Tuijin Jishu/Journal of Propulsion Technology,
Journal Year:
2023,
Volume and Issue:
44(3), P. 3988 - 4006
Published: Nov. 22, 2023
This
systematic
review
delves
into
the
mechanisms
of
catalytic
reactions
on
K10
clay,
synthesizing
a
wealth
experimental
and
computational
insights
to
offer
comprehensive
understanding.
The
versatility
clay
is
dissected
across
diverse
reactions,
including
esterification,
aldol
condensation,
methane
activation,
biomass
conversion,
redox
ester
hydrolysis,
tandem
reactions.
Thematic
analysis
unravels
broad
spectrum
applications
for
emphasizing
need
nuanced
understanding
reaction-specific
mechanisms.
A
critical
comparative
approaches
showcases
their
complementary
roles
in
unraveling
intricacies
catalysis.
quality
assessment
process
underscores
methodological
rigor
individual
studies,
guiding
interpretation
findings.
Practical
implications
environmental
remediation,
fine
chemical
synthesis,
industrial
processes
are
discussed,
accompanied
by
identified
gaps
that
delineate
future
research
directions.
not
only
advances
but
also
serves
as
template
explorations
dynamic
realm
materials.
With
foundation
built
rigorous
thoughtful
integration
findings,
this
aims
inspire
continued
innovation
investigation
field
catalysis
research.
Discover Chemistry.,
Journal Year:
2024,
Volume and Issue:
1(1)
Published: Nov. 26, 2024
The
present
research
showcases
the
synthesis
of
novel
metal
complexes
including
Cu
(II),
Ni
Co
VO
and
Zn
(II)
derived
from
Acetyl
Acetone-4-Imino-2,
3-Dimethyl-1-Phenyl-3-Pyrazolin-5-One
2-Aminothiazole.
Various
analytical
techniques
such
as
Powder
X-ray
diffraction
(PXRD),
Scanning
electron
microscopy
(SEM)
for
morphological
studies,
UV–Vis
spectroscopy,
FT-IR,
1H-NMR
elemental
analysis,
Electron
spin
resonance
(ESR),
magnetic
susceptibility
measurements
were
employed
to
thoroughly
characterize
these
complexes.
analysis
susceptibility,
spectra
suggests
a
square
planar
geometry
most,
except
complex
[VOL]Cl,
which
exhibits
rectangular
pyramidal
geometry.
Cyclic
voltammetry
[VOL]Cl
[CuL]Cl
in
MeCN
reveals
that
coordinated
ligands
play
role
influencing
redox
potential
ions.
XRD
data
SEM
images
indicate
composite
materials
consist
small-sized
grains
with
polycrystalline
structure.
This
study
also
explores
antimicrobial
properties
schiff
base
using
biologically
active
ligands.
exhibit
enhanced
activity
compared
free
ligands,
demonstrated
by
minimum
inhibitory
concentration
(MIC)
values
against
various
bacterial
fungal
strains.
These
findings
highlight
coordination
drug
design
set
stage
future
investigations
into
their
therapeutic
applications.
conference,
Journal Year:
2024,
Volume and Issue:
unknown, P. 1 - 13
Published: March 3, 2024
Abstract
Production
of
Renewable
Diesel
(RD)
and
Sustainable
Aviation
Fuels
(SAF)
from
bio
/
natural
oils
has
seen
significant
investment
in
recent
years,
stemming
worldwide
government
mandated
need
to
reduce
fossil
fuel
CO2
emissions.
New
investments
have
occurred
retrofitting
adapting
existing
refinery
hydroprocessing
infrastructure
process
or
coprocess
blended
with
crudes
produce
RD
SAF.
This
stems
the
fact
that
hydrocarbon
(HC)
structures
fit
within
mid-distillate
product
such
as
diesel
aviation
well
these
processes
are
optimized
for
removal
unwanted
Sulfur
Oxygen
removal.
In
Corrosion/2023,
authors
introduced
a
molecular
mechanistic
model
quantify
FFA
corrosion
function
temperature
concentration.
exploited
similarity
carboxylic
acids,
akin
naphthenic
acids
found
conventional
crude
unit
streams,
especially
case
unsaturated
FFA.
A
key
aspect
modeling
is
inhibitive
role
hydrogen
presence
Iron
sulfide
species.
While
do
not
contain
sulfur
compounds,
reactive
species
thiols
sulfides
coprocessing
applications
provides
an
easy
pathway
provide
formation
potentially
protective
nano
barrier
layer
FeS.
Further,
FeS
acts
catalyst
towards
dissociation
H2
atomic
H
subsequent
reduction
through
hydrogen.
threshold
partial
pressure
required
ensure
kinetically
dominant
when
compared
acid
Fe.
Residence
time
another
parameter
will
impact
propensity
inhibition
considered
development
prediction
model.
framework
incorporating
effects
pressure,
residence
S
concentration
proposed
assessing
various
commonly
utilized
renewable
applications.
Tuijin Jishu/Journal of Propulsion Technology,
Journal Year:
2023,
Volume and Issue:
44(3), P. 3988 - 4006
Published: Nov. 22, 2023
This
systematic
review
delves
into
the
mechanisms
of
catalytic
reactions
on
K10
clay,
synthesizing
a
wealth
experimental
and
computational
insights
to
offer
comprehensive
understanding.
The
versatility
clay
is
dissected
across
diverse
reactions,
including
esterification,
aldol
condensation,
methane
activation,
biomass
conversion,
redox
ester
hydrolysis,
tandem
reactions.
Thematic
analysis
unravels
broad
spectrum
applications
for
emphasizing
need
nuanced
understanding
reaction-specific
mechanisms.
A
critical
comparative
approaches
showcases
their
complementary
roles
in
unraveling
intricacies
catalysis.
quality
assessment
process
underscores
methodological
rigor
individual
studies,
guiding
interpretation
findings.
Practical
implications
environmental
remediation,
fine
chemical
synthesis,
industrial
processes
are
discussed,
accompanied
by
identified
gaps
that
delineate
future
research
directions.
not
only
advances
but
also
serves
as
template
explorations
dynamic
realm
materials.
With
foundation
built
rigorous
thoughtful
integration
findings,
this
aims
inspire
continued
innovation
investigation
field
catalysis
research.
