Anodic oxidation using 3D carbon felt/PbO 2 anode: a electron transfer-mediated system for degradation of Rhodamine B DOI
Yitong Li,

Xinyu Sui,

Shiyu Geng

et al.

Environmental Technology, Journal Year: 2025, Volume and Issue: unknown, P. 1 - 18

Published: Feb. 2, 2025

This study investigates the use of porous structured carbon felt (CF) as a substrate for preparation lead dioxide (CF/PbO2) anode electrochemical oxidation Rhodamine B (RhB). Compared to traditional titanium-based (Ti/PbO2) and graphite sheet-based (GS/PbO2) anodes, CF/PbO2 exhibited superior electrocatalytic activity, achieving RhB degradation efficiency exceeding 99%. After 10 cycles, activity remained robust, with over 97%. Fluorescence spectroscopy, quenching experiments, tests indicate that behaviour on GS/PbO2 anodes was governed by direct electron transfer, while indirect via •HO radicals pivotal Ti/PbO2 anode. LC-MS analysis identified intermediates degradation, contributing proposed pathway. provides an efficient organic pollutants in water.

Language: Английский

Degradation of polyvinyl chloride microplastics via electrochemical oxidation with a CeO2–PbO2 anode DOI

Ziqi Ning,

Xiaoyue Duan, Yitong Li

et al.

Journal of Cleaner Production, Journal Year: 2023, Volume and Issue: 432, P. 139668 - 139668

Published: Nov. 10, 2023

Language: Английский

Citations

41

Enhanced electrocatalytic removal of tetracycline using dual carbon material combined particle electrodes in a three-dimensional electrochemical system: Degradation pathway and mechanism DOI

Xiaotang Xu,

Xiaolan Zeng,

Cunkuan Zhang

et al.

Journal of Cleaner Production, Journal Year: 2023, Volume and Issue: 419, P. 138257 - 138257

Published: July 25, 2023

Language: Английский

Citations

40

A detailed electrochemical study of anti-malaria drug hydroxychloroquine: Application of a highly porous 3D multi-metal oxide carbon felt/β-PbO2-ZrO2−MoOx electrode for its electrocatalytic degradation DOI

Parva Ashrafi,

Davood Nematollahi,

Amir Shabanloo

et al.

Electrochimica Acta, Journal Year: 2023, Volume and Issue: 458, P. 142555 - 142555

Published: May 8, 2023

Language: Английский

Citations

36

Anodic oxidation of ciprofloxacin antibiotic and real pharmaceutical wastewater with Ti/PbO2 electrocatalyst: Influencing factors and degradation pathways DOI
Mohammad Mahdi Emamjomeh,

Amir Shabanloo,

Amin Ansari

et al.

Journal of Water Process Engineering, Journal Year: 2023, Volume and Issue: 57, P. 104662 - 104662

Published: Dec. 12, 2023

Language: Английский

Citations

35

Electrochemical advanced oxidation of 2,4-D herbicide and real pesticide wastewater with an integrated anodic oxidation/heterogeneous electro-Fenton process DOI
Hadi Rahimzadeh, Abdollah Dargahi,

Amir Shabanloo

et al.

Journal of Water Process Engineering, Journal Year: 2023, Volume and Issue: 56, P. 104429 - 104429

Published: Oct. 19, 2023

Language: Английский

Citations

31

Synergistic activation of persulfate by ultrasound/PbO2 anodic oxidation system for effective degradation of naproxen, a toxic and bio-recalcitrant pollutant: Process optimization and application for pharmaceutical wastewater DOI

Amir Shabanloo,

Hamed Akbari, Amir Adibzadeh

et al.

Journal of Water Process Engineering, Journal Year: 2023, Volume and Issue: 54, P. 103915 - 103915

Published: June 21, 2023

Language: Английский

Citations

28

Improved electrocatalytic degradation of toxic and resistant picric acid with PbO2-ZrO2 anode; New insight into degradation mechanism by a DFT approach DOI

Mitra Zargarian,

Amin Ansari, Hossein Masoumi

et al.

