Catalytic Conversion of Carbon Dioxide to Propylene Carbonate: Catalyst Design and Industrialization Progress

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 1305 - 1340

Published: Jan. 7, 2025

Converting CO2 into valuable chemicals is an effective way to alleviate the high level of global CO2. The cycloaddition reaction and propylene oxide (PO) has atomic economy advantage environmental friendliness compared with traditional phosgene method carbonate (PC). Due chemical inertness CO2, catalysts are needed make proceed smoothly. Through rational design, a multifunctional catalyst that combines activation sites attack PO adsorption can be formed. At same time, use harmful substances reduced by making catalytic process more environmentally friendly. In this work, we discuss research progress synthesis PC from PO. Starting mechanism, system summarized perspective design. homogeneous catalysts, focus on effect composition performance. heterogeneous heterogenization (preparation methods), including supported, confined, polymerized catalysts. addition, promising photocatalysis biomass catalysis especially introduced. Finally, in order experimental results move toward industrial production, several problems existing industrialization discussed, production equipment, influence source, product/catalyst separation.

Language: Английский

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Two-Dimensional Cu(II)-MOF with Lewis Acid–Base Bifunctional Sites for Chemical Fixation of CO₂ and Bioactive 1,4-DHP Synthesis via Hantzsch Condensation

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(23), P. 10832 - 10842

Published: May 29, 2024

Five- and six-membered heterocycles containing nitrogen or oxygen have been considered as privileged scaffolds in organic chemistry the chemical industry because of their usage high-value commodities. Herein, we report a two-dimensional (2D) Cu(II)-based MOF catalyst, IITKGP-40, via strategic employment ample Lewis acid–base bifunctional sites (open metal nodes free pyrazine moieties) along pore wall. IITKGP-40 could convert toxic CO2 to cyclic carbonates an atom-economical manner under solvent-free conditions aromatic aldehyde bioactive 1,4-DHPs Hantzsch condensation. Exceptional catalytic performance (99%) turnover number mild reaction for fixation using sterically hindered styrene oxide, good-to-excellent yields wide range aldehydes toward 1,4-dihydropyridines (1,4-DHPs) make promising multipurpose heterogeneous catalyst. Moreover, demonstrate practical utility two biologically important drug molecules, diludine nitrendipine analogue, also synthesized. is recyclable at least three consecutive runs without significant loss activity, making it real-time applications.

Language: Английский

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Oxalamide-derived ionic polymer/carbon nanotube composites: Highly active heterogeneous catalyst for promoting cycloaddition of carbon dioxide to epoxides

Journal of CO2 Utilization, Journal Year: 2025, Volume and Issue: 92, P. 103026 - 103026

Published: Jan. 22, 2025

Language: Английский

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Bottom-up fabrication of DABCO-based bicationic ionic liquid-grafted MIL-101(Cr): Facilitating simultaneous activation of CO2 and epoxides for cyclic carbonate synthesis

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 354, P. 128851 - 128851

Published: July 20, 2024

Language: Английский

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The embedding of 1,8-diazabicyclo[5.4.0]undec-7-ene into hyper-crosslinked ionic polymers for efficient CO2 conversion at atmospheric pressure

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 130148 - 130148

Published: Oct. 1, 2024

Language: Английский

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Acid-Base Neutralization Strategy for Immobilization Amino Acid Ionic Liquid within Sulfonic Acid-based COF as a Switch for Selective Conversion of Epoxides

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(5), P. 113718 - 113718

Published: July 31, 2024

Language: Английский

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Multiple-site activation induced by guanidine ionic liquid decorated chromium (III) terephthalate for coupling of carbon dioxide with epoxides

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 687, P. 561 - 572

Published: Feb. 16, 2025

Language: Английский

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Facile Synthesis of Binuclear Imidazole-Based Poly(ionic liquid) via Monomer Self-Polymerization: Unlocking High-Efficiency CO2 Conversion to Cyclic Carbonate

Catalysts, Journal Year: 2025, Volume and Issue: 15(5), P. 406 - 406

Published: April 22, 2025

Strategic utilization of carbon dioxide as both a mitigation tool and sustainable C1 feedstock represents pivotal pathway toward green chemistry. Although poly(ionic liquid)s (PILs) exhibit promise in CO2 conversion, conventional divinylbenzene (DVB) cross-linked architectures are limited by reduced ionic density accessibility active sites. Herein, we reported binuclear imidazolium-functionalized PIL catalyst (P-BVIMCl), synthesized through simple self-polymerization process, derived from rationally designed liquid monomers formed quaternization 1,4-bis(chloromethyl)benzene with N-vinylimidazole. The dual sites P-BVIMCl-quaternary ammonium cation (N+) nucleophilic chloride anion (Cl−) synergistically enhanced adsorption/activation epoxide ring-opening. Under optimal preparation conditions (100 °C, 24 h, water/ethanol = 1:3 (v/v), 10 wt% AIBN initiator) reaction 2.0 MPa CO2, mmol epichlorohydrin, 6.7 loading, 3.0 h), P-BVIMCl catalyzed the synthesis glycerol carbonate (GLC) yield up to 93.4% selectivity 99.6%, maintaining activity close 90% after five cycles. Systematic characterization functional theory (DFT) calculations confirmed synergistic activation mechanism. This work established paradigm for constructing high-ionic-density catalysts molecular engineering, advancing development high-performance PILs industrial valorization.

Language: Английский

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Multifunctional ionic covalent triazine framework as heterogeneous catalysts for efficient CO2 cycloaddition

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 359, P. 130579 - 130579

Published: Nov. 17, 2024

Language: Английский

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The effects of mixed metal oxide catalysts on the synthesis of cyclic carbonates from epoxides under atmospheric CO2 pressure.

Published: March 19, 2024

One use of CO2 as a starting material in organic transformations is the synthesis cyclic carbonates and polycarbonates. Due to low reactivity CO2, this transformation must be carried out presence an efficient catalyst. Although several catalytic systems have been developed last decade, reducing pressure at which reaction remains one main challenges process. In context, present work, we describe activity mixed metal oxides (MMOs) from (1 atm) epoxides 70 °C. The these materials catalysts represents great advantage since they are highly stable economical can reused cycles.

Language: Английский

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