Metal–Organic Frameworks and Derivative Materials in Perovskite Solar Cells: Recent Advances, Emerging Trends, and Perspectives DOI
Syed Afaq Ali Shah, Muhammad Hassan Sayyad, Zhongyi Guo

et al.

Solar RRL, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 30, 2024

The power conversion efficiency (PCE) of perovskite solar cells (PSCs) has reached an impressive value 26.1%. While several initiatives such as structural modification and fabrication techniques helped steadily increase the PCE stability PSCs in recent years, incorporation metal–organic frameworks (MOFs) stands out among other innovations emerged a promising path forward to make this technology front‐runner for realizing next‐generation low‐cost photovoltaic technologies. Owing their unique physiochemical properties extraordinary advantages large specific surface area tunable pore structures, incorporating them as/in different functional layers endows devices with optoelectronic properties. This article reviews latest research practices adapted integrating MOFs derivative materials into constituent blocks photoactive absorber, electron‐transport layer, hole‐transport interfacial layer. Notably, special emphasis is placed on aspect improvement by materials. Also, potential lead absorbents highlighted. Finally, outlook critical challenges faced future perspectives employing light commercialization provided.

Language: Английский

Yttrium Metal–Organic Framework Nanocrystals for Two‐Step Deposited Perovskite Photovoltaics with Enhanced UV‐light Durability DOI
Jiajun Wu, Xiao Liang, Jiaqi Liu

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(44)

Published: June 27, 2024

Abstract Metal–organic frameworks (MOFs), renowned for their porous and tunable functionalities, hold significant potential enhancing perovskite photovoltaic. However, the influence of MOF, particularly those with balanced cations in pores, on conversion bottom‐layer PbI 2 distribution MOFs within remains underexplored. Herein, a newly synthesized Yttrium (Y)‐MOF material is introduced, featuring dimethylamine (DMA) as its pores strong absorption UV regime, to modify films. Y‐MOF, rich oxygen nitrogen sites, DMA can passivate uncoordinated Pb 2+ perovskite. Scanning electron microscopy (SEM) grazing incidence wide‐angle X‐ray scattering (GIWAXS) analysis top bottom surfaces pristine Y‐MOF‐assisted samples reveal that presence films negligible. In situ UV–vis analyses demonstrate incorporation Y‐MOF decelerates crystallization kinetics perovskite, facilitating development larger grains. Moreover, GIWAXS experiments conducted at different angles predominant which effectively mitigates impact ultraviolet light Consequently, devices achieve an efficiency 24.05% improved stability especially UV‐light stability.

Language: Английский

Citations

6
Synergistic Enhancement of Light Harvesting and Interfacial Defect Reduction Using Metal–Organic Frameworks for Efficient and Stable Perovskite Solar Cells DOI
Chenyu Zhao, Meihan Liu, Xiaoye Liu

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: March 28, 2025

Language: Английский

Citations

0
Suppression of light-induced phase segregation in all-inorganic wide-bandgap perovskite solar cells via molecular interaction design DOI
Jing Yang, Ye-Hua Gan, Mengqi Han

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

Citations

0
A Comprehensive Review of Organic Frameworks：from Synthesis to Perovskite Solar Cells Fabrication DOI
Jiajun Wu, Xiao Liang,

Xianfang Zhou

et al.

Organic Electronics, Journal Year: 2024, Volume and Issue: 132, P. 107100 - 107100

Published: July 22, 2024

Language: Английский

Citations

2
Energy Level Alignment Regulation and Carrier Management in Perovskite Solar Cells with Various Bandgaps Using Tailored Metal‐Organic Frameworks DOI
Bo Xiao, Wenguang Zhang,

Yuchen Xiong

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 21, 2024

Abstract The interface energy level alignment modulation and charge carrier transportation play an important role in the device performance of perovskite solar cells (PSCs). Herein, tailored hydrophobic metal‐organic frameworks (MOFs) are employed as interfacial layers between absorbers hole transport (HTLs). MOFs feature abundant carboxylic acid groups capable bonding with Pb 2+ organic cations, which can effectively passivate defects suppress non‐radiative recombination. Meanwhile, MOF optimized HTL, further facilitating transportation. Specifically, CsFAMA‐based PSCs a bandgap 1.63 eV attained power conversion efficiency (PCE) 23.06% upon modification MOFs. Additionally, MOFs‐treated FA‐based 1.55 achieved remarkable PCE 24.81%, accompanied by outstanding fill factor 84.3% minimal open‐circuit voltage loss merely 0.386 V. Furthermore, integration layer substantially improved moisture stability PSCs. unencapsulated CsFAMA modified retained 91.2% their initial after 2500 h aging under ambient conditions 40% relative humidity (RH). This work underpins commercialization diverse bandgaps.

Language: Английский

Citations

2
Metal–Organic Frameworks and Derivative Materials in Perovskite Solar Cells: Recent Advances, Emerging Trends, and Perspectives DOI
Syed Afaq Ali Shah, Muhammad Hassan Sayyad, Zhongyi Guo

et al.

Solar RRL, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 30, 2024

The power conversion efficiency (PCE) of perovskite solar cells (PSCs) has reached an impressive value 26.1%. While several initiatives such as structural modification and fabrication techniques helped steadily increase the PCE stability PSCs in recent years, incorporation metal–organic frameworks (MOFs) stands out among other innovations emerged a promising path forward to make this technology front‐runner for realizing next‐generation low‐cost photovoltaic technologies. Owing their unique physiochemical properties extraordinary advantages large specific surface area tunable pore structures, incorporating them as/in different functional layers endows devices with optoelectronic properties. This article reviews latest research practices adapted integrating MOFs derivative materials into constituent blocks photoactive absorber, electron‐transport layer, hole‐transport interfacial layer. Notably, special emphasis is placed on aspect improvement by materials. Also, potential lead absorbents highlighted. Finally, outlook critical challenges faced future perspectives employing light commercialization provided.

Language: Английский

Citations

0