Enhanced activation of sulfite by CoFe2O4-loaded with WS2 nanosheet with smooth surface for elimination and detoxification of metronidazole DOI
Zeyu Li, Siying Liu, Tianqi Jiang

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: unknown, P. 114544 - 114544

Published: Oct. 1, 2024

Language: Английский

Carbon nanotube supported cobalt nickel sulphide nano-catalyst for degradation of chloroquine phosphate with peroxymonosulphate DOI
Keke Chen,

Qinyuan Tang,

Chunlin Dong

et al.

Environmental Technology, Journal Year: 2023, Volume and Issue: 45(25), P. 5465 - 5482

Published: Dec. 29, 2023

Carbon nanotubes supported cobalt nickel sulphide nanoparticles (nano-NiCo2S4@CNTs) were successfully prepared by a hydrothermal method as heterogeneous catalyst which can be used an activator of peroxymonosulphate (PMS) for the degradation chloroquine phosphate (CQP). Based on characterisation techniques, has excellent surface properties and structural stability. When different concentrations CQP treated with 0.2 g/L nano-NiCo2S4@CNTs 1.0 mM PMS, highest rate could reach 99.86% after 30 min. Under interference pH, common anions humic acid in water environment, reaction system still achieve high efficiency, showing anti-interference ability practical applicability. Furthermore, nano-NiCo2S4@CNTs/PMS system, according to identification results reactive oxygen species, free radical non-free pathway are responsible CQP, PMS mechanism activation was comprehensively proposed. Twelve intermediate products detected process, possible pathways This toxicity analysis demonstrates that formed during pose lower environmental risks compared original pollutant. In addition, using four cycles, removal efficiency remains above 80%, indicating reusability low metal ion leaching characteristics. Therefore, synthesised this research broad application prospects activating wastewater treatment.

Language: Английский

Citations

5
Synthesis of Fe-Loaded Biochar Obtained from Rape Straw for Enhanced Degradation of Emerging Contaminant Antibiotic Metronidazole DOI Open Access
Dongyuan Zhang, Lin Shi, Edwin Hena Dawolo

et al.

Water, Journal Year: 2024, Volume and Issue: 16(13), P. 1822 - 1822

Published: June 26, 2024

In this study, magnetic (Fe)-loaded biochar was successfully prepared by a simple impregnation pyrolysis method. Meanwhile, its degradation capability and mechanism for typical antibiotic metronidazole (MNZ) were systematically investigated under different conditions. The characterization of the synthesized material showed that specific surface area, pore diameter, volume changed significantly. Also, functional groups metal element Fe introduced on biochar, leading to better activate peroxymonosulfate (PMS). experiments removal MNZ in Fe-BC/PMS system can reach up 95.3% 60 min optimal Free-radical capture there several active species •OH, SO4•−, •O2−, 1O2 present catalyst synergistically degrade MNZ, among which SO4•− played major role; it also found be easily recycled still effective after uses. Further, main pathways include nitrohydroxylation, hydroxyethyl group deletion, carboxylation amino demethylation, oxidation, carboxylation. It is obvious magnetic-loaded Fe-BC, generated from waste rape straw crops, shows high catalytic performance pollutant degradation, providing an insight into recycling potential biomass field removal.

Language: Английский

Citations

1
Mechanistic and DFT studies on the degradation of metronidazole by cerium oxide-loaded iron-cobalt layered double hydroxide-activated calcium sulfite DOI
Siqian Chen,

Dedong Wu,

Haijiao Xie

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 357, P. 130058 - 130058

Published: Oct. 10, 2024

Language: Английский

Citations

1
Efficient sulfite activation with Mn(II)-doped γ-Fe2O3 enriched by surface oxygen vacancy for rapid iohexol abatement DOI
Jiamin Sun,

Z.-Q. Fang,

Xian‐Fa Zhang

et al.

Applied Surface Science, Journal Year: 2024, Volume and Issue: unknown, P. 162224 - 162224

Published: Dec. 1, 2024

Language: Английский

Citations

1
Selective Oxidation Based on Non-Radical Pathways Triggered by Mof-Derived Modifications: Sulfite Activation and Mechanism DOI
Bingzhi Liu, Haitao Lu, Honghao Huang

et al.

Published: Jan. 1, 2024

Download This Paper Open PDF in Browser Add to My Library Share: Permalink Using these links will ensure access this page indefinitely Copy URL DOI

Language: Английский

Citations

0
Sulfite Activation by Chitosan Modified Mof Derivatives Enhances the Non-Radical Pathway of Elimination of Organic Contaminants DOI
Bingzhi Liu, Haitao Lu, Honghao Huang

et al.

Published: Jan. 1, 2024

Language: Английский

Citations

0
Enhanced activation of sulfite by CoFe2O4-loaded with WS2 nanosheet with smooth surface for elimination and detoxification of metronidazole DOI
Zeyu Li, Siying Liu, Tianqi Jiang

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: unknown, P. 114544 - 114544

Published: Oct. 1, 2024

Language: Английский

Citations

0