Carbon Dioxide to Alcohols DOI Creative Commons

Alamelu Kaliyaperumal,

P. D. Gupta,

Yadavalli Satya Sivaram Prasad

et al.

ACS Engineering Au, Journal Year: 2023, Volume and Issue: 3(6), P. 403 - 425

Published: Oct. 25, 2023

Since the industrial revolution, energy demand has increased, resulting in an increase atmospheric carbon dioxide concentration. Increasing CO2 concentration contributes to global warming and climate change. Strategies alleviate emissions by reducing fossil fuel usage replacing them with renewable sources have been devised resolve this issue. In addition, there are several ways reduce concentrations including capture, utilization, sequestration (CCUS). Electrochemical conversion of is a value-added approach as well producing valuable chemicals, feedstocks, building blocks. review, we report on electrochemical reduction alcohols progress made over past five years. Alcohols critical liquid fuels higher density, ease storage, transportation. Herein, discuss possible mechanisms for converting various electrocatalysts employed conversion. Detailed studies compared performances based faradaic efficiency, current product selectivity, stability. Furthermore, types devices that can be used alcohol also discussed. Finally, challenges perspectives further research presented.

Language: Английский

Citations

13
Tailoring multi-layered BiVO4/WO3 photoanodes for an efficient photoelectrochemical gas-phase solar water splitting DOI
Ivan Merino‐Garcia,

Sara Crespo,

Maite Perfecto-Irigaray

et al.

Catalysis Today, Journal Year: 2024, Volume and Issue: 432, P. 114581 - 114581

Published: Feb. 17, 2024

Language: Английский

Citations

4