Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 1, 2024
Language: Английский
Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 1, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 498, P. 155118 - 155118
Published: Aug. 24, 2024
Language: Английский
Citations
5Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1005, P. 176009 - 176009
Published: Aug. 13, 2024
Language: Английский
Citations
4Rare Metals, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 26, 2025
Language: Английский
Citations
0Rare Metals, Journal Year: 2025, Volume and Issue: unknown
Published: April 4, 2025
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 180478 - 180478
Published: April 1, 2025
Language: Английский
Citations
0ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 7966 - 7978
Published: April 29, 2025
Language: Английский
Citations
0Energy & Fuels, Journal Year: 2025, Volume and Issue: unknown
Published: May 2, 2025
Language: Английский
Citations
0Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 539, P. 216752 - 216752
Published: May 2, 2025
Language: Английский
Citations
0ACS Applied Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: May 12, 2025
Language: Английский
Citations
0Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: May 13, 2025
Abstract This study designs a Fe 3 N/Fe‐NC catalyst with dual internal‐external structure to address polysulfide conversion in Li‐S batteries. Derived from ZIF precursors, the features hollow cavity and star‐like tip structure, where high‐curvature exterior enhances electron transfer at N/Fe heterointerfaces stabilizes Fe‐Nx sites for sulfur adsorption. Multivalent increases effective nuclear charge via penetration effect, promoting 3d orbital tunneling into inner layers. reduces energy levels, populates non‐bonding orbitals single electrons, enables efficient d‐p hybridization minimized antibonding states, strengthening interactions. DFT calculations reveal N/Fe's d band center (ɛ ) proximity Fermi level reduced work function, facilitating transfer. The optimized N/Fe‐NC@PP‐based battery exhibits low capacity decay rate of 0.0603% after 600 cycles 2C maintains high under 6.668 mg cm⁻² loading. pouch cell delivers an initial 1511.57 mAh g⁻¹ 0.1 C 50 cycle stability.
Language: Английский
Citations
0