Science China Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 29, 2024
Language: Английский
Science China Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 29, 2024
Language: Английский
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(46)
Published: June 18, 2024
Abstract Metal thiophosphite has demonstrated promising application potential as an anode material for sodium‐ion batteries. Nevertheless, the intrinsic low electrical conductivity and drastic volume expansion impede its commercialization. Herein, a series of metal thiophosphite/Ti 3 C 2 T x (metal = Fe, Ni, Co, Cd) composites are constructed via Lewis acidic molten salt etching followed by synchronous phospho‐sulfurization. The Ti substrate endows hybrids with high conductivity. Importantly, grown on MXene layers exhibits 3D cross‐linked structure, which not only facilitates electron/ion transport, but also maintains robust structural stability owing to space confinement effect. As proof concept, FePS /Ti demonstrates remarkable rate performance (827.4 598.1 mAh g −1 at 0.1 10 A , respectively) along long‐term cycling (capacity retention 93.7% after 2000 cycles 5 ). Impressively, //NVPO full cell reversible capacity 396.8 over 1350 . sodium storage mechanism is further unveiled through in situ XRD/ex HRTEM characterizations theoretical calculations. This work provides fresh perspective enhancing electrochemical construction hybrids.
Language: Английский
Citations
15Nanoscale, Journal Year: 2024, Volume and Issue: 16(11), P. 5685 - 5694
Published: Jan. 1, 2024
Bismuth telluride (Bi
Language: Английский
Citations
4Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 98, P. 623 - 633
Published: July 20, 2024
Language: Английский
Citations
4Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160944 - 160944
Published: Feb. 1, 2025
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 163080 - 163080
Published: April 1, 2025
Language: Английский
Citations
0Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 93, P. 112407 - 112407
Published: June 3, 2024
Language: Английский
Citations
3Advanced Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Aug. 28, 2024
Abstract 1D layered nanowires (NWs) are expected to be excellent electrode materials due their efficient electron/ion transport and strain/stress relaxation. However, it is a great challenge synthesize NWs by top‐down synthetic route. Herein, ultralong K 0.5 Mn 0.75 PS 3 (length: >100 µm; diameter: ≈300 nm) synthesized for the first time using “K‐ion chemical scissors”, whose sodium storage performance originates from bifunctional structural unit, ingeniously combining alloying energy functional unit (P−P dimer) with quasi‐intercalated ([MnS ] 4− framework). Stress‐driven K‐ion scissors achieve rapid transformation of MnPS bulk directed tailoring. Compared , exhibit enlarged interlayer spacing (9.32 Å), enhanced electronic conductivity (8.17 × 10 −5 S m −1 vs 4.47 −10 ), high ionic (2.14 mS cm ). As expected, demonstrate capacity (709 mAh g at A ) cycling (≈100% retention after 2500 cycles ranking among metal thiophosphates. quasi‐topological intercalation mechanism revealed through further characterizations. This work expands synthesis approach offers innovative insights cost‐effective large‐scale fabrication outstanding electrochemical performance.
Language: Английский
Citations
2Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 499, P. 155871 - 155871
Published: Sept. 16, 2024
Language: Английский
Citations
2Journal of Power Sources, Journal Year: 2024, Volume and Issue: 614, P. 234990 - 234990
Published: July 1, 2024
Language: Английский
Citations
1Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 1, 2024
Language: Английский
Citations
1