Characterization and Application of Nanomaterials,
Journal Year:
2024,
Volume and Issue:
7(2), P. 4946 - 4946
Published: April 23, 2024
Graphene
has
been
ranked
among
one
of
the
most
remarkable
nanostructures
in
carbon
world.
modification
and
nanocomposite
formation
have
used
to
expand
practical
potential
graphene
nanostructure.
The
overview
is
an
effort
highlight
indispensable
synthesis
strategies
towards
nanocomposites.
Consequently,
combined
with
useful
matrices
(thermoplastic,
conducting,
or
others)
attain
desired
end
material.
Common
fabrication
approaches
like
in-situ
method,
solution
processing,
melt
extrusion
widely
involved
form
Moreover,
advanced,
sophisticated
methods
such
as
three-
four-dimensional
printing,
electrospinning,
others
synthesize
focus
all
remained
on
standardized
dispersion,
physical
properties,
applications.
However,
continuous
future
efforts
are
required
resolve
challenges
optimization
parameters
behind
each
technique.
As
design
properties
directly
depend
upon
techniques
used,
there
obvious
need
for
development
advanced
having
better
control
over
process
parameters.
Here,
main
challenging
factors
may
involve
precise
parameter
manufacturing.
Hence,
not
only
a
current
research
field
related
material
fabrication,
but
also
reporting
compiled
review
articles
can
be
interested
researchers
challenge
solving
developments
ACS Nano,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 15, 2025
The
thermal
runaway
issue
of
polymer
electrolytes
(solid
(SPEs))
at
high
temperatures,
particularly
the
irreconcilable
contradiction
between
safety
and
electrochemical
performance,
remains
a
great
challenge
for
SPEs
that
can
be
applied
to
solid-state
lithium
batteries.
Here,
an
intelligent
self-extinguishing
system
originating
from
core-shell
structure
microcapsules
is
designed
snuff
out
possibility
provides
high-performance
Li
metal
battery.
shell
not
only
serves
as
barrier
eliminate
detrimental
interactions
flame
retardant
with
electrolyte
or
active
anode
but
also
acts
thermoresponsive
agent
release
retardant.
ion
hopping
points
on
further
contribute
conducting
nature
SPE,
boosting
ionic
conductivity
9.3
×
10-4
S
cm-1.
Significantly,
Li//Li
symmetric
cells
exhibit
stable
long-term
cycling
over
3400
h,
battery
shows
capacity
retention
87.4%
after
500
cycles.
Meanwhile,
SPE
displays
superior
retardancy
self-expansion
time
3
s
g-1.
This
work
offers
versatile
strategy
designing
truly
safe
Li-metal
Polymers for Advanced Technologies,
Journal Year:
2024,
Volume and Issue:
35(10)
Published: Oct. 1, 2024
ABSTRACT
This
work
focuses
on
the
development
of
a
composite
polymer
electrolyte
(CPE)
for
all‐solid‐state
lithium
metal
batteries
(ASSLMBs),
integrating
LLTO
nanofibers
into
PEO
(polyethylene
oxide)‐PVDF‐HFP
(poly(vinylidene
fluoride‐cohexafluoropropylene))
matrix
with
LiClO
4
as
salt.
The
has
high
ionic
conductivity
and
flexibility,
PVDF‐HFP
mechanical
strength
electrochemical
stability.
Therefore,
resulting
improved
performance
properties.
Incorporating
enhances
due
to
one‐dimensional
ion
transport
pathways
provided
by
while
maintaining
integrity
air
stability,
overcoming
challenges
associated
conventional
fillers.
prepared
CPE
demonstrates
exceptional
stability
up
5.1
V
versus
Li/Li
+
,
making
it
suitable
high‐voltage
applications
over
traditional
electrolytes.
optimized
15
wt%
provides
1.1
×
10
−5
S
cm
−1
at
room
temperature
reaches
1.46
−4
80°C.
assembled
LiNi
1/3
Mn
Co
PO
||PEO‐PVDF‐HFP‐LiClO₄‐LLTO||Li
based
2032
coin
cell
worked
in
between
3
4.8
potential
window
without
any
decomposition
from
0.5
5
mV/s
scan
rates.
