Coalescing theoretical and experimental approaches for Schiff base and its copper complex as high-performing corrosion inhibitors for XC52 alloy DOI
Amar Benaissa, Mohamed Yazid Belghit, Gamil Gamal Hasan

et al.

Progress in Organic Coatings, Journal Year: 2024, Volume and Issue: 200, P. 109011 - 109011

Published: Dec. 18, 2024

Language: Английский

Study of the adsorption behavior of Schiff base-type planar conjugated corrosion inhibitors on metal surfaces using DFT calculations and MD simulations DOI

Yining Deng,

K. Liu, Ran Chen

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142423 - 142423

Published: April 1, 2025

Language: Английский

Citations

0
Corrosion Inhibition of Carbon Steel by Some Schiff Base Compounds in HCl and H2SO4 Solutions DOI

Maryam Iranpour,

Ali Babaei, Mojtaba Bagherzadeh

et al.

ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(14)

Published: April 11, 2024

Abstract The inhibition power of two Schiff bases on carbon steel corrosion in 1 M HCl and 0.5 H 2 SO 4 solutions has been investigated using weight loss, Tafel polarization, electrochemical impedance spectroscopy techniques. results revealed that increasing the concentration inhibitors acidic led to a higher efficiency. polarization curves indicated acted as mixed inhibitors, affecting both cathodic anodic reactions. adsorption surface followed Langmuir isotherm, various isotherm parameters such K ads , ΔG ΔH ΔS were determined at room temperature. Furthermore, effect temperature inhibitors′ performance was examined within range 25–45 °C. corrosion‐related activation energy, pre‐exponential factor (k), enthalpy, entropy calculated assess behavior. Scanning electron microscopy (SEM) employed examine some samples, revealing differences efficiency attributed chemical structure. highlighted highest medium 93.4 %, with corresponding free energy 39.51 KJ/mol indicating physical‐chemical inhibitor molecules. an enthalpy value −40.6 suggested exothermic absorption process. findings are presented discussed detail.

Language: Английский

Citations

1
Aromatic Metal Corrosion Inhibitors DOI Creative Commons

Jessica Roscher,

Dan Liu, Xuan Xie

et al.

Corrosion and Materials Degradation, Journal Year: 2024, Volume and Issue: 5(4), P. 513 - 560

Published: Oct. 31, 2024

Molecular inhibitors added to the corrosive medium attacking metallic materials are a well-established way of combating corrosion. The inhibitive action proceeds via adsorption inhibitor on surface be protected. Aromatic building blocks in play major role its protective action, and further details like substituents, heteroatoms, molecular geometry contribute. An overview focused aromatic is provided, aiming at identification particularly promising their mode action. Directions for research development pointed out conclusion.

Language: Английский

Citations

1
Comprehensive analysis of the corrosion inhibition effect of Houttuynia Cordata extract: experimental and theoretical research DOI

Pengjie Wang,

Zijie Tang,

Yuhao Song

et al.

Corrosion Engineering Science and Technology The International Journal of Corrosion Processes and Corrosion Control, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 6, 2024

Background Due to the low toxicity and easy decomposition of green plant extracts, they are gradually replacing traditional corrosion inhibitors. Generally, extracts have inhibition efficiency in corrosive media difficult exert effects. Therefore, it is urgent find efficient resources as Houttuynia cordata (HC) was used raw material performance mechanism on Q235 were studied 1.0 mol/L HCl solution. Methods The verified through weight loss electrochemical experiments. SEM + EDS, ATR-IR XPS detect analyse protective film formed surface after loss. DFT demonstrated adsorption sites reaction activity inhibitor, MD further mechanism. Significant Findings HC could spontaneously adsorb a stable film. With temperature increased, decreased gradually. At 293 K g/L, reach 96.97% experiment, simultaneously inhibit anodic cathodic reactions solution, followed Langmuir isotherm.

Language: Английский

Citations

1
Novel advancements in protection of steel surfaces using polystyrene supported nanoparticles of metallic zinc as sacrificial corrosion inhibitors DOI
Ahmed M.A. El Naggar, Esraa M. El‐Fawal,

Mohamed I. Abd el Karim

et al.

New Journal of Chemistry, Journal Year: 2024, Volume and Issue: 48(30), P. 13475 - 13491

Published: Jan. 1, 2024

Corrosion poses a significant challenge, causing severe damage to steel infrastructures across various industries, particularly those involved in delivering fossil fuel sources.

Language: Английский

Citations

0
Inhibition performance of gemini cationic surfactants for carbon steel in formation water: Electrochemical and computational investigations DOI
Amira E. El‐Tabey, A. Elaraby, A.S. El-Tabei

et al.

Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: 409, P. 125452 - 125452

Published: July 9, 2024

Language: Английский

Citations

0
Unveiling the potency of tetrahydropalmitine as a green anticorrosion material for 2024 aluminum alloy in acid-chloride environments DOI
Wilfred Emori,

Rita Emmanuel Odey,

Paul C. Okonkwo

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(5), P. 113809 - 113809

Published: Aug. 12, 2024

Language: Английский

Citations

0
Eco-friendly pyridine-derivatives for corrosion inhibition of carbon steel during acidic treatments: mechanistic insights from electrochemical, surface, and computational studies DOI Creative Commons

Rem Jalab,

Alankaa Al-Harbi,

Najamus Sahar Riyaz

et al.

Deleted Journal, Journal Year: 2024, Volume and Issue: 6(12)

Published: Nov. 25, 2024

Pyridine and urea derivatives have emerged as valuable corrosion platforms ascribed to exceptional coordination potential, environmental friendliness. Two novel structures of pyridine-carbamides (MS30 & MS31) were synthesized used green inhibitors for the carbon steel in 1M HCl. Electrochemical measurements determined increase efficiency with concentrations, reaching 95.3% 97.1% at 200 mg L −1 298 K MS30 MS31. Despite reduced performance increasing temperature 303 313 K, results revealed improved inhibition 323 K. At highest MS31 proved their influence maintaining 97.6% 93.4% efficiency, highlighting suitability treatments oilfield downhole regions. The adsorption both fitted Langmuir model was attributed chemisorption, inferred from thermodynamics. Corrosion kinetics activation energy also verified chemical interaction Fe–inhibitor complex. Spectroscopic surface evaluation interpreted surpassed metallic dissolution by through protective barrier formation, X-ray photoelectron spectroscopy (XPS) existence Fe–N bond. sustained viability human cells affirmed nontoxic nature after treatment 0.2 mL−1 compounds. DFT calculations that exhibited strong on metal (− 9.5 eV), classified chemisorption. Overall, experimental findings are well supported computational studies. These pioneering compounds introduced herein advance state-of-the-art inhibitors, providing high under challenging environments.

Language: Английский

Citations

0
Coalescing theoretical and experimental approaches for Schiff base and its copper complex as high-performing corrosion inhibitors for XC52 alloy DOI
Amar Benaissa, Mohamed Yazid Belghit, Gamil Gamal Hasan

et al.

Progress in Organic Coatings, Journal Year: 2024, Volume and Issue: 200, P. 109011 - 109011

Published: Dec. 18, 2024

Language: Английский

Citations

0