Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 116642 - 116642
Published: April 1, 2025
Language: Английский
Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 116642 - 116642
Published: April 1, 2025
Language: Английский
Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 461, P. 141947 - 141947
Published: Feb. 17, 2023
Language: Английский
Citations
129Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 318, P. 123970 - 123970
Published: May 3, 2023
Language: Английский
Citations
51Journal of Hazardous Materials, Journal Year: 2023, Volume and Issue: 447, P. 130795 - 130795
Published: Jan. 14, 2023
Language: Английский
Citations
43Journal of Cleaner Production, Journal Year: 2024, Volume and Issue: 444, P. 141177 - 141177
Published: Feb. 12, 2024
Language: Английский
Citations
22The Science of The Total Environment, Journal Year: 2024, Volume and Issue: 942, P. 173736 - 173736
Published: June 4, 2024
Improved treatment of per- and polyfluoroalkyl substances (PFAS) in water is critically important light the proposed United States Environmental Protection Agency (USEPA) drinking regulations at ng L−1 levels. The addition peroxymonosulfate (PMS) during electrochemical oxidation (EO) can remove destroy PFAS, but levels have not been tested, PMS itself be toxic. objective this research was to test peroxydisulfate (PDS, an alternative PMS) activation by boron-doped diamond (BDD) electrodes for level perfluorooctanoic acid (PFOA) degradation. influence PDS concentration, temperature, real matrix effects, PFOA concentration on PDS-EO performance were systematically examined. Batch reactor experiments revealed that 99.8 % degraded 69.1 defluorination achieved, confirming mineralization. Scavenging implied sulfate radicals (SO4–) played a more role degradation than HO, 1O2, or electrons (e−). Further identification transformation products liquid chromatography-mass spectrum (LC-MS) analysis established plausible pathways. corroborates direct electron transfers electrode initiate SO4– improves overall cleaving CC bond between C7F15 COOH moieties PFOA, leading possible such as F−. perfluoroalkyl oxidized resulting formation shorter chain perfluorocarboxylic acids (e.g., perfluorobutanoic [PFBA]), with eventual mineralization CO2 At environmentally relevant low initial 100 99 achieved. slightly affected less removal observed river sample (91 %) compared tests conducted Milli-Q (99 %). Overall, EO provided destructive approach elimination PFOA.
Language: Английский
Citations
18Chemical Engineering Journal, Journal Year: 2022, Volume and Issue: 454, P. 140232 - 140232
Published: Nov. 9, 2022
Language: Английский
Citations
54Journal of environmental chemical engineering, Journal Year: 2023, Volume and Issue: 11(3), P. 109693 - 109693
Published: March 15, 2023
Language: Английский
Citations
30Chemosphere, Journal Year: 2024, Volume and Issue: 356, P. 141877 - 141877
Published: April 3, 2024
Language: Английский
Citations
14Journal of Colloid and Interface Science, Journal Year: 2022, Volume and Issue: 634, P. 586 - 600
Published: Dec. 17, 2022
Language: Английский
Citations
36Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 471, P. 144368 - 144368
Published: June 28, 2023
Language: Английский
Citations
20