Journal of environmental chemical engineering, Journal Year: 2023, Volume and Issue: 11(3), P. 110280 - 110280

Published: June 1, 2023

Language: Английский

Citations

26

Applications of bismuth-based nanoparticles for the removal of pollutants in wastewater: a review DOI
Shan Jiang, Yihang Zhang, Jianyu Gong

et al.

Environmental Science Nano, Journal Year: 2024, Volume and Issue: 11(4), P. 1332 - 1367

Published: Jan. 1, 2024

This review discusses the characteristics and synthesis methods of Bi-based NPs. It delves into removal efficiency in wastewater, emphasizing traditional/emerging strategies to enhance performance, mechanisms, toxicology, challenges.

Language: Английский

Citations

11

Degradation and mineralization of diazinon pesticide by G/PbO2 anodic oxidation process DOI Creative Commons
Mohammad Reza Samarghandi, Alireza Rahmani, Mohammad Rasool Khazaei

et al.

Case Studies in Chemical and Environmental Engineering, Journal Year: 2024, Volume and Issue: 9, P. 100685 - 100685

Published: March 12, 2024

The high toxicity and environmental stability of organochlorine pesticides have made organophosphorus (OPPs) more preferred today. Diazinon is one the most widely used insecticides in group OPPs, which has environment causes neurobehavioral side effects case long-term exposure to humans. present study aims fabricate PbO2 electrocatalyst on a graphite sheet (G/PbO2) use it as non-active anode for diazinon degradation. effect independent variables such solution pH, current applied electrodes, initial concentration reaction time removal efficiency pesticide was studied. SEM XRD results showed that lead dioxide crystals β-PbO2 phase were formed compact pyramidal clusters surface anode. At pH 8, significantly improved. However, mild operating conditions (solution = 5 0.4 A), with concentrations 20 100 mg/L after 90 min 100% 70%, respectively. After optimizing intermediates LC-MS analysis, proposed degradation pathway mineralization presented. confirm anodic oxidation can be an effective method pesticide.

Language: Английский

Citations

9

Degradation of Antiviral Drug Favipiravir Using UV, UV/H2O2, and Photocatalysis with Co-Doped ZnS Quantum Dots: Operational Parameters, Kinetic Studies, and Toxicity Assessment DOI Creative Commons
Bahriye Eryıldız Yesir, Hale Özgün, Mustafa Evren Erşahin

et al.

Langmuir, Journal Year: 2025, Volume and Issue: unknown

Published: March 5, 2025

Antiviral drugs, in particular those used to treat COVID-19, have been categorized as emerging pollutants recent years due their persistent presence water/wastewater. They identified environmental matrices all over the world, proving that current treatment methods cannot eliminate them from In this study, degradation of favipiravir (FAV) and ecotoxicity changes different water were investigated using UV, UV/H2O2, UV/Co-doped ZnS quantum dots (QDs) photocatalytic processes. The effects initial FAV concentration, matrices, pH, H2O2 catalyst amount on rate evaluated. Initial concentrations (50, 100, 150 μg/L) a slight effect rate. matrix composition significantly reduced rates efficiencies for QDs processes following order: wastewater plant (WWTP) effluent > tap (TW) distilled (DW). pH (4.0, 5.0, 7.0, 9.0) had remarkable enhanced 86.3 98.1% with increasing 4.0 9.0 ionization degree UV process. maximum was obtained at 7.0 removal 93.9 100% UV/H2O2 processes, respectively. Transformation products determined toxicity algae increased 50 μg/L water. Growth inhibition 50, 15.1, 33.3, 36.3% 96 h, respectively, without any treatment. After 60 min process, growth decreased below 0.5% regardless concentration. Overall, process is effective degrading aqueous matrices; however, an step required remove natural organic matter actual matrices.

Language: Английский

Citations

1