PVC-based
materials
are
bad
in
terms
of
biodegradability.
To
enhance
the
ecological
property
such
materials,
fabrication
composites
using
biofillers
with
acceptable
performance
characteristics
could
be
considered.
In
this
work,
plant-filled
composite
were
obtained
and
study
their
optical,
structural,
thermal,
mechanical
properties
depending
on
nature
filler
(spruce
flour,
birch
rice
husk)
studied.
Increasing
proportion
plant
somewhat
reduces
strength
flexibility
samples.
But
samples
allows
them
to
used
at
low
temperatures
without
changing
operating
characteristics.
Some
fillers
affected
thermal
stability
by
increasing
decomposition
resistance.
So,
results
have
shown
that
polymer
based
PVC
can
an
equal
basis
unfilled
plastic
compound
for
some
applications
as
construction.
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 16, 2025
Abstract
Solid
composite
electrolytes
(SCEs)
composed
of
functional
fillers
and
solid
polymer
(SPEs)
can
overcome
some
shortcomings
single‐phase
combine
advantages
each
component,
are
considered
as
high‐performance
solid‐state
(SSEs)
candidates
for
assembling
lithium
metal
batteries
(SSLMBs)
with
high
safety
energy
density.
In
recent
years,
due
to
designability
metal–organic
frameworks
(MOFs),
MOFs/polymer
(MPCEs)
have
become
a
highly
promising
novel
type
SCEs.
Based
on
the
above
content,
this
article
first
describes
composition
mechanism
action
MPCEs,
followed
by
discussion
typical
fabrication
methods
MPCEs.
addition,
mechanisms
unmodified
neat
MOFs
in
improving
performance
SSEs
enhancing
interface
stability
presented
detail,
focus
design
strategies
their
applications
including
dimensional
design,
ligand
IL@MOFs
hybrid
design.
Finally,
thorough
analysis
is
conducted
current
challenges
faced
corresponding
future
development
directions
proposed.
This
review
presents
comprehensive,
systematic,
easily
understandable
application
different
designs
providing
new
perspective
researchers
study
SSEs.
Nano-Micro Letters,
Journal Year:
2025,
Volume and Issue:
17(1)
Published: May 6, 2025
Abstract
Solid
polymer
electrolytes
(SPEs)
have
garnered
considerable
interest
in
the
field
of
lithium
metal
batteries
(LMBs)
owing
to
their
exceptional
mechanical
strength,
excellent
designability,
and
heightened
safety
characteristics.
However,
inherently
low
ion
transport
efficiency
poses
a
major
challenge
for
application
LMBs.
To
address
this
issue,
covalent
organic
framework
(COF)
with
ordered
channels,
chemical
stability,
large
specific
surface
area,
designable
multifunctional
sites
has
shown
promising
potential
enhance
lithium-ion
conduction.
Here,
we
prepared
an
anionic
COF,
TpPa-COOLi,
which
can
catalyze
ring-opening
copolymerization
cyclic
lactone
monomers
situ
fabrication
SPEs.
The
design
leverages
high
area
COF
facilitate
absorption
polymerization
precursor
within
pores,
forming
additional
COF-polymer
junctions
that
pathways.
partial
exfoliation
achieved
through
these
improved
its
dispersion
matrix,
preserving
channels
facilitating
across
grain
boundaries.
By
controlling
variables
alter
crystallinity
TpPa-COOLi
presence
–COOLi
substituents,
long-range
order
substituents
exhibited
superior
electrochemical
performance.
This
research
demonstrates
constructing
high-performance
SPEs
Polymers,
Journal Year:
2024,
Volume and Issue:
16(11), P. 1551 - 1551
Published: May 30, 2024
To
enhance
the
ecological
properties
of
polyvinyl
chloride
(PVC)
products,
fabrication
PVC-based
composites
using
biofillers
with
acceptable
performance
characteristics
could
be
considered.
In
this
work,
plant-filled
composite
materials
were
fabricated
and
their
optical,
structural,
thermal,
mechanical
properties,
depending
on
nature
filler,
studied.
Spruce
flour,
birch
rice
husk
used
as
fillers.
Optical
measurements
showed
selected
technological
parameters,
allowing
films
a
uniform
distribution
dispersed
plant
filler
in
polymer
matrix
to
obtained.
Using
fillers
PVC
leads
reduction
strength
characteristics;
for
instance,
tensile
changed
from
18.0
MPa
(for
pure
film)
~7
20
wt.%
fillers),
~5–6.2
40
fillers).
Thermal
investigations
that
samples
at
low
temperatures
without
changing
operating
characteristics.
Thus,
have
wide
temperature
range,
from—65
°C
150
°C.
TGA
analysis
has
demonstrated
affected
thermal
stability
by
increasing
decomposition
resistance.
The
ability
absorb
water
was
observed
during
investigation
absorption
samples.
And
highest
degree
(up
160
mg/g)
detected
sample
husk.
general,
based
can
an
equal
basis
unfilled
plastic
compounds
some
applications
such
construction
example,
design
tasks).
PVC-based
materials
are
bad
in
terms
of
biodegradability.
To
enhance
the
ecological
property
such
materials,
fabrication
composites
using
biofillers
with
acceptable
performance
characteristics
could
be
considered.
In
this
work,
plant-filled
composite
were
obtained
and
study
their
optical,
structural,
thermal,
mechanical
properties
depending
on
nature
filler
(spruce
flour,
birch
rice
husk)
studied.
Increasing
proportion
plant
somewhat
reduces
strength
flexibility
samples.
But
samples
allows
them
to
used
at
low
temperatures
without
changing
operating
characteristics.
Some
fillers
affected
thermal
stability
by
increasing
decomposition
resistance.
So,
results
have
shown
that
polymer
based
PVC
can
an
equal
basis
unfilled
plastic
compound
for
some
applications
as
construction.