Similarly,
fabricated
LiFePO₄||PEO‐PVDF‐HFP
(1:2)‐LiClO
‐LLTO
(15
wt%)||Li
an
initial
capacity
149
mAh
g
0.1
C
85
C,
exploring
its
batteries.
Overall,
this
offers
promising
pathway
developing
advanced
solid
electrolytes
next‐generation
batteries,
which
combine
conductivity,
excellent
performances,
robust
Defect and diffusion forum/Diffusion and defect data, solid state data. Part A, Defect and diffusion forum,
Journal Year:
2025,
Volume and Issue:
442, P. 35 - 42
Published: May 16, 2025
Cellulose
polymer-based
Solid
Polymer
Electrolytes
(SPEs)
have
gained
attention
as
an
environmentally
friendly
and
sustainable
alternative
for
energy
storage
applications,
particularly
in
lithium-ion
batteries.
The
proper
selection
of
electrolytes
is
crucial
enhancing
the
performance
stability
SPEs.
This
study
presents
a
comparative
analysis
LiBOB,
LiPF
6
LiTFSI
cellulose-based
solid
polymer
(SPEs).
cellulose-SPEs
were
evaluated
based
on
their
mechanical
electrochemical
performance.
Our
findings
reveal
that
cellulose-LiTFSI
exhibited
highest
electrolyte
uptake
(784%)
retention
(88.69%),
followed
by
cellulose-LiPF
(690%
87.34%
retention),
cellulose-LiBOB
(355.33%
78.04%
retention).
Morphological
research
reveals
all
SPEs
exhibit
porous
structures
demonstrate
contact
with
electrolyte,
however
LiBOB
cellulose
does
not
effectively
absorb
electrolyte.
Heat
treatment
at
150°C
4
hours
demonstrated
significant
differences
thermal
stability,
where
maintained
structural
integrity
negligible
alteration
color,
while
darkened
underwent
decomposition.
has
greatest
potential
window
4.25
V,
ionic
conductivity,
measuring
1.359
x
10-6
C/m.
Conversely,
(3.37)
better
than
(2.91
V),
lowest
conductivity
(1.424
10
-7
C/m).
These
results
suggest
profoundly
impacts
properties
SPEs,
showing
best
possibility
application
Crystals,
Journal Year:
2024,
Volume and Issue:
15(1), P. 31 - 31
Published: Dec. 30, 2024
Lithium-conducting
NASICON
materials
have
emerged
as
a
promising
alternative
to
organic
liquid
electrolytes
for
high-energy-density
Li-metal
batteries,
owing
their
superior
ionic
conductivity
and
excellent
air
stability.
However,
practical
application
is
hindered
by
poor
sintering
characteristics
high
grain
boundary
resistance.
In
this
investigation,
Li1.3Al0.3−xYxTi1.7(PO4)3
(LAYTP-x,
x
=
0.00,
0.01,
0.03,
0.05,
0.07)
were
successfully
synthesized
via
conventional
solid-state
reaction
explore
the
impact
of
Y3+
on
both
chemical
The
structural,
morphological,
transport
properties
samples
comprehensively
characterized
in
order
identify
optimal
doping
concentration.
All
exhibited
structure
with
uniform
distribution
Y
elements
within
electrolyte.
Due
its
highest
relative
density
(95.8%),
LAYTP-0.03
electrolyte
demonstrated
total
2.03
×
10−4
S
cm−1
relatively
low
activation
energy
0.33
eV,
making
it
suitable
batteries.
When
paired
NCM811
cathode,
Li/LAYTP-0.03/NCM811
cell
outstanding
electrochemical
performance:
capacity
155
mAh/g
was
achieved
at
0.2C
after
50
cycles
Coulombic
efficiency
approximately
100%,
indicating
highly
reversible
lithium
plating/stripping
facilitated
These
results
suggest
that
ceramic
could
be
developing
safe
