Published: Jan. 1, 2024
Language: Английский
Published: Jan. 1, 2024
Language: Английский
Solar Energy, Journal Year: 2024, Volume and Issue: 275, P. 112640 - 112640
Published: May 25, 2024
Language: Английский
Citations
19Chemical Engineering Science, Journal Year: 2025, Volume and Issue: unknown, P. 121361 - 121361
Published: Feb. 1, 2025
Language: Английский
Citations
3Small, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 23, 2025
Abstract A polyacrylamide gel method has been used to synthesize a variety of polyvalent‐transition‐metal‐doped Ni position high entropy spinel oxides (Ni 0.2 Zn Mg Cu Co )Al 2 O 4 ‐800 °C (A ) on the basis NiAl , and catalytic activity is studied under synergistic action peroxymonosulfate (PMS) activation simulated sunlight. The containing polyvalent transition metals 2+ can effectively activate PMS efficiently degrade levofloxacin (LEV) tetracycline hydrochloride (TCH) sunlight irradiation. After 90 min light exposure, degradation percentages LEV (50 mg L −1 TCH (100 by /PMS/vis system reach 87.0% 90.2%, respectively. superoxide radicals, photoinduced holes, singlet dominate process, while hydroxyl radicals sulfate play only small role. adsorption energy charge density difference between different systems are calculated functional theory, efficiency combining with change length O─O bond after adsorption. mechanism proposed, which provides new idea for study in field catalysis.
Language: Английский
Citations
2Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 678, P. 639 - 656
Published: Sept. 11, 2024
Language: Английский
Citations
16Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: 1017, P. 179057 - 179057
Published: Feb. 1, 2025
Language: Английский
Citations
1Materials Research Bulletin, Journal Year: 2024, Volume and Issue: 182, P. 113132 - 113132
Published: Oct. 6, 2024
Language: Английский
Citations
6Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 180189 - 180189
Published: April 1, 2025
Language: Английский
Citations
0Environmental Research, Journal Year: 2025, Volume and Issue: unknown, P. 121258 - 121258
Published: Feb. 1, 2025
Language: Английский
Citations
0Journal of Water Process Engineering, Journal Year: 2025, Volume and Issue: 74, P. 107791 - 107791
Published: April 24, 2025
Language: Английский
Citations
0Separations, Journal Year: 2025, Volume and Issue: 12(5), P. 111 - 111
Published: April 28, 2025
Tetracycline hydrochloride pollution poses a serious environmental threat; however, it is difficult to deal with by conventional methods. In this study, the Z-scheme BiOCl/Bi2WO6 composite was hydrothermally synthesized and evaluated for its ability decompose tetracycline under visible light. The material systematically characterized XRD, SEM, TEM/HRTEM, XPS, FTIR, BET, PL, UV-Vis DRS, EPR analyze structure, morphology, optical/electrochemical properties. Characterization revealed that featured flower-ball structure broader light absorption higher solar energy efficiency. A narrow bandgap further facilitated charge separation, boosting photocatalytic performance. Among materials, 20% exhibited best performance, removing 94% of in 60 min, which 5.2 times 1.4 than pure BiOCl Bi2WO6, respectively. rate constant 10.8 2.5 Bi2WO6. After five cycles, maintained 88.7% removal rate, X-ray diffraction analysis confirming structural stability well mechanical Electron paramagnetic resonance radical scavenging experiments identified photogenerated holes (h+) superoxide radicals (·O2−) as primary active species. This work highlights fact prepared excellent performance degradation hydrochloride, demonstrating promising potential practical applications.
Language: Английский
Citations
